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公开(公告)号：US4148975A
公开(公告)日：1979-04-10
申请号：US892655
申请日：1978-04-03
摘要： An improved lithium iodine battery, depolarizer therefor and method of making same in which the depolarizer comprises a pelletized particulate mixture of iodine, an organic polymer of either poly-2-vinylpyridine or poly-2-vinylquinoline and a charge transfer complex consisting of the selected organic polymer and iodine wherein the mixture contains from 3 to 30 parts of iodine for each part of total organic.
摘要翻译： 改进的锂碘电池及其去极化剂及其制造方法，其中去极化剂包括碘的颗粒状颗粒混合物，聚-2-乙烯基吡啶或聚-2-乙烯基喹啉的有机聚合物和由所选择的电荷转移络合物组成的电荷转移络合物 有机聚合物和碘，其中混合物对于总有机物的每一部分含有3至30份碘。
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42.发明授权
公开(公告)号：US4135519A
公开(公告)日：1979-01-23
申请号：US853136
申请日：1977-11-21
申请人： Wilson Greatbatch
发明人： Wilson Greatbatch
摘要： A cardiac pacer having an alkali metal-halogen cell comprising an alkali metal anode, preferably lithium, a solid alkali metal-halogen electrolyte and a cathode comprising a mixture of two halogens, for example iodine and bromine, the two halogens providing discharge of the cell at two different levels of cell output voltage. The two halogens are in different proportions by weight of the mixture thereby providing a two step output voltage-time characteristic. The second step or plateau in the output voltage characteristic provides an early warning of pacer battery exhaustion.
摘要翻译： 一种具有碱金属卤素电池的心脏起搏器，其包含碱金属阳极，优选锂，固体碱金属 - 卤素电解质和包含两种卤素如碘和溴的混合物的阴极，所述两种卤素提供电池的放电 在两个不同级别的电池输出电压。 两种卤素按混合物的重量不同，由此提供两步输出电压 - 时间特性。 输出电压特性的第二步或平台提供了电池耗尽的预警。
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公开(公告)号：US4128703A
公开(公告)日：1978-12-05
申请号：US812641
申请日：1977-07-05
CPC分类号： H01M6/182
摘要： A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium element and extending out from the casing, and a cathode comprising iodine-containing material in operative contact with both the casing and the lithium element. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The anode operative surface is provided with a coating of an organic electron donor material. The anode is enclosed within an insulator element within the casing and a ferrule having one end within the insulator and the other end extending from the casing.
摘要翻译： 一种锂 - 碘电池，包括导电材料的壳体，在壳体内包含锂元素的阳极，可操作地连接到锂元素并从壳体延伸出来的电导体，以及包含操作接触的含碘材料的阴极 与壳体和锂元素。 阳极电导体与电池的其余部分完全密封，并且壳体用作阴极集电器。 阳极工作表面设置有有机电子给体材料的涂层。 阳极被封装在壳体内的绝缘体元件内，并且套管具有在绝缘体内的一端，另一端从壳体延伸。
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公开(公告)号：US4071662A
公开(公告)日：1978-01-31
申请号：US647002
申请日：1976-01-07
摘要： A lithium-iodine cell comprising a cathode including a charge transfer complex of an organic donor component and iodine, an anode including a lithium element having a surface operatively contacting the charge transfer complex material, and a coating on the lithium surface of an organic electron donor material, preferably but not necessarily the organic donor component of the charge transfer complex. The organic electron donor material preferably comprises polyvinyl pyridine polymer and in particular two-vinyl pyridine polymer. A solution of two-vinyl pyridine polymer in benzene is brushed onto the anode lithium surface and then exposed to a desiccant. A number of coatings preferably are applied successively to provide a resulting or finished coating of increased thickness.
摘要翻译： 一种锂碘电池，其包含阴极，其包括有机供体组分和碘的电荷转移络合物，包含具有可操作地接触电荷转移络合物材料的表面的锂元素的阳极和有机电子给体的锂表面上的涂层 材料，优选但不一定是电荷转移络合物的有机供体组分。 有机电子给体材料优选包含聚乙烯基吡啶聚合物，特别是二乙烯基吡啶聚合物。 将二乙烯基吡啶聚合物在苯中的溶液刷在阳极锂表面上，然后暴露于干燥剂中。 优选连续施加多个涂层以提供增加厚度的所得或成品涂层。
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公开(公告)号：US4060672A
公开(公告)日：1977-11-29
申请号：US681642
申请日：1976-04-29
摘要： Electrochemical cells utilize crystalline chalcogen halides as solid eleclytes. Processes for the manufacture of the chalcogen halides and of the solid electrolyte cells are disclosed.
摘要翻译： 电化学电池使用结晶硫属卤化物作为固体电解质。 公开了用于制造硫属卤化物和固体电解质电池的方法。
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公开(公告)号：US3874929A
公开(公告)日：1975-04-01
申请号：US33810173
申请日：1973-03-05
申请人： WILSON GREATBACK LTD
发明人： GREATBATCH WILSON
摘要： A lithium-iodine cell comprising a casing of electrically conducting material, an anode including a lithium element within the casing, an electrical conductor operatively connected to the lithium member and extending out from the casing, and a cathode comprising iodine-containing material in contact with both the casing and the lithium member. The anode electrical conductor is completely sealed from the rest of the cell, and the casing serves as the cathode current collector. The anode conductor is positioned in a ferrule which is sealed at the end adjacent the anode with material which is non-reactive with iodine and which is provided with an hermetic seal at the other end.
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公开(公告)号：US3773557A
公开(公告)日：1973-11-20
申请号：US3773557D
申请日：1972-03-01
申请人： WURLITZER CO
发明人： MEAD R
CPC分类号： H01M6/182
摘要： A solid state battery construction is disclosed wherein the anode structure can be formed from one of the compounds selected from the group consisting of lithium, lithium and magnesium, lithium and calcium, or lithium, magnesium and calcium. The cathode is formed of conductive metal such as stainless steel and nickel engaging an ionic conductive layer formed of one or more of the compounds selected from the group consisting of rubidium iodide, cesium iodide, tetramethyl ammonium iodide and mixtures of iodine and non-ionic organic compounds such as pyrene or polyvinylpyrene or ion exchange resins such as polyvinylpyridine. The battery structure utilizes two layers of lithium or lithium compounds which sandwich a screen member of nickel to form the conductive contact with the anode.
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公开(公告)号：US3719746A
公开(公告)日：1973-03-06
申请号：US3719746D
申请日：1970-12-08
发明人： JOHNSTON W
摘要： An aqueous process for the preparation of a solid ionically conductive composition of matter having the formula MAg4I5 in which M is Rb, K, NH4, Cs, or a combination of these, Cs being present only as a minor constituent of M, comprising preparing a substantially saturated solution of MI in water, intimately admixing four molar equivalents of AgI with the MI solution to effect reaction between the MI and AgI, and removing the water to recover MAg4I5 as the synthesized ionically conductive composition.
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公开(公告)号：US3701685A
公开(公告)日：1972-10-31
申请号：US3701685D
申请日：1970-07-21
发明人： ERVIN GUY
CPC分类号： H01M4/58 , H01M6/182 , Y10T29/417
摘要： A SPRAYED-IN-PLACE SOLID STATE ELECTRIC CELL ON A SUBSTRATE SURFACE, THE CELL CONSISTING OF OVERLYING FILMS OF ANODE, SOLID ELECTROLYTE, AND CATHODE. THE CELL IS FORMED BY SUCCESSIVELY SPRAYING A SILVER-CONTAINING ANODE, A SILVER-ION-CONDUCTING SOLID ELECTROLYTE, AND A TELLURIUM TETRAIODIDE-COMPLEXED CATHODE, USING AN INERT ORGANIC SOLVENT, PREFERABLY ACETONE.
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50.发明授权PROCESS FOR PREPARING LITHIUM COMPOUNDS OF THE FORMULA LiMF{11 {0 WHEREIN M IS ARSENIC OR ANTIMONY 失效用于制备公式LiMF的锂化合物的方法{11 {0，因为原子性或抗原性
公开(公告)号：US3655332A
公开(公告)日：1972-04-11
申请号：US3655332D
申请日：1970-06-15
申请人： FOOTE MINERAL CO
CPC分类号： H01M6/182 , C01G28/004 , C01G30/002 , C01P2006/80
摘要： Lithium compounds of the formula LiMF6 wherein M is arsenic or antimony are prepared by a metathesis reaction in an inert organic solvent between lithium tetrafluoroborate and an alkali metal compound of the formula ZMF6, wherein Z is potassium or sodium and M is as defined above.
摘要翻译： 其中M为砷或锑的式LiMF 6的锂化合物通过在四氟硼酸锂与式ZMF6的碱金属化合物之间的惰性有机溶剂中的复分解反应制备，其中Z为钾或钠，M如上所定义。
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