摘要:
In a process for manufacturing unsaturated polyester resins which comprises (A) a stage of reacting a dialkyl terephthalate with a polyhydric alcohol in the presence of an interesterification catalyst, (B) a stage of reacting the reaction product obtained at the stage (A) with an unsaturated dicarboxylic acid, one or more polyhydric alcohols and optionally a saturated dicarboxylic acid to produce an unsaturated alkyd resin and (C) a stage of dissolving the unsaturated alkyd resin obtained at the stage (B) in a vinyl monomer, the reaction at the stage (A) or (B) is carried out in the coexistence of a hydroquinone and a phosphite.
摘要:
Graft copolymers are prepared by the in situ polymerization of phosphorus or phosphorus and halogen containing monomers in the presence of a free radical catalyst in a polyol containing from about 1.0 to about 2.5 moles of unsaturated per mole of polyol.
摘要:
A PROCESS FOR PREPARATION OF COPOLYMERIZABLE COMPOSITIONS COMPRISING REACTING MALEIC ANHDRIDE WITH ONE OR MORE POLYHYDROXYLATED COMPOUNDS IN THE RATIO OF 1 MOLE MALEIC ANHDRIDE PER HYDROXYL GROUP OF THE RANGE OF Y LATED COMPOUNDS AT A TEMPERATURE WITHIN THE RANGE OF 50-100* C. UNTIL A HYDROXYL NUMBER OF 20 OR BELOW IS REACHED AND THEREAFTER ADDING AT A TEMPERATURE WITHIN ONE RANGE OF ROOM TEMPERATURE TO 100* C. OF AT LEAST ONE CROSS-LINKING VINYL MONOMER IN THE PRESENCE OF A POLYMERIZATION INHIBITOR.
摘要:
A RADIATION-CURABLE PAINT IS PROVIDED BY MIXING AN ALIPHA-BETA OLEFINICALLY UNSATURATED SILOXANE. THE RESIN ALPHA-BETA OLEFINICALLY UNSATURATED SILOXANE. THE RESIN MAY BE ANY ALPHA-BETA OLEFINICALLY UNSATURATED POLYESTER HAVING BETWEEN ABOUT 0.5 AND ABOUT 5 UNITS OF ALPHA-BETA OLEFINIC UNSATURATION PER 1,000 UNITS MOLECULAR WEIGHT. BOTH MALEIC TYPE AND ACRYLIC TYPE UNSATURATION ARE ILLUSTRATE. IN ONE EMBODIMENT, THE POLYESTER IS THE COMMON, CONVENTIONAL POLYESTER FORMED FROM MELEIC ANHYDRIDE, A GLYCOL, AND RING TYPE ANHYDRIDE, E.G., PHTHALIC ANHYDEIDE, A GLYCOL, AND AN AROMATIC OR SATURATED ANHYDEIDE, E.G., PHTHALIC ANHYDRIDE, TETRAHYDROPHTHALIANHYDDRIDE, ETC. IN ANOTHER EMBODIMENT, A SATURATED POLYESTER IS REACTED WITH A DIISOCYANATE AND THE PRODUCT REACTED WITH A HYDROXYALKYL ACRYLATE. IN ANOTHER EMBODIMENT, THE POLYESTER IS A SILOXANE-MODIFIED POLYESTER. THE UNSATURATED SILOXANE COMPONENT IS THE REACTION PRODUCT OF AT LEAST TWO MOLAR PARTS OF A MONOMERIC, MONOHYDROXY ESTER OF AN ALPHA-BETA OLEFINICALLY UNSATURATED MONOCARBOXYLIC ACID, E.G., ACRYLATES, METHACRYLATES, CROTONATES, CINNAMATES, WITH ONE MOLAR PART OF A SILOXANE HAVING AT LEAST TWO SILICON ATOMS WITH ONE VALENCE SATIFIED BY A HYDROXYL GROUP OR AN ALKOXY GROUP; THE REACTION IS A CONVENTIONAL CONDENSATION REACTION. VINYL MONOMERS MAY ALSO BE INCLUDED IN THE PAINT DISPERSION.
摘要:
A polyester resin obtained by the polycondensation from a hydrogenated polydiene having two ester conjunction forming functions at the ends of a chain thereof and an organic compound having at least one function capable of forming ester conjunction with said forming function. The present disclosure is also directed to a method of manufacturing said polyester resins and polyesters compositions produced thereby.
摘要:
This invention relates to brominated polyesters, based on diols and as co-reactants a brominated maleic acid, a brominated tetrahydrophthalic acid, anhydrides or brominated monomeric esters of the anhydrides thereof, which are substantially free of dibromosuccinate and dibromohexahydrophthalate groups, contain bromine end groups and possess excellent flame-retardant properties, excellent thermal stability, excellent resistivity to ultraviolet light and can be used as flame-retardant plasticizers and when containing unsaturated groups, derived from nonhalogenated unsaturated polycarboxylic acids, can be used in molding applications to form aesthetically attractive thermoset articles characterized by excellent chemical, physical and electrical properties.