公开(公告)号：US5654434A

公开(公告)日：1997-08-05

申请号：US555822

申请日：1995-11-09

申请人： Stephen D. Pastor ,  Andrea R. Smith ,  Kurt M. Bessonen

发明人： Stephen D. Pastor ,  Andrea R. Smith ,  Kurt M. Bessonen

IPC分类号： C07D211/94

CPC分类号： C07D211/94

摘要： An environmentally friendly process is described for the preparation of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl by the direct hydrogen peroxide oxidation of 4-hydroxy-2,2,6,6-tetramethylpiperidine in the absence of any catalyst.

摘要翻译： 描述了在不存在的情况下通过4-羟基-2,2,6,6-四甲基哌啶的直接过氧化氢氧化制备4-羟基-2,2,6,6-四甲基哌啶-N-氧基的环境友好的方法 的任何催化剂。

公开(公告)号：US5021479A

公开(公告)日：1991-06-04

申请号：US420194

申请日：1989-10-12

申请人： Ramanathan Ravichandran ,  Stephen D. Pastor

发明人： Ramanathan Ravichandran ,  Stephen D. Pastor

IPC分类号： C08K5/32 ,  C08K5/372 ,  C09K15/24

CPC分类号： C08K5/32 ,  C08K5/3725 ,  C09K15/24

摘要： Substituted hydroxylamine ester stabilizers corresponding to the formula ##STR1## wherein n is 0-2, X is a direct bond, --S-- or --CH.sub.2 S--, R.sub.1 and R.sub.2 are independently hydrogen, alkyl, cycloalkyl, aralkyl, R.sub.3 and R.sub.4 are independently alkyl, cycloalkyl or aralkyl, and R.sub.5 is hydrogen or the group ##STR2## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation.

公开(公告)号：US4758614A

公开(公告)日：1988-07-19

申请号：US855662

申请日：1986-04-25

申请人： Stephen D. Pastor ,  Edward T. Hessell ,  Ramanathan Ravichandran

发明人： Stephen D. Pastor ,  Edward T. Hessell ,  Ramanathan Ravichandran

IPC分类号： C09K15/22 ,  C07C67/00 ,  C07C239/00 ,  C07C269/00 ,  C07C271/06 ,  C07C325/00 ,  C07C333/02 ,  C08K5/16 ,  C08K5/205 ,  C08L67/02 ,  C08L69/00 ,  C09K15/28 ,  C08K5/34 ,  C08K5/52

CPC分类号： C08L67/02 ,  C07C271/06 ,  C07C333/02 ,  C08K5/205 ,  C08L69/00

摘要： Substituted amino carbamate derivatives corresponding to the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants and/or metal salts of fatty acids and/or hindered amine light stabilizers and/or organic phosphorus compounds; and certain of said derivatives as new compounds.

摘要翻译： 相应于式“IMAGE”的取代的氨基氨基甲酸酯衍生物有效稳定有机材料，防止氧化，热和光化学降解，所述衍生物特别有效，作为含有酚类抗氧化剂和/或脂肪酸金属盐的有机材料中的颜色改进剂和加工稳定剂 和/或受阻胺光稳定剂和/或有机磷化合物; 和某些所述衍生物作为新化合物。

公开(公告)号：US4611023A

公开(公告)日：1986-09-09

申请号：US756147

申请日：1985-07-17

申请人： John D. Spivak ,  Stephen D. Pastor

发明人： John D. Spivak ,  Stephen D. Pastor

IPC分类号： C08K5/37 ,  C08K5/375 ,  C08L53/02 ,  C08L59/00 ,  C07C149/36

CPC分类号： C07C323/00 ,  C08K5/375

摘要： Organic materials are stabilized against thermal, oxidative and photo-degradation by incorporating therein an effective amount of a compound of formula I ##STR1## wherein R is tert-butyl, R.sub.1 is hydrogen or alkyl of 1 to 4 carbon atoms, R.sub.2 is alkyl of 1 to 17 carbon atoms, cyclohexyl, cyclohex-3-enyl, phenyl or 3,5-di-tert-butyl-4-hydroxyphenyl; where R.sub.1 and R.sub.2 together must have a total of at least 5 carbon atoms; or where R.sub.1 and R.sub.2 together are alkylene of 5 to 11 carbon atoms. Polyolefins, ABS resins, natural and synthetic rubbers and polyesters are particularly well stabilized by the compounds of formula I.

摘要翻译： 通过在其中加入有效量的式I化合物（I）稳定有机材料，其中R为叔丁基，R 1为氢或1至4个碳原子的烷基，R 2为 具有1至17个碳原子的烷基，环己基，环己-3-烯基，苯基或3,5-二叔丁基-4-羟基苯基; 其中R 1和R 2必须总共具有至少5个碳原子; 或者其中R 1和R 2一起是5至11个碳原子的亚烷基。 聚烯烃，ABS树脂，天然和合成橡胶和聚酯通过式I化合物特别好地稳定。

公开(公告)号：US4521320A

公开(公告)日：1985-06-04

申请号：US544295

申请日：1983-10-21

申请人： John D. Spivack ,  Stephen D. Pastor

发明人： John D. Spivack ,  Stephen D. Pastor

IPC分类号： C08K5/00 ,  C07C67/00 ,  C07C325/00 ,  C07C333/02 ,  C08K5/36 ,  C08K5/39 ,  C08L23/00 ,  C08L101/00 ,  C10M1/38 ,  C07C155/02 ,  C09K15/26

CPC分类号： C08K5/39

摘要： The title compounds correspond to the formula ##STR1## and are useful as stabilizers for organic polymers and lubricating oils to counteract the degradative effects of heat, light and air.

摘要翻译： 标题化合物对应于式“IMAGE”，可用作有机聚合物和润滑油的稳定剂，以抵消热，光和空气的降解作用。

公开(公告)号：US4497959A

公开(公告)日：1985-02-05

申请号：US463176

申请日：1983-02-03

申请人： John D. Spivack ,  Stephen D. Pastor

发明人： John D. Spivack ,  Stephen D. Pastor

IPC分类号： C08K5/00 ,  C07C67/00 ,  C07C313/00 ,  C07C323/52 ,  C07D307/64 ,  C08K5/36 ,  C08K5/37 ,  C08K5/375 ,  C08K5/378 ,  C08L21/00 ,  C08L23/00 ,  C08L59/04 ,  C08L101/00 ,  C09K15/14

CPC分类号： C07C323/00 ,  C07D307/64 ,  C08K5/375 ,  C08K5/378 ,  C09K15/14

摘要： Substituted succinic anhydride or succinate stabilizers of the formula I or II ##STR1## where R.sub.1 and R.sub.2 are independently alkyl, cycloalkyl, phenyl or aralkyl, R.sub.3 is hydrogen or methyl, R.sub.4 is hydrogen, lower alkyl or phenyl, R.sub.5 is hydrogen, alkyl, alkylthio, arylthio or the structure ##STR2## and R.sub.6 and R.sub.7 are independently hydrogen, alkyl; aryl or substituted aryl are useful as stabilizers for polymeric substrates, particularly polyolefins and rubber.

公开(公告)号：US4052527A

公开(公告)日：1977-10-04

申请号：US766026

申请日：1977-02-07

申请人： Stephen D. Pastor ,  Martin M. Skoultchi

发明人： Stephen D. Pastor ,  Martin M. Skoultchi

IPC分类号： C08F20/00 ,  C08F2/46 ,  C08F20/22 ,  C09J133/04 ,  C09J133/16

CPC分类号： C09J133/16 ,  Y10S430/111 ,  Y10S522/904 ,  Y10S522/913 ,  Y10T428/31699 ,  Y10T428/31797 ,  Y10T428/31906 ,  Y10T428/31928

摘要： The present invention is directed to hot melt pressure sensitive adhesive compositions formed by copolymerizing at least one 3-(chlorinated aryloxy)-2-hydroxypropyl ester of an alpha, beta unsaturated carboxylic acid with acrylate based copolymerizable monomers, heating the resultant ethylenically saturated prepolymer to a temperature sufficient to render it fluid and flowable; coating onto a substrate and exposing to ultraviolet radiation.

公开(公告)号：US06703510B2

公开(公告)日：2004-03-09

申请号：US10417999

申请日：2003-04-17

申请人： Stephen D. Pastor ,  Andrew B. Naughton ,  Robert Detlefsen ,  Mervin G. Wood ,  Joseph Suhadolnik ,  Anthony DeBellis ,  Deborah DeHessa

发明人： Stephen D. Pastor ,  Andrew B. Naughton ,  Robert Detlefsen ,  Mervin G. Wood ,  Joseph Suhadolnik ,  Anthony DeBellis ,  Deborah DeHessa

IPC分类号： C07D24920

CPC分类号： C07D401/04 ,  C07D249/20 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D409/14

摘要： Compounds of formula I or II where R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1 and E2 are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium (II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.

摘要翻译： 式I或II的化合物，其中R是芳基部分，例如苯基，萘基或联苯基，或被一个或多个三氟甲基，溴或氰基取代的苯基，E1和E2独立地是氢，烷基，芳烷基等 通过在过渡金属催化剂如二乙酸钯（II）的存在下，将苯并环的5-位被卤素原子取代的苯并三唑与芳基硼酸或酯反应。 式I的苯并三唑化合物作为汽车涂料和蜡烛蜡的稳定剂是特别有效的。

公开(公告)号：US06579328B2

公开(公告)日：2003-06-17

申请号：US09824149

申请日：2001-04-02

申请人： Stephen D. Pastor ,  Sai Ping Shum

发明人： Stephen D. Pastor ,  Sai Ping Shum

IPC分类号： C11C500

CPC分类号： C09K15/30 ,  C07B63/04 ,  C07D211/94 ,  C09K15/20

摘要： Sterically hindered N-substituted aryloxyamines are prepared by the transition-metal-catalyzed decomposition of diazonium salts in the presence of a sterically hindered nitroxyl radical. These compounds are useful as thermal and light stabilizers for a variety of organic substrates.

公开(公告)号：US5310890A

公开(公告)日：1994-05-10

申请号：US918323

申请日：1992-07-22

申请人： Stephen D. Pastor ,  Joseph E. Babiarz

发明人： Stephen D. Pastor ,  Joseph E. Babiarz

IPC分类号： C07H17/00 ,  C08K5/527 ,  C07H15/00 ,  C08K5/00 ,  C08K5/53 ,  C08L77/00

CPC分类号： C08K5/527 ,  C07H17/00

摘要： Carbohydrate substituted dibenzo[d,g][1,3,2]dioxaphosphocin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.

摘要翻译： 碳水化合物取代的二苯并[d，g] [1,3,2]二氧磷酸磷酸酯化合物，其中A是碳水化合物残基，是在升高的温度下经受热或氧化降解处理的聚合物的有效稳定剂。