公开(公告)号：US20120264611A1

公开(公告)日：2012-10-18

申请号：US13497975

申请日：2010-09-18

申请人： Andreas Wacker ,  Joachim Hess ,  Robert Milbradt ,  Franz-Xaver Scherl

发明人： Andreas Wacker ,  Joachim Hess ,  Robert Milbradt ,  Franz-Xaver Scherl

IPC分类号： A01N25/00 ,  A01P7/04 ,  A01P13/00 ,  A01P3/00 ,  A01N25/02 ,  A01N25/04

CPC分类号： A01N25/30 ,  A01N43/36 ,  A01N53/00 ,  A01N57/12 ,  A01N57/20 ,  A01N2300/00

摘要： The invention relates to pesticide preparations that contain one or more pesticides and one or more N-substituted 2-pyrrolidone-4-carboxylic acid derivatives and to the use of said pesticide preparations for controlling and/or combating weeds, fungal diseases, or insect infestation. The N-substituted 2-pyrrolidone-4-carboxylic acid derivatives act as adjuvants, emulsifiers, dispersants, and/or wetting agents in the pesticide preparations.

摘要翻译： 本发明涉及含有一种或多种农药和一种或多种N-取代的2-吡咯烷酮-4-羧酸衍生物的农药制剂，以及所述农药制剂用于控制和/或防治杂草，真菌病害或昆虫侵袭的用途 。 N-取代的2-吡咯烷酮-4-羧酸衍生物作为农药制剂中的佐剂，乳化剂，分散剂和/或润湿剂起作用。

公开(公告)号：US07696385B2

公开(公告)日：2010-04-13

申请号：US11922856

申请日：2006-06-10

申请人： Dirk Buehring ,  Andreas Gallas ,  Martin Glos ,  Klaus Raab ,  Franz-Xaver Scherl ,  Olaf Wachsen

发明人： Dirk Buehring ,  Andreas Gallas ,  Martin Glos ,  Klaus Raab ,  Franz-Xaver Scherl ,  Olaf Wachsen

IPC分类号： C07C209/16

CPC分类号： C07C213/02 ,  B01J23/75 ,  B01J25/00 ,  C07C217/08 ,  C07C217/50

摘要： The invention relates to a method for producing amines of formula (1), wherein R3 is an organic group containing from 2 to 600 alkoxy groups and R1 and R3 groups are similar or different and represent a hydrogen atom or an organic group containing from 1 to 400 carbon atoms. The inventive method consists in bringing a compound of formula (2) into contact a compound of formula (3) in the presence of hydrogen with a metal-containing catalyst, wherein the metal content in cobalt is equal to or greater than 80% by weight.

摘要翻译： 本发明涉及一种制备式（1）胺的方法，其中R 3是含有2至600个烷氧基的有机基团，R 1和R 3基团相似或不同，表示氢原子或含有1至 400个碳原子。 本发明的方法包括使式（2）的化合物与氢存在下的式（3）化合物与含金属的催化剂接触，其中钴中的金属含量等于或大于80重量％ 。

公开(公告)号：US20110065811A1

公开(公告)日：2011-03-17

申请号：US12293671

申请日：2007-03-15

申请人： Franz-Xaver Scherl ,  Joachim Hess ,  Ralf Zerrer ,  Christian Sowa

发明人： Franz-Xaver Scherl ,  Joachim Hess ,  Ralf Zerrer ,  Christian Sowa

IPC分类号： B01F17/16 ,  C07C215/06

CPC分类号： C07C217/28 ,  C07C213/06 ,  C07C217/50

摘要： Ethanolamine glyceryl ether condensation products of the formula (I) are described, in which R1, R2 and R3 may each independently be the same or different and are each hydrogen, a linear or branched, saturated alkyl chain having from 1 to 20 carbon atoms, a linear or branched unsaturated alkenyl group having from 2 to 20 carbon atoms, —CH2—CH2—OH or a radical of the formula (II), with the proviso that at least one of the R1, R2 and R3 radicals is a radical of the formula (II) and at least one further radical of the R1, R2 and R3 radicals is selected from —CH2—CH2—OH and radicals of the formula (II), wherein (O-A), (O-D), R4, R5, a, b, d, and e are as defined in the specification.

摘要翻译： 描述了式（I）的乙醇胺甘油醚缩合产物，其中R 1，R 2和R 3可各自独立地相同或不同，各自为氢，具有1至20个碳原子的直链或支链饱和烷基链， 具有2至20个碳原子的直链或支链不饱和链烯基，-CH 2 -CH 2 -OH或式（II）基团，条件是R 1，R 2和R 3基团中的至少一个为 式（II）和R 1，R 2和R 3基团的至少一个另外的基团选自-CH 2 -CH 2 -OH和式（II）的基团，其中（OA），（OD），R 4，R 5， a，b，d和e如说明书中所定义。

公开(公告)号：US07671098B2

公开(公告)日：2010-03-02

申请号：US10559719

申请日：2004-05-25

申请人： Dirk Leinweber ,  Franz-Xaver Scherl ,  Elisabeth Wasmund ,  Heidi Rausch

发明人： Dirk Leinweber ,  Franz-Xaver Scherl ,  Elisabeth Wasmund ,  Heidi Rausch

IPC分类号： B01D17/05

CPC分类号： C10G33/04

摘要： The invention relates to the use of alkoxylated crosslinked polyglycerols for demulsifying oil/water emulsions in amounts of from 0.0001 to 5% by weight, based on the oil content of the emulsion to be demulsified. The alkoxylated crosslinked polyglycerols of the invention is crosslinked with multifunctional electrophilic compounds having a molecular weight of from 1000 to 100 000 units and which comprise 5 to 100 glycerol units which are alkoxylated with C2-C4-alkylene oxide groups or a mixture of such alkylene oxide groups so that the crosslinked alkoxylated polyglycerols have a degree of alkoxylation of from 1 to 100 alkylene oxide units per free OH group.

摘要翻译： 本发明涉及烷氧基化交联聚甘油用于基于待破乳的乳液的油含量为0.0001至5重量％的量将油/水乳液破乳的用途。 本发明的烷氧基化交联聚甘油与分子量为1000至100000单位的多官能亲电子化合物交联，并且包含5至100个用C 2 -C 4 - 氧化烯基团烷氧基化的甘油单元或这种烯化氧的混合物 使得交联的烷氧基化聚甘油的每个游离OH基具有1至100个烯化氧单元的烷氧基化程度。

公开(公告)号：US08071814B2

公开(公告)日：2011-12-06

申请号：US12517506

申请日：2007-07-07

申请人： Dirk Buehring ,  Andreas Gallas ,  Klaus Raab ,  Franz-Xaver Scherl ,  Olaf Wachsen

发明人： Dirk Buehring ,  Andreas Gallas ,  Klaus Raab ,  Franz-Xaver Scherl ,  Olaf Wachsen

IPC分类号： C07C209/16

CPC分类号： C07C213/02 ,  C07C217/08

摘要： The invention provides a process for preparing polyetheramines of the formula (1), R2 (NR1R3)n, in which n is a number from 1 to 20, R2 represents an organic radical that contains between 2 and 600 oxalkylene groups, and R1 and R3 are alike or different and represent hydrogen or an organic radical having 1 to 400 carbon atoms, by combining a compound of the formula (2), H(NR1R3), with a compound of the formula (3), R2 (OH)n, in the presence of hydrogen with a metal-containing catalyst whose metal content, based on the dry, reduced catalyst excluding any support material that may be present, is composed either of at least 80% by mass of cobalt or, in the case of Raney catalysts, of at least 80% by mass of metals from the group consisting of cobalt and aluminium, the catalyst containing less than 5% by mass of copper.

摘要翻译： 本发明提供一种制备式（1）的聚醚胺，R2（NR1R3）n，其中n为1至20的数，R2表示含有2至600个氧亚烷基的有机基团，R1和R3 通过将式（2），H（NR 1 R 3）的化合物与式（3）的化合物，R2（OH）n， 在含有金属的催化剂的存在下，其金属含量（基于干燥的还原催化剂，不包括任何可能存在的载体材料）由至少80质量％的钴组成，或者在阮内 催化剂，至少80质量％的来自钴和铝的金属，所述催化剂含有小于5质量％的铜。

公开(公告)号：US20060264330A1

公开(公告)日：2006-11-23

申请号：US10546504

申请日：2004-02-13

申请人： Ralf Zerrer ,  Franz-Xaver Scherl

发明人： Ralf Zerrer ,  Franz-Xaver Scherl

IPC分类号： A01N25/10

CPC分类号： A01N25/30 ,  A01N2300/00

摘要： The present invention relates to agricultural compositions comprising: A) a pesticide or a plant growth regulator B) a copolymer made of a) a polyglycerol ether b) one or more dicarboxylic acid(s) and/or polycarboxylic acids, wherein the polyglycerol ethers being defined by the formula (I) wherein the radicals R1, R2 and R3 are independently identical or different and represent hydrogen; (C1-C30)-alkyl which is optionally substituted by 1 to 3 (C1-C4)-alkyl or (C1-C4)-alkoxy groups; (C2-C30)-alkenyl which is optionally sulfonated and optionally substituted by 1 to 3 (C1-C4)-alkyl or (C1-C4)-alkoxy groups; phenyl which is optionally substituted by 1 to 3 (C1-C4)-alkyl or (C1-C4)-alkoxy groups; naphthyl which is optionally substituted by 1 to 3 (C1-C4)-alkyl or (C1-C4)-alkoxy groups; groups of the formulae R4R5N—(CH2)y—; HO—(CH2)y—; -(AO)zH; —SO3H; —SO3−X+; —PO3H2; —PO32−X+; —CR2—COOR′; —CR2—COO−X+; —CO—R6—COOH; —CO—R6—COO−X+; —C(R)2C(R)2C(R)2—N(R)2; —C(R)2C(R)2C(R)2—N((AO)zH)2; —[CH2CH(O(AO)zH)CH2O]n—R1; where R represents H and/or C1-C4-alkyl; R′ represents H or (C1-C10)-alkyl, (C2-C30)-alkenyl, optionally sulfonated; R4 and R5, which can be identical or different, represent hydrogen, (C1-C10)-alkyl, (C2-C30)-alkenyl, optionally sulfonated, or a group of the formula -(AO)zH; R6 represents (C1-C10)-alkylene, (C2-C30)-alkenylene, optionally sulfonated; X+ represents Na+, K+, Ca2+ or N(R7)4+, where R7 represents H or (C1-C10)-alkyl, preferably (C1-C4)-alkyl; x represents a number from 0 to 15; y represents a number from 4 to 6; z represents a number from 0 to 30, preferably 1 to 5; A represents an alkylene group, preferably a group —C2H4—, —C3H6— or —C4H8—; n represents a number from 4 to 40, preferably 5 to 20, in particular 10 to 20; and the indices p1, q1, r1, p2, q2, r2, p3, q3 and r3 represent numbers from 0 to 500; with the proviso that the compounds of the formula (I) comprise free OH groups, and at least one of the radicals R1, R2 and R3 represents a hydrocarbon group, preferably (C1-C30)-alkyl.

公开(公告)号：US20090177013A1

公开(公告)日：2009-07-09

申请号：US11922856

申请日：2006-06-10

申请人： Dirk Buehring ,  Andreas Gallas ,  Martin Glos ,  Klaus Raab ,  Franz-Xaver Scherl ,  Olaf Wachsen

发明人： Dirk Buehring ,  Andreas Gallas ,  Martin Glos ,  Klaus Raab ,  Franz-Xaver Scherl ,  Olaf Wachsen

IPC分类号： C07C209/16

CPC分类号： C07C213/02 ,  B01J23/75 ,  B01J25/00 ,  C07C217/08 ,  C07C217/50

摘要： The invention relates to a method for producing amines of formula (1), wherein R3 is an organic group containing from 2 to 600 alkoxy groups and R1 and R3 groups are similar or different and represent a hydrogen atom or an organic group containing from 1 to 400 carbon atoms. The inventive method consists in bringing a compound of formula (2) into contact a compound of formula (3) in the presence of hydrogen with a metal-containing catalyst, wherein the metal content in cobalt is equal to or greater than 80% by weight.

摘要翻译： 本发明涉及一种制备式（1）胺的方法，其中R 3是含有2至600个烷氧基的有机基团，R 1和R 3基团相似或不同，表示氢原子或含有1至 400个碳原子。 本发明的方法包括使式（2）的化合物与氢存在下的式（3）化合物与含金属的催化剂接触，其中钴中的金属含量等于或大于80重量％ 。

公开(公告)号：US20110237667A1

公开(公告)日：2011-09-29

申请号：US12671712

申请日：2008-07-31

申请人： Matthias Loeffler ,  Franz-Xaver Scherl ,  Tom Fricke

发明人： Matthias Loeffler ,  Franz-Xaver Scherl ,  Tom Fricke

IPC分类号： A61K31/225 ,  C07C229/24 ,  A61K8/92 ,  A61Q19/00 ,  A61Q5/00 ,  A61P17/00

CPC分类号： A61K8/416 ,  A61Q5/12 ,  A61Q19/00

摘要： The invention relates to compositions containing one or more compounds of the formula (1), wherein R1CO and R2CO are linear or branched saturated acyl groups independent of each other, having 18 to 24 C atoms, and A− is a counter-ion, and the total amount of C18-23-alkyl COO groups is 40.0 wt.-% or more, based on all groups R1COO— and R2COO—. The compositions are, for example, cosmetic, dermatological, or pharmaceutical compositions.

摘要翻译： 本发明涉及含有一种或多种式（1）化合物的组合物，其中R1CO和R2CO是彼此独立的具有18-24个C原子的直链或支链饱和酰基，A-是抗衡离子，和 基于所有基团R1COO-和R2COO-，C18-23烷基COO基团的总量为40.0重量％以上。 组合物是例如化妆品，皮肤病学或药物组合物。

公开(公告)号：US20110083957A1

公开(公告)日：2011-04-14

申请号：US12935308

申请日：2009-03-18

申请人： Matthias Krull ,  Roman Morschhaeuser ,  Joachim Hess ,  Robert Milbradt ,  Franz-Xaver Scherl ,  Andreas Wacker ,  Michael Seebach ,  Joerg Appel

发明人： Matthias Krull ,  Roman Morschhaeuser ,  Joachim Hess ,  Robert Milbradt ,  Franz-Xaver Scherl ,  Andreas Wacker ,  Michael Seebach ,  Joerg Appel

IPC分类号： B01J19/12

CPC分类号： C07C231/02 ,  B01J19/126 ,  B01J2219/00141 ,  B01J2219/1248 ,  C07C235/06

摘要： The invention relates to a continuous method for producing hydroxycarboxylic acid amides, according to which at least one hydroxycarboxylic acid of formula (I) HO—R3—COOH  (I) wherein R3 is an optionally substituted aliphatic hydrocarbon group comprising between 1 and 100 carbon atoms, is reacted with at least one amine of formula (II) HNR1R2  (II) wherein R1 and R2 are independently hydrogen or a carbon group comprising between 1 and 100 C atoms, to form an ammonium salt, and said ammonium salt is then reacted to form a hydroxycarboxylic acid amide, under microwave irradiation in a reaction pipe, the longitudinal axis of the pipe being oriented in the direction of propagation of the microwaves of a monomode microwave applicator.

摘要翻译： 本发明涉及一种用于生产羟基羧酸酰胺的连续方法，根据该方法，至少一种式（I）HO-R 3 -COOH（I）的羟基羧酸（其中R 3是含有1至100个碳原子的任选取代的脂族烃基） 与式（II）HNR1R2（Ⅱ）的至少一种胺反应，其中R 1和R 2独立地是氢或含有1至100个碳原子的碳基，以形成铵盐，然后所述铵盐与 在微波辐射下在反应管中形成羟基羧酸酰胺，管的纵向轴线沿着单模微波施加器的微波的传播方向取向。

公开(公告)号：US20100069671A1

公开(公告)日：2010-03-18

申请号：US12517506

申请日：2007-07-07

申请人： Dirk Buehring ,  Andreas Gallas ,  Klaus Raab ,  Franz-Xaver Scherl ,  Olaf Wachsen

发明人： Dirk Buehring ,  Andreas Gallas ,  Klaus Raab ,  Franz-Xaver Scherl ,  Olaf Wachsen

IPC分类号： C07C211/03

CPC分类号： C07C213/02 ,  C07C217/08

摘要： The invention provides a process for preparing polyetheramines of the formula (1), R2 (NR1R3)n, in which n is a number from 1 to 20, R2 represents an organic radical that contains between 2 and 600 oxalkylene groups, and R1 and R3 are alike or different and represent hydrogen or an organic radical having 1 to 400 carbon atoms, by combining a compound of the formula (2), H(NR1R3), with a compound of the formula (3), R2 (OH)n, in the presence of hydrogen with a metal-containing catalyst whose metal content, based on the dry, reduced catalyst excluding any support material that may be present, is composed either of at least 80% by mass of cobalt or, in the case of Raney catalysts, of at least 80% by mass of metals from the group consisting of cobalt and aluminium, the catalyst containing less than 5% by mass of copper.

摘要翻译： 本发明提供一种制备式（1）的聚醚胺，R2（NR1R3）n，其中n为1至20的数，R2表示含有2至600个氧亚烷基的有机基团，R1和R3 通过将式（2），H（NR 1 R 3）的化合物与式（3）的化合物，R2（OH）n， 在含有金属的催化剂的存在下，其金属含量（基于干燥的还原催化剂，不包括任何可能存在的载体材料）由至少80质量％的钴组成，或者在阮内 催化剂，至少80质量％的来自钴和铝的金属，所述催化剂含有小于5质量％的铜。