Silver halide emulsions with improved heat stability
    41.
    发明授权
    Silver halide emulsions with improved heat stability 失效
    具有改善的热稳定性的卤化银乳剂

    公开(公告)号:US5914226A

    公开(公告)日:1999-06-22

    申请号:US927866

    申请日:1997-09-11

    申请人: Roger Lok

    发明人: Roger Lok

    IPC分类号: G03C1/035 G03C1/09 G03C1/34

    CPC分类号: G03C1/09

    摘要: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride, said emulsion being in reactive association with a dithiolone 1-oxide compound represented by the following formula: ##STR1## wherein b is C(O), C(S), C(Se), CH.sub.2 or (CH.sub.2).sub.2, and R.sup.1 and R.sup.2 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, sulfo groups, or amino groups, or R.sup.1 and R.sup.2 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system; and a sulfinate compound.

    摘要翻译: 一种卤化银照相元件,其包含大于50摩尔%氯化银的卤化银乳剂,所述乳液与由下式表示的二硫醇酮1-氧化物化合物反应性缔合:其中b为C(O),C(S ),C(Se),CH 2或(CH 2)2,并且R 1和R 2独立地为H或脂族,芳族或杂环基团,烷氧基,羟基,卤素原子,芳氧基,烷硫基,芳硫基,酰基 磺酰基,酰氧基,羧基,氰基,磺基或氨基,或者R 1和R 2一起代表形成五元或六元环或多环系所必需的原子; 和亚磺酸盐化合物。

    Cubical grain silver iodochloride emulsions and processes for their
preparation
    42.
    发明授权
    Cubical grain silver iodochloride emulsions and processes for their preparation 失效
    立方颗粒碘化银乳剂及其制备方法

    公开(公告)号:US5736310A

    公开(公告)日:1998-04-07

    申请号:US651193

    申请日:1996-05-17

    CPC分类号: G03C1/015 G03C1/035 G03C1/34

    摘要: Radiation sensitive emulsions are disclosed comprised of silver iodochloride grains having three pairs of equidistantly spaced parallel {100} crystal faces and containing from 0.05 to 3 mole percent iodide, based on total silver, in a controlled, non-uniform iodide distribution forming a core containing at least 50 percent of total silver, a surface shell, and a sub-surface shell that contains a maximum iodide concentration and provides, when the emulsion is exposed to 390 nm electromagnetic radiation at 10.degree. K., stimulated fluorescent emissions in the range of from 450 to 470 nm and at 500, the stimulated fluorescent emission in the range of from 450 to 470 nm having a peak intensity more than twice the stimulated fluorescent emission intensity at 500 nm. The emulsion is prepared by a process wherein a) grains accounting for at least 50 percent of total silver forming the silver iodochloride grains are grown in the dispersing medium, (b) while employing the grains as substrates for further grain growth, locating crystal lattice variances in the grains by the incorporation of iodide to form a first shell having a higher local iodide concentration than any other grain portion, and (c) precipitating silver chloride onto the surface of the grains formed in step (b) to create a surface shell separating the first shell from the surface of the completed grains.

    摘要翻译: 公开的辐射敏感乳剂由具有三对等距间隔的平行{100}晶面的碘氯化银颗粒组成,并以受控的不均匀的碘分布形式含有基于总银的0.05至3摩尔%的碘化物,形成含有 总银的至少50%,表面壳和含有最大碘化物浓度的亚表面壳,当乳液暴露于10°K的390nm电磁辐射时,其刺激的荧光发射范围为 在450nm至470nm和500nm处,在450nm至470nm范围内的受激荧光发射峰强度大于500nm处的受激荧光发射强度的两倍。 通过以下方法制备乳液,其中a)在分散介质中生长构成形成碘氯化银粒子的总银的至少50%的晶粒,(b)当使用晶粒作为进一步晶粒生长的基底时,定位晶格方位 通过引入碘化物形成具有比任何其它颗粒部分更高的局部碘化物浓度的第一壳的晶粒,和(c)将氯化银沉淀到步骤(b)中形成的晶粒的表面上,以形成分离的表面壳 第一个壳从完成的谷物的表面。

    Heat stabilized silver chloride photographic emulsions containing
phosphine compounds
    43.
    发明授权
    Heat stabilized silver chloride photographic emulsions containing phosphine compounds 失效
    含有膦化合物的热稳定氯化银照相乳剂

    公开(公告)号:US5415992A

    公开(公告)日:1995-05-16

    申请号:US159354

    申请日:1993-11-30

    申请人: Roger Lok

    发明人: Roger Lok

    摘要: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride, said emulsion being in reactive association with a sulfur donating compound and a phosphine compound represented by Formulae I and II, and polymers having a repeating unit derived from the compounds of Formula I,Formula (I) R.sup.18 R.sup.19 R.sup.20 PFormula (II) R.sup.21 R.sup.22 P--A--PR.sup.23 R.sup.24wherein R.sup.18, R.sup.19, R.sup.20, R.sup.21, R.sup.22, R.sup.23, and R.sup.24 are independently alkyl, or aryl groups, or R.sup.18, R.sup.19, R.sup.20, R.sup.21, R.sup.22, R.sup.23, and R.sup.24 may combine to form a 5 or 6-membered ring , and wherein A is a divalent carbon linking group, and a method of making the silver chloride emulsion.

    摘要翻译: 一种卤化银照相元件,其包含大于50摩尔%氯化银的卤化银乳剂,所述乳液与供硫化合物和由式I和II表示的膦化合物反应结合,以及衍生自 式I,式(I)R 18 R 19 R 20 P式(II)R 21 R 22 P-A-PR 23 R 24的化合物,其中R 18,R 19,R 20,R 21,R 22,R 23和R 24独立地为烷基或芳基,或R 18,R 19,R 20, R 21,R 22,R 23和R 24可以结合形成5或6元环,其中A是二价碳连接基团,以及制备氯化银乳液的方法。

    Thiosulfonate-sulfinate stabilizers for photosensitive emulsions
    45.
    发明授权
    Thiosulfonate-sulfinate stabilizers for photosensitive emulsions 失效
    用于感光乳剂的硫代磺酸盐 - 亚磺酸盐稳定剂

    公开(公告)号:US5292635A

    公开(公告)日:1994-03-08

    申请号:US634407

    申请日:1990-12-27

    申请人: Roger Lok

    发明人: Roger Lok

    IPC分类号: G03C1/34 G03C1/09

    CPC分类号: G03C1/346

    摘要: A method for reducing speed change, or both speed change and fog growth, on aging in a photographic material composed of a silver chloride or silver bromochloride emulsion, by treating the emulsion with a thiosulfonate compound and a sulfinate compound, and the photographic emulsion and materials resulting from such treatment.

    摘要翻译: 通过用硫代磺酸盐化合物和亚磺酸盐化合物处理乳液,在由氯化银或溴氯化银乳剂组成的照相材料的老化时减少速度变化或速度变化和雾增长的方法,以及照相乳液和材料 由这种治疗引起。

    Divalent chalcogenide fog inhibiting agents for silver halide photography
    48.
    发明授权
    Divalent chalcogenide fog inhibiting agents for silver halide photography 失效
    用于卤化银摄影的二价硫族化物防雾剂

    公开(公告)号:US4607001A

    公开(公告)日:1986-08-19

    申请号:US719839

    申请日:1985-04-04

    IPC分类号: G03C1/34

    CPC分类号: G03C1/346

    摘要: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by aromatic tellurochalcogenides. The aromatic tellurochalcogenides can be initially incorporated in the photographic element as manufactured or during processing.

    摘要翻译: 公开了辐射敏感的卤化银照相元件,其通过芳香族碲化锑化物防止雾化。 芳香族碲化钴元素可以最初并入制造的或在加工过程中的照相元件中。

    Tellurium salt fog inhibiting agents for silver halide photography
    49.
    发明授权
    Tellurium salt fog inhibiting agents for silver halide photography 失效
    碲盐防雾剂用于卤化银摄影

    公开(公告)号:US4581330A

    公开(公告)日:1986-04-08

    申请号:US702545

    申请日:1985-02-19

    IPC分类号: G03C1/34 G03C5/305

    CPC分类号: G03C5/305 G03C1/34

    摘要: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by aromatic oxatellurazinium salts. The aromatic oxatellurazinium salts can be initially incorporated in the photographic element as manufactured or during processing.

    摘要翻译: 公开了辐射敏感的卤化银照相元件,其被芳族氧杂环唑烷鎓盐防雾。 芳族氧杂环唑烷鎓盐可以最初并入制造的或在加工过程中的照相元件中。