摘要:
A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride, said emulsion being in reactive association with a dithiolone 1-oxide compound represented by the following formula: ##STR1## wherein b is C(O), C(S), C(Se), CH.sub.2 or (CH.sub.2).sub.2, and R.sup.1 and R.sup.2 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, sulfo groups, or amino groups, or R.sup.1 and R.sup.2 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system; and a sulfinate compound.
摘要:
Radiation sensitive emulsions are disclosed comprised of silver iodochloride grains having three pairs of equidistantly spaced parallel {100} crystal faces and containing from 0.05 to 3 mole percent iodide, based on total silver, in a controlled, non-uniform iodide distribution forming a core containing at least 50 percent of total silver, a surface shell, and a sub-surface shell that contains a maximum iodide concentration and provides, when the emulsion is exposed to 390 nm electromagnetic radiation at 10.degree. K., stimulated fluorescent emissions in the range of from 450 to 470 nm and at 500, the stimulated fluorescent emission in the range of from 450 to 470 nm having a peak intensity more than twice the stimulated fluorescent emission intensity at 500 nm. The emulsion is prepared by a process wherein a) grains accounting for at least 50 percent of total silver forming the silver iodochloride grains are grown in the dispersing medium, (b) while employing the grains as substrates for further grain growth, locating crystal lattice variances in the grains by the incorporation of iodide to form a first shell having a higher local iodide concentration than any other grain portion, and (c) precipitating silver chloride onto the surface of the grains formed in step (b) to create a surface shell separating the first shell from the surface of the completed grains.
摘要:
A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride, said emulsion being in reactive association with a sulfur donating compound and a phosphine compound represented by Formulae I and II, and polymers having a repeating unit derived from the compounds of Formula I,Formula (I) R.sup.18 R.sup.19 R.sup.20 PFormula (II) R.sup.21 R.sup.22 P--A--PR.sup.23 R.sup.24wherein R.sup.18, R.sup.19, R.sup.20, R.sup.21, R.sup.22, R.sup.23, and R.sup.24 are independently alkyl, or aryl groups, or R.sup.18, R.sup.19, R.sup.20, R.sup.21, R.sup.22, R.sup.23, and R.sup.24 may combine to form a 5 or 6-membered ring , and wherein A is a divalent carbon linking group, and a method of making the silver chloride emulsion.
摘要翻译:一种卤化银照相元件,其包含大于50摩尔%氯化银的卤化银乳剂,所述乳液与供硫化合物和由式I和II表示的膦化合物反应结合,以及衍生自 式I,式(I)R 18 R 19 R 20 P式(II)R 21 R 22 P-A-PR 23 R 24的化合物,其中R 18,R 19,R 20,R 21,R 22,R 23和R 24独立地为烷基或芳基,或R 18,R 19,R 20, R 21,R 22,R 23和R 24可以结合形成5或6元环,其中A是二价碳连接基团,以及制备氯化银乳液的方法。
摘要:
The present invention relates to a photographic element comprising a silver halide emulsion, the emulsion comprising silver halide grains which contain an alkynylamine dopant. The presence of the alkynylamine dopant imparts to the photographic element the advantageous characteristic of increased sensitivity.
摘要:
A method for reducing speed change, or both speed change and fog growth, on aging in a photographic material composed of a silver chloride or silver bromochloride emulsion, by treating the emulsion with a thiosulfonate compound and a sulfinate compound, and the photographic emulsion and materials resulting from such treatment.
摘要:
Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by quaternized aromatic oxatellurazinium salts. The aromatic oxatellurazinium salts can be initially incorporated in the photographic element as manufactured or during processing.
摘要:
Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by quaternized aromatic oxatellurazinium salts. The aromatic oxatellurazinium salts can be initially incorporated in the photographic element as manufactured or during processing.
摘要:
Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by aromatic tellurochalcogenides. The aromatic tellurochalcogenides can be initially incorporated in the photographic element as manufactured or during processing.
摘要:
Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by aromatic oxatellurazinium salts. The aromatic oxatellurazinium salts can be initially incorporated in the photographic element as manufactured or during processing.
摘要:
Photographic silver halide emulsions show increased speed and reduced latent image fading when a compound of the following structure is incorporated: ##STR1## wherein: X is ##STR2## Y.sup.1 and Y.sup.2 individually represent hydrogen or an aromatic nucleus or together represent the atoms completing a fused aromatic nucleus;Z is ##STR3## R is hydrogen or lower alkyl of from 1 to 5 carbon atoms; and R.sup.1 is hydrogen or methyl.