公开(公告)号：US20090199351A1

公开(公告)日：2009-08-13

申请号：US12384849

申请日：2009-04-09

申请人： Mervin G. Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael P. DiFazio ,  Joseph E. Babiarz

发明人： Mervin G. Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael P. DiFazio ,  Joseph E. Babiarz

IPC分类号： C07D401/14 ,  C08K5/34 ,  C09D11/02 ,  C09B67/00

CPC分类号： C07D211/94 ,  C07D401/14

摘要： Sterically hindered hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula (8)-(10) These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.

摘要翻译： 经受特定羟基取代的烷氧基胺稳定剂化合物通过某些主链与水具有亲水性而使其与水相容。 空间位阻胺例如具有式（8） - （10）这些化合物在稳定含水聚合物体系中对抗氧化，热和光化辐射的有害影响是特别有效的。 该化合物例如在稳定水性涂料，水性油墨，水性喷墨介质和光固化水性体系中是有效的。

公开(公告)号：US20050261401A1

公开(公告)日：2005-11-24

申请号：US11136792

申请日：2005-05-25

申请人： Mervin Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael DiFazio ,  Joseph Babiarz

发明人： Mervin Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael DiFazio ,  Joseph Babiarz

IPC分类号： C07D211/94 ,  C07D401/14 ,  C08K5/34 ,  C03C17/00 ,  C09D11/00

CPC分类号： C07D211/94 ,  C07D401/14

摘要： Sterically hindered alkoxyamine and hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula where for example E and E′ are 2-hydroxycyclohexyloxy, 2-hydroxy-2-methylpropoxy, benzyloxy, methoxy, propoxy, hexyloxy, heptyloxy, octyloxy or cyclohexyloxy, Rx is for example —NH2+CH2CH2OH Cl−, —NH3+−OAc, ═NOH, —NHCH(CH3)COO−K+, —NHCH2CH2N(CH3)2+−OAc, —NHCH2CH2SO3−K+, —NHCH(COO−K+)CH2CH2SCH3, —NHCH2COO−K+, —OCH(CH3)COO−K+, —OCH2CH2N(CH3)2+−OAc, —OCH2CH2SO3−K+, —OCH(COO−K+)CH2CH2SCH3 or —OCH2COO31K+, and where R5 comprises repeating units of —(OCH2CH2)—, —(OCH2CH2(CH3))—, —(CH2CHCOOH)—, —(CH2C(CH3)COOH)—, —(CH2CHCOOCH3)—, —(NHCH2CH2)—, —(CH2CHOH)—, —(CH2CHCONH2)— or —(CH2CH(NHCOH))—. These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.

公开(公告)号：US20050014948A1

公开(公告)日：2005-01-20

申请号：US10889339

申请日：2004-07-12

申请人： James Galbo ,  Robert Detlefsen

发明人： James Galbo ,  Robert Detlefsen

IPC分类号： C07D211/94 ,  C07C239/08

CPC分类号： C07D211/94

摘要： Sterically hindered N-hydrocarbyloxyamines are prepared from hindered amine N-oxyl compounds by a process which uses hydrogen peroxide or a hydrogen peroxide equivalent, a catalytic amount of a peroxide decomposing transition metal salt, metal oxide, or metal-ligand complex, a hydrocarbon solvent containing no activated hydrogen atoms, and a relatively inert cosolvent. These compounds are useful as thermal and light stabilizers for a variety of organic substrates.

摘要翻译： 通过使用过氧化氢或过氧化氢当量的方法，催化量的过氧化物分解过渡金属盐，金属氧化物或金属 - 配体络合物，烃溶剂来制备受阻胺N-氧基化合物的间接受阻的N-烃氧基胺 不含活性氢原子和相对惰性的助溶剂。 这些化合物可用作多种有机底物的热稳定剂和光稳定剂。

公开(公告)号：US06703510B2

公开(公告)日：2004-03-09

申请号：US10417999

申请日：2003-04-17

申请人： Stephen D. Pastor ,  Andrew B. Naughton ,  Robert Detlefsen ,  Mervin G. Wood ,  Joseph Suhadolnik ,  Anthony DeBellis ,  Deborah DeHessa

发明人： Stephen D. Pastor ,  Andrew B. Naughton ,  Robert Detlefsen ,  Mervin G. Wood ,  Joseph Suhadolnik ,  Anthony DeBellis ,  Deborah DeHessa

IPC分类号： C07D24920

CPC分类号： C07D401/04 ,  C07D249/20 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D409/14

摘要： Compounds of formula I or II where R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1 and E2 are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium (II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.

摘要翻译： 式I或II的化合物，其中R是芳基部分，例如苯基，萘基或联苯基，或被一个或多个三氟甲基，溴或氰基取代的苯基，E1和E2独立地是氢，烷基，芳烷基等 通过在过渡金属催化剂如二乙酸钯（II）的存在下，将苯并环的5-位被卤素原子取代的苯并三唑与芳基硼酸或酯反应。 式I的苯并三唑化合物作为汽车涂料和蜡烛蜡的稳定剂是特别有效的。

公开(公告)号：US08013162B2

公开(公告)日：2011-09-06

申请号：US12384840

申请日：2009-04-09

申请人： Mervin G. Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael P. DiFazio ,  Joseph E. Babiarz

发明人： Mervin G. Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael P. DiFazio ,  Joseph E. Babiarz

IPC分类号： C07D401/12 ,  C08K5/3435

CPC分类号： C07D211/94 ,  C07D401/14

摘要： Sterically hindered hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of formulae (5)-(7) These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.

摘要翻译： 经受特定羟基取代的烷氧基胺稳定剂化合物通过某些主链与水具有亲水性而使其与水相容。 空间位阻胺是例如式（5） - （7）这些化合物在稳定含水聚合物体系中抵抗氧化，热和光化辐射的有害影响方面特别有效。 该化合物例如在稳定水性涂料，水性油墨，水性喷墨介质和光固化水性体系中是有效的。

公开(公告)号：US20070100031A1

公开(公告)日：2007-05-03

申请号：US11640808

申请日：2006-12-18

申请人： Ramanathan Ravichandran ,  Stephen Pastor ,  Deborah Judd ,  Joseph Babiarz ,  Andrew Naughton ,  Mervin Wood ,  Anthony Debellis ,  Rong Xiong ,  Robert Detlefsen ,  Joseph Suhadolnik

发明人： Ramanathan Ravichandran ,  Stephen Pastor ,  Deborah Judd ,  Joseph Babiarz ,  Andrew Naughton ,  Mervin Wood ,  Anthony Debellis ,  Rong Xiong ,  Robert Detlefsen ,  Joseph Suhadolnik

IPC分类号： C08K5/34 ,  C08K5/48

CPC分类号： C07D239/91 ,  C07D239/74 ,  C07D239/86 ,  C07D249/20 ,  C07D265/22 ,  C07D405/04

摘要： The present invention relates to novel ultraviolet light absorbers of the benzoxazinone, oxanilide, benzylidene malonate, quinazoline and benzotriazole classes. The invention also relates to polymer and photographic compositions stabilized against the deleterious effects of light induced degradation which comprise the novel ultraviolet light absorbers.

公开(公告)号：US07148274B2

公开(公告)日：2006-12-12

申请号：US10764960

申请日：2004-01-26

申请人： Stephen D. Pastor ,  Andrew B. Naughton ,  Robert Detlefsen ,  Mervin G. Wood ,  Joseph Suhadolnik ,  Anthony DeBellis ,  Deborah DeHessa

发明人： Stephen D. Pastor ,  Andrew B. Naughton ,  Robert Detlefsen ,  Mervin G. Wood ,  Joseph Suhadolnik ,  Anthony DeBellis ,  Deborah DeHessa

IPC分类号： C08K5/3492 ,  C10L5/00

CPC分类号： C07D401/04 ,  C07D249/20 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D409/14

摘要： where R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1 and E2 are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium (II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.

摘要翻译： 其中R是芳基部分，例如苯基，萘基或联苯基，或被一个或多个三氟甲基，溴或氰基取代的苯基，和E 1和E 2是 独立地，氢，烷基，芳烷基等通过在苯并环的5-位被卤素原子取代的苯并三唑与芳基硼酸或酯在过渡金属催化剂如钯（ II）二乙酸酯。 式I的苯并三唑化合物作为汽车涂料和蜡烛蜡的稳定剂是特别有效的。

公开(公告)号：US06774238B2

公开(公告)日：2004-08-10

申请号：US10602094

申请日：2003-04-17

申请人： Stephen D. Pastor ,  Andrew B. Naughton ,  Robert Detlefsen ,  Mervin G. Wood ,  Joseph Suhadolnik ,  Anthony DeBellis ,  Deborah DeHessa

发明人： Stephen D. Pastor ,  Andrew B. Naughton ,  Robert Detlefsen ,  Mervin G. Wood ,  Joseph Suhadolnik ,  Anthony DeBellis ,  Deborah DeHessa

IPC分类号： C07D24920

CPC分类号： C07D401/04 ,  C07D249/20 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D409/14

摘要： Compounds of formula I or II where R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1 and E2 are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium(II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.

摘要翻译： 式I或II的化合物，其中R是芳基部分，例如苯基，萘基或联苯基，或被一个或多个三氟甲基，溴或氰基取代的苯基，E1和E2独立地是氢，烷基，芳烷基等 通过在过渡金属催化剂如二乙酸钯（II）的存在下，将苯并环的5-位被卤素原子取代的苯并三唑与芳基硼酸或酯反应。 式I的苯并三唑化合物作为汽车涂料和蜡烛蜡的稳定剂是特别有效的。

公开(公告)号：US07947832B2

公开(公告)日：2011-05-24

申请号：US12384849

申请日：2009-04-09

申请人： Mervin G. Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael P. DiFazio ,  Joseph E. Babiarz

发明人： Mervin G. Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael P. DiFazio ,  Joseph E. Babiarz

IPC分类号： C07D403/12 ,  C08K5/3492

CPC分类号： C07D211/94 ,  C07D401/14

摘要： Sterically hindered hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula (8)-(10) These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.

摘要翻译： 经受特定羟基取代的烷氧基胺稳定剂化合物通过某些主链与水具有亲水性而使其与水相容。 空间位阻胺例如具有式（8） - （10）这些化合物在稳定含水聚合物体系中对抗氧化，热和光化辐射的有害影响是特别有效的。 该化合物例如在稳定水性涂料，水性油墨，水性喷墨介质和光固化水性体系中是有效的。

公开(公告)号：US20090202725A1

公开(公告)日：2009-08-13

申请号：US12384840

申请日：2009-04-09

申请人： Mervin G. Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael P. DiFazio ,  Joseph E. Babiarz

发明人： Mervin G. Wood ,  Robert Detlefsen ,  James Galbo ,  Wanda Martin ,  Paul Kondracki ,  Michael P. DiFazio ,  Joseph E. Babiarz

IPC分类号： B05D5/00 ,  C07D401/14 ,  C07D401/12

CPC分类号： C07D211/94 ,  C07D401/14

摘要： Sterically hindered hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of formulae (5)-(7) These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.

摘要翻译： 经受特定羟基取代的烷氧基胺稳定剂化合物通过某些主链与水具有亲水性而使其与水相容。 空间位阻胺是例如式（5） - （7）这些化合物在稳定含水聚合物体系中抵抗氧化，热和光化辐射的有害影响方面特别有效。 该化合物例如在稳定水性涂料，水性油墨，水性喷墨介质和光固化水性体系中是有效的。