Multi-modal vinyl ester resins
    41.
    发明授权
    Multi-modal vinyl ester resins 有权
    多元乙烯基酯树脂

    公开(公告)号:US07449525B2

    公开(公告)日:2008-11-11

    申请号:US11568600

    申请日:2005-05-06

    IPC分类号: C08F222/10

    摘要: Multi-modal vinyl ester resins having one or more of good fracture toughness, good processing viscosity, and low volatile organic compound emissions are provided. The multi-modal vinyl ester resins are the reaction product of a liquid or crystalline epoxy and an amorphous, solid epoxy, as determined at 25° C., with a vinyl carboxylic acid. The multi-modal vinyl ester resins may contain a reactive diluent, though generally, lower reactive diluent contents are required for such resins than for similar, commercially available vinyl ester resins.

    摘要翻译: 提供了具有良好的断裂韧性,良好的加工粘度和低挥发性有机化合物排放的一种或多种的多模态乙烯基酯树脂。 多模态乙烯基酯树脂是液体或结晶环氧树脂与25℃下测定的无定形固体环氧树脂与乙烯基羧酸的反应产物。 多模态乙烯基酯树脂可以含有反应性稀释剂,但是通常相对于类似的市售乙烯基酯树脂,这种树脂通常需要较低的反应性稀释剂含量。

    Air curing water base copolymers and method of preparation
    42.
    发明授权
    Air curing water base copolymers and method of preparation 失效
    空气固化水基共聚物及其制备方法

    公开(公告)号:US06177510B1

    公开(公告)日:2001-01-23

    申请号:US09290055

    申请日:1999-04-12

    申请人: John C. Saam

    发明人: John C. Saam

    IPC分类号: C08J300

    摘要: An aqueous dispersion comprising a copolymer which is the polymerization product of a mixture of vinylic monomers wherein from about 5% to about 90% by weight of the vinylic monomers are selected from co-esters of a drying oil acid and an unsaturated &agr;, &bgr;-polymerizable unsaturated carboxylic acid, contains from about 0.5% to about 50% by weight based on the weight of the copolymer of a hydrophobic ester or partial ester of a drying oil acid and a polyol. The copolymer polymerized in the presence of the hydrophobic ester or partial ester is characterized by a relatively low gel content, and by a relatively broad, multi-nodal, molecular weight distribution, including a low molecular weight component which acts as a transient plasticizer and coalescing agent. The aqueous dispersions can be formulated into quick drying coating compositions which form smooth protective films on various substrates, without requiring volatile coalescing agents.

    摘要翻译: 包含共聚物的水分散体,其是乙烯基单体的混合物的聚合产物,其中约5重量%至约90重量%的乙烯基单体选自干性油酸和不饱和的α,β- 基于干性油酸和多元醇的疏水酯或偏酯的共聚物的重量,含有约0.5%至约50%重​​量的可聚合不饱和羧酸。 在疏水酯或偏酯的存在下聚合的共聚物的特征在于相对低的凝胶含量,并且具有相对宽的多节分子量分布,包括作为瞬时增塑剂和聚结的低分子量组分 代理商 水性分散体可以配制成快干涂料组合物,其在各种底物上形成平滑的保护膜,而不需要挥发性聚结剂。