摘要:
Fire resistant glass fiber products are produced by coating the glass fibers with at least one nitrogen containing compound and at least 10 weight percent of at least one boron containing compound, drying the glass fibers and curing a binder that is in the coating. The nitrogen containing compound(s) are present in sufficient amounts that there is at least one mol or atom of nitrogen present for each mol or atom of boron present in the boron containing compound(s). When the product is exposed to a fire or high temperatures, such as about 1000 degrees F. or higher, the nitrogen released from the nitrogen containing compound(s) reacts with boron or boron oxide to form a sheath of refractory material around the fibers that protects the fibers and allows the fibers to maintain integrity to higher temperatures and/or for longer times than untreated fibers.
摘要:
Fire resistant glass fiber products are produced by coating the glass fibers with at least one nitrogen containing compound and at least 10 weight percent of at least one boron containing compound, drying the glass fibers and curing a binder that is in the coating. The nitrogen containing compound(s) are present in sufficient amounts that there is at least one mol or atom of nitrogen present for each mol or atom of boron present in the boron containing compound(s). When the product is exposed to a fire or high temperatures, such as about 1000 degrees F. or higher, the nitrogen released from the nitrogen containing compound(s) reacts with boron or boron oxide to form a sheath of refractory material around the fibers that protects the fibers and allows the fibers to maintain integrity to higher temperatures and/or for longer times than untreated fibers.
摘要:
Flame-retardant treated cotton/thermoplastic fiber blend fabrics have been discovered which have extended wear life and retain their flame-retardant treatment for the life of the garment.
摘要:
A process and product obtained thereby are disclosed wherein a cellulosic textile material is impregnated with an aqueous solution of a condensation product of tetrakis(hydroxymethyl)phosphonium sulfate and urea, partially dried, impregnated with a thickened solution of ammonium hydroxide, rolled and stored in a container, unrolled, rinsed with water and dried to obtain durable flame retardance.
摘要:
An improved apparatus and process for imparting durable flame retardancy to textile materials wherein said material is impregnated with a solution having a poly(hydroxymethyl) phosphonium cation content of from about 10 to about 60 percent by weight, dried to a moisture content of from about 0 to about 8 percent, aerated by passing air through the dried material, cured by polymerizing the monomer on and in the cellulose material with exposure in an enclosed chamber to an atmosphere containing gaseous ammonia and thereafter contacting with water, the improvement comprising, impregnating said material with said solution containing poly(hydroxymethyl) phosphonium cation having a pH of from about 2 to about 9, and after contacting said material with said water, further exposing said material to an atmosphere containing gaseous ammonia.
摘要:
Phosphorus- and nitrogen-containing polymers, solubilized by hydroxymethylphosphonium salts and formaldehyde, were allowed to react with phenol, alkyl substituted phenols, or halogen substituted phenols which contain one or more hydrogens ortho or para to the phenolic hydroxyl group to (a) prepare flame-resistant polymers and (b) prepare flame-, glow-, wrinkle-, and shrink-resistant woven and knit textiles which contain 25% or more cellulosic fibers.
摘要:
A process for rendering cellulose and cellulose containing fabrics fire resistant by first impregnating the fibers with an aminoplast resin and polymerizing the resin while the fibers are wet and swollen. Thereafter, the fabric is impregnated with tetrakis (hydroxymethyl) phosphonium hydroxide, cured, washed and dried. The fabric obtained from this process possesses high fire-retardency values, soft hand, and tensile values similar to that of the untreated fabric.
摘要:
Fibrous material such as cotton cloth is rendered flame retardant by treating the material with cyanamide and at least one halomethyl phosphonic acid represented by the structural formula:
wherein R1 represents a monovalent radical such as chloro or bromo and R2 represents a monovalent radical such as hydrogen or methyl. Durability of the flame retardancy to repeated hard water washing may be improved through a subsequent treatment with Nmethylol compounds such as methylolated melamine precondensate. A particularly high degree of flame retardancy is imparted to mercerized cotton cloth.
摘要:
A flammable substrate, especially a cellulosic substrate such as cotton, is rendered flame-retardant by treatment with (1) a bis(epoxyalkyl) methylphosphonate such as bis(2,3-epoxypropyl) methylphosphonate or bis(2,3-epoxypropyl) chloromethylphosphonate, and (2) an organic nitrogen-containing compound, such as urea or N2, N4, N6-tris(hydroxymethyl)melamine. A treatment which is resistant to laundering is obtained when at least the phosphonate is insolubilized by polymerization on the surface of the substrate and/or reaction with the substrate. When a halomethylphosphonate is employed, the phosphorus content of the treated substrate can be increased by further treatment with a tris(haloalkyl) phosphite and/or a trialkyl phosphite.