METHOD FOR THE REESTERIFICATION OR ESTERIFICATION OF SIDE CHAINS IN POLYMERS
    4.
    发明申请
    METHOD FOR THE REESTERIFICATION OR ESTERIFICATION OF SIDE CHAINS IN POLYMERS 失效
    聚合物中侧链的反应或纯化方法

    公开(公告)号:US20100062500A1

    公开(公告)日:2010-03-11

    申请号:US12095068

    申请日:2006-11-24

    申请人: Dietmar Haring

    发明人: Dietmar Haring

    IPC分类号: C12P7/64

    摘要: The present invention relates to a process for esterifying or transesterifying side chains in polymers, comprising the following steps a) preparing a copolymer obtainable by polymerization of aa) at least one (meth)acrylate of the general formula (I) as component A, in which R1 is H or CH3, and R2 is H or an alkyl radical which is optionally substituted by functional groups such as acryloyl, ether, amino, epoxy, halogen or sulfonic acid groups, and ab) at least one monomer of the general formula (II) as component B, in which R3 is as defined for R1, R4 is as defined for R2, and n=from 1 to 40, and b) esterifying or transesterifying the carboxyl group having the R4 radical with an alcohol in the presence of an enzyme which catalyzes the esterification or transesterification. The present invention further relates to the polymers as such and to their use.

    摘要翻译: 本发明涉及聚合物中侧链酯化或酯交换的方法,包括以下步骤:a)制备可通过aa)至少一种作为组分A的通式(I)的(甲基)丙烯酸酯聚合获得的共聚物, R1为H或CH3,R2为H或任选被官能团如丙烯酰基,醚,氨基,环氧基,卤素或磺酸基取代的烷基,和ab)至少一种通式( II)作为组分B,其中R 3如对R 1所定义,R 4如对R 2所定义,n = 1至40,和b)在醇存在下使醇与R 4基团的羧基酯化或酯交换 催化酯化或酯交换的酶。 本发明还涉及聚合物本身及其用途。

    Copolymer functionalized with an iodine atom, composition comprising it and treatment process
    5.
    发明申请
    Copolymer functionalized with an iodine atom, composition comprising it and treatment process 审中-公开
    用碘原子官能化的共聚物,包含它的组合物和处理方法

    公开(公告)号:US20050288410A1

    公开(公告)日:2005-12-29

    申请号:US11152338

    申请日:2005-06-15

    申请人: Céline Farcet

    发明人: Céline Farcet

    摘要: The present disclosure relates to novel copolymers functionalized with an iodine atom, and comprising at least two different monomers chosen from monomers of (meth)acrylic type. The disclosure also relates to a cosmetic or dermatological composition comprising, in a physiologically acceptable medium, at least one copolymer functionalized with an iodine atom and comprising at least two different monomers chosen from (meth)acrylic monomers. The disclosure also relates to a cosmetic process for making up or caring for keratin materials using the composition.

    摘要翻译: 本公开涉及用碘原子官能化的新型共聚物,并且包含至少两种选自(甲基)丙烯酸类单体的不同单体。 本公开还涉及化妆品或皮肤病学组合物,其在生理学上可接受的介质中包含至少一种用碘原子官能化并且包含至少两种选自(甲基)丙烯酸单体的不同单体的共聚物。 本公开还涉及使用该组合物来补充或照顾角蛋白材料的美容方法。

    NOVEL CATIONIC THICKENERS, FREE OF OIL AND SURFACTANTS, METHOD FOR PREPARING SAME AND COMPOSITION CONTAINING SAME
    7.
    发明申请
    NOVEL CATIONIC THICKENERS, FREE OF OIL AND SURFACTANTS, METHOD FOR PREPARING SAME AND COMPOSITION CONTAINING SAME 有权
    不含油和表面活性剂的新型立体稠化剂,其制备方法和包含其的组合物

    公开(公告)号:US20130197177A1

    公开(公告)日:2013-08-01

    申请号:US13878594

    申请日:2011-11-29

    IPC分类号: A61K8/81 C08F226/02

    摘要: Polyelectrolyte resulting from polymerization, for 100 mol %, of: a) a molar ratio ≧50% and ≦99% of monomer units originating from at least one cationic monomer; b) a molar ratio >1% and ≦50% of monomer units originating from at least one monomer including a fully or partially salified free weak acid function; c) optionally a molar ratio >0 mol % and ≦5 mol % of monomer units originating from at least one monomer of formula A-C(═O)—O—[(CH2—CH(R)—O]n—R (I), where n is, independently, a number from 1 to 50, A is a monovalent unsaturated aliphatic radical having 2 to 6 carbon atoms, R1 is a hydrogen atom, a methyl radical, or an ethyl radical, and R is a linear or branched, saturated or unsaturated aliphatic hydrocarbon radical having 8 to 30 carbon atoms; and d) optionally a molar ratio >0% and ≦1% of a diethylene or polyethylene cross-linking monomer.

    摘要翻译: 100mol%的聚合产生的聚电解质为:a)摩尔比≥50%和99%的源自至少一种阳离子单体的单体单元; b)摩尔比> 1%和50%来源于至少一种单体的单体单元,包括完全或部分成盐的游离弱酸功能; c)任选的摩尔比> 0mol%和5mol%的源自至少一种式AC(= O)-O - [(CH 2 -CH(R)-O] n R(I)单体的单体单元, 其中n独立地为1至50的数,A是具有2至6个碳原子的单价不饱和脂族基团,R 1是氢原子,甲基或乙基,R是直链或支链的, 具有8至30个碳原子的饱和或不饱和脂族烃基;和d)任选的摩尔比> 0%和1%的二亚乙基或聚乙烯交联单体。

    Adhesive composition and adhesion method
    8.
    发明授权
    Adhesive composition and adhesion method 有权
    粘合剂组合物和粘合方法

    公开(公告)号:US08273827B2

    公开(公告)日:2012-09-25

    申请号:US13122020

    申请日:2009-10-08

    摘要: Disclosed is an adhesive composition having adhesion properties, high-speed curing properties and moisture resistance. Also disclosed is an adhesion method. Specifically disclosed is a composition which comprises: a first preparation comprising (A) a nitrile-butadiene rubber, (B) a (meth)acrylic composition, (C) a compound having an enal structure, and (F) a radical polymerization initiator; and a second preparation comprising (A) the nitrile-butadiene rubber, (B) the (meth)acrylic composition, (D) a compound having an amine structure, and (E) a compound containing copper. Also disclosed is a composition which comprises: a first preparation comprising (A) a nitrile-butadiene rubber, (B) a (meth)acrylic composition, (D) a compound having an amine structure, and (F) a radical polymerization initiator; and a second preparation comprising (A) the nitrile-butadiene rubber, (B) the (meth)acrylic composition, (C) a compound having an enal structure, and (E) a compound containing copper.

    摘要翻译: 公开了具有粘合性,高速固化性和耐湿性的粘合剂组合物。 还公开了粘合方法。 具体公开的是一种组合物,它包括:(A)丁腈橡胶,(B)(甲基)丙烯酸组合物,(C)具有烯醛结构的化合物和(F)自由基聚合引发剂)的第一制剂; 和(A)腈 - 丁二烯橡胶,(B)(甲基)丙烯酸组合物,(D)具有胺结构的化合物和(E)含铜化合物的第二制剂。 还公开了一种组合物,其包括:第一制剂,其包含(A)丁腈橡胶,(B)(甲基)丙烯酸组合物,(D)具有胺结构的化合物和(F)自由基聚合引发剂; 和(A)腈 - 丁二烯橡胶,(B)(甲基)丙烯酸组合物,(C)具有烯醛结构的化合物和(E)含铜化合物的第二制剂。

    Process for esterifying or transesterifying side chains in polymers
    9.
    发明授权
    Process for esterifying or transesterifying side chains in polymers 失效
    在聚合物中酯化或酯交换侧链的方法

    公开(公告)号:US08273555B2

    公开(公告)日:2012-09-25

    申请号:US12095068

    申请日:2006-11-24

    摘要: Provided is a process for esterifying or transesterifying side chains in polymers, which involves esterifying or transesterifying the carboxyl group having the R4 radical of a copolymer obtained by polymerizing a (meth)acrylate of formula (I), and a monomer of formula (II): wherein R1 and R3 are independently H or CH3, R2 and R4 are independently H or an alkyl radical which is optionally substituted by functional groups such as acryloyl, ether, amino, epoxy, halogen or sulfonic acid groups, and n is from 1 to 40, with an alcohol in the presence of an enzyme which catalyzes the esterifying or transesterifying. Further provided is the esterified or transesterified polymer product and its use.

    摘要翻译: 本发明提供聚合物中侧链的酯化或酯交换的方法,该方法包括使通过聚合式(I)的(甲基)丙烯酸酯得到的共聚物的R4基团的羧基和式(II)的单体酯化或酯交换, :其中R 1和R 3独立地是H或CH 3,R 2和R 4独立地是H或任选被官能团如丙烯酰基,醚,氨基,环氧基,卤素或磺酸基取代的烷基,n是1〜 40,在催化酯化或酯交换的酶存在下用醇。 进一步提供酯化或酯交换聚合物产品及其用途。

    (METH)ACRYLATE POLYMER, COATING AGENT, METHOD FOR PRODUCING A COATING, AND COATED OBJECT
    10.
    发明申请
    (METH)ACRYLATE POLYMER, COATING AGENT, METHOD FOR PRODUCING A COATING, AND COATED OBJECT 审中-公开
    (METH)丙烯酸酯聚合物,涂料代理,生产涂料的方法和涂料

    公开(公告)号:US20120065322A1

    公开(公告)日:2012-03-15

    申请号:US13257178

    申请日:2010-03-02

    摘要: The present invention relates to a (meth)acrylate polymer for preparing a coating composition, where the (meth)acrylate polymer has a weight-average molecular weight in the range from 10 000 to 60 000 g/mol and the (meth)acrylate polymer comprises 0.5 to 40% by weight of units derived from (meth)acrylic monomers which in the alkyl radical have at least one double bond and 8 to 40 carbon atoms, 0.1 to 10% by weight of units derived from monomers containing acid groups, and 50 to 99.4% by weight of units derived from (meth)acrylates having 1 to 12 carbon atoms in the alkyl radical that have no double bonds or heteroatoms in the alkyl radical, and these (meth)acrylates having 1 to 12 carbon atoms in the alkyl radical are selected such that a polymer composed of these (meth)acrylates having 1 to 12 carbon atoms in the alkyl radical has a glass transition temperature of at least 40° C., based in each case on the weight of the (meth)acrylate polymer.The present invention further relates to a coating material comprising the stated polymer, and to a method of producing a coating. The present invention additionally describes a coated article comprising a coating obtainable by the method.

    摘要翻译: 本发明涉及一种用于制备涂料组合物的(甲基)丙烯酸酯聚合物,其中(甲基)丙烯酸酯聚合物的重均分子量在10000至60000g / mol范围内,(甲基)丙烯酸酯聚合物 包含0.5至40重量%的衍生自(甲基)丙烯酸单体的单元,其在烷基中具有至少一个双键和8至40个碳原子,0.1至10重量%的源自含酸基团的单元,以及 50〜99.4重量%的衍生自在烷基中不具有双键或杂原子的烷基中具有1至12个碳原子的(甲基)丙烯酸酯的单元,并且这些在(甲基)丙烯酸烷基酯中具有1至12个碳原子的(甲基)丙烯酸酯 选择烷基,使得由烷基中具有1至12个碳原子的(甲基)丙烯酸酯组成的聚合物的玻璃化转变温度至少为40℃,基于每种情况下的(甲基) 丙烯酸酯聚合物。 本发明还涉及包含所述聚合物的涂料,以及制备涂料的方法。 本发明另外描述了包含可通过该方法获得的涂层的涂覆制品。