Secondary Battery
    41.
    发明公开
    Secondary Battery 审中-公开

    公开(公告)号:US20240178368A1

    公开(公告)日:2024-05-30

    申请号:US18010818

    申请日:2022-11-16

    CPC classification number: H01M4/134 H01M10/0567 H01M2004/027 H01M2300/0028

    Abstract: The present application provides a secondary battery, including a positive electrode, a negative electrode with a negative electrode material layer, and a non-aqueous electrolyte, the negative electrode material layer comprises a negative electrode active material, and the negative electrode active material comprises a silicon-based material;
    the non-aqueous electrolyte comprises a solvent, an electrolyte salt and an additive, the additives comprises a compound represented by structural formula 1;




    wherein n is 0 or 1, A is selected from C or O, X is selected from






    R1 and R2 are each independently selected from H,
    R1 and R2 are not selected from H at the same time, and X, R1 and R2 comprise at least one sulfur atom;








    the secondary battery meets the following requirements:







    0
    .
    2


    1




    m
    *
    n
    *
    r

    S


    40

    ;




    and 40%≤m≤90%, 0.05%≤n≤2%, 1.2 g/cm3≤r≤1.8 g/cm3, 5%≤S≤30%.

    NON-AQUEOUS ELECTROLYTE FOR LITHIUM-ION BATTERY AND LITHIUM-ION BATTERY

    公开(公告)号:US20220263133A1

    公开(公告)日:2022-08-18

    申请号:US17735109

    申请日:2022-05-02

    Abstract: A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte includes an unsaturated phosphate compound and a cyclic unsaturated carboxylic anhydride compound. The unsaturated phosphate compound has a structure represented by structural formula (4). R13, R11 and R12 are each independently selected from a hydrocarbon group having 1 to 5 carbon atoms, and at least one of R13, R11 and R12 is an unsaturated hydrocarbon group having a double bond or a triple bond. The unsaturated cyclic carboxylic anhydride compound having a structure represented by Structural Formula 5. R14 is selected from the group consisting of an alkenylene group having 2 to 4 carbon atoms or a fluorinated alkenylene group having 2 to 4 carbon atoms. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance.

    Non-aqueous electrolyte for lithium ion battery and lithium ion battery

    公开(公告)号:US11380937B2

    公开(公告)日:2022-07-05

    申请号:US16632862

    申请日:2017-12-28

    Abstract: Provide is a non-aqueous electrolyte for lithium ion battery, comprising a compound represented by structural formula I: In formula I, R1, R2, R3 and R4 are each independently selected from hydrogen atom, fluorine atom, cyano group, hydrocarbyl group or halogenated hydrocarbyl group having 1-5 carbon atoms, oxygen-containing hydrocarbyl group having 1-5 carbon atoms, silicon-containing hydrocarbyl group having 1-5 carbon atoms, X is a —O—R5—CN group, R5 is a hydrocarbyl group or a halogenated hydrocarbyl group having 1-5 carbon atoms, m, n, z and y are integers of 0 or 1, and m+n+y+z≠0. When the non-aqueous electrolyte is used for lithium ion battery, the decomposition of electrolyte on the surface of electrode can be inhibited, and the high-temperature storage performance is improved with less gas generation and small expansion rate, therefore the high-temperature cycle performance and high-temperature storage performance of the battery are effectively improved.

    NON-AQUEOUS ELECTROLYTE AND LITHIUM ION BATTERY

    公开(公告)号:US20220013810A1

    公开(公告)日:2022-01-13

    申请号:US17294176

    申请日:2019-11-22

    Abstract: Provided is a non-aqueous electrolyte, comprising a solvent, a lithium salt, an additive A and an additive B, the additive A is selected from compound represented by structural formula 1, and the additive B is selected from one or more of compounds represented by structural formula 2 and structural formula 3: R1 is an alkenyl with 2-5 carbon atoms or an alkynyl with 2-5 carbon atoms, R2 is a fluoroalkyl with 1-5 carbon atoms, R3 is an alkyl with 1-4 carbon atoms, an aryl with 6-10 carbon atoms, an alkenyl with 2-5 carbon atoms, an alkynyl with 2-5 carbon atoms or a fluoroalkyl with 1-5 carbon atoms. Meanwhile, the invention also discloses a lithium ion battery comprising the non-aqueous electrolyte. The non-aqueous electrolyte provided by the invention can effectively give consideration to both high and low temperature performances of the battery.

    NON-AQUEOUS ELECTROLYTE FOR LITHIUM ION BATTERY AND LITHIUM ION BATTERY

    公开(公告)号:US20200020972A1

    公开(公告)日:2020-01-16

    申请号:US16490899

    申请日:2017-06-23

    Abstract: The application provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a compound A represented by formula I and a compound B represented by formula II, In formula I, R1, R2 and R3 are independently selected from C1-C5 alkyl or haloalkyl, C2-C5 unsaturated hydrocarbon group or unsaturated halohydrocarbon group, and at least one of R1, R2 and R3 is the unsaturated hydrocarbon group or unsaturated halohydrocarbon group; In formula II, R4, R5, R6, R7, R8 and R9 are each independently selected from one of hydrogen atom, fluorine atom and C1-C5 group. The non-aqueous electrolyte for lithium ion battery provided by the application enables the battery to have excellent cycle performance and high-temperature storage performance through the synergistic effect of the compound A and the compound B.

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