Method of producing polyarylene sulfide

    公开(公告)号:US10647817B2

    公开(公告)日:2020-05-12

    申请号:US15761120

    申请日:2016-09-30

    IPC分类号: C08G75/025 C08G75/0209

    摘要: The present invention is to provide a method that can produce polyarylene sulfide having a high viscosity at a high yield. The method of producing polyarylene sulfide according to an embodiment of the present invention includes: a preparation step of preparing a mixture containing an organic amide solvent, a sulfur source, a dihalo aromatic compound, and an alkali metal hydroxide; a first-stage polymerization step of initiating a polymerization reaction by heating the mixture and producing a prepolymer until a pH of a reaction system reaches a range of 10 to 11; and a second-stage polymerization step of continuing the polymerization reaction.

    METHOD FOR PRODUCING GRANULAR POLYARYLENE SULFIDE AND GRANULAR POLYARYLENE SULFIDE

    公开(公告)号:US20200024402A1

    公开(公告)日:2020-01-23

    申请号:US16481721

    申请日:2018-02-05

    IPC分类号: C08G75/0209 C08G75/0254

    摘要: To provide a method for producing granular polyarylene sulfide (hereinafter, PAS), the method capable of providing granular PAS having high particle strength and low melt viscosity in high yield without using special additives and the like; and granular PAS.A method according to the present invention is a method for producing granular PAS having a melt viscosity of from 1 to 30 Pa.s, which is measured at a temperature of 310° C. and a shear rate of 1216/s, by polymerizing a sulfur source and a dihalo aromatic compound in an organic amide solvent.

    METHOD OF PRODUCING POLYARYLENE SULFIDE
    45.
    发明申请

    公开(公告)号:US20190367682A1

    公开(公告)日:2019-12-05

    申请号:US16099587

    申请日:2018-02-05

    IPC分类号: C08G75/0259 C08G75/0209

    摘要: The production method of the present invention includes: a supplying step of supplying reaction raw materials to at least one of a plurality of reaction vessels mutually communicated through a gas phase; a polymerizing step of carrying out a polymerization reaction; and a step of removing at least some of the water present in the reaction vessels. Each of the steps is carried out in parallel, and a reaction mixture is transferred sequentially between the reaction vessels. The total amount of water contained in the reaction raw materials in at least one of the reaction vessels to which the reaction raw materials are supplied is 3 moles or more per mole of the sulfur source, and the internal temperature of at least one of the reaction vessels to which the reaction raw materials are supplied is from 180° C. to 300° C.

    METHOD OF PRODUCING POLYARYLENE SULFIDE
    46.
    发明申请

    公开(公告)号:US20190367679A1

    公开(公告)日:2019-12-05

    申请号:US16099538

    申请日:2018-02-05

    IPC分类号: C08G75/0209 C08G75/0259

    摘要: The production method of the present invention includes: a supplying step of supplying reaction raw materials to at least one of a plurality of reaction vessels that mutually communicate through a gas phase; a polymerizing step of carrying out a polymerization reaction; and a step of removing at least some of the water present in the reaction vessels. Each of the steps is carried out in parallel, and a reaction mixture is transferred sequentially between the reaction vessels. The amount of water contained in the reaction mixture in at least one of the reaction vessels is from 0.1 moles to less than 3 moles per mole of a sulfur source, and the total amount of water contained in the reaction raw materials that are supplied is 3 moles or more per mole of the sulfur source.

    Polyphenylene sulfide resin composition and method of manufacturing same

    公开(公告)号:US10294330B2

    公开(公告)日:2019-05-21

    申请号:US15748584

    申请日:2016-07-22

    摘要: A polyphenylene sulfide resin composition includes a polyphenylene sulfide resin (a) of 90 to 50% by weight and a polyphenylene sulfide resin (b) and/or a polyphenylene sulfide resin (c) of the total of 10 to 50% by weight blended with the polyphenylene sulfide resin (a), relative to the total of the polyphenylene sulfide resins (a) to (c) as 100% by weight, in which the polyphenylene sulfide resin composition has a change rate of viscosity of 1.5 times or less when the composition is heated at 320° C. for 5 hours.

    METHOD OF PRODUCING POLYARYLENE SULFIDE
    48.
    发明申请

    公开(公告)号:US20180265636A1

    公开(公告)日:2018-09-20

    申请号:US15761120

    申请日:2016-09-30

    IPC分类号: C08G75/025 C08G75/0209

    CPC分类号: C08G75/025 C08G75/0209

    摘要: The present invention is to provide a method that can produce polyarylene sulfide having a high viscosity at a high yield. The method of producing polyarylene sulfide according to an embodiment of the present invention includes: a preparation step of preparing a mixture containing an organic amide solvent, a sulfur source, a dihalo aromatic compound, and an alkali metal hydroxide; a first-stage polymerization step of initiating a polymerization reaction by heating the mixture and producing a prepolymer until a pH of a reaction system reaches a range of 10 to 11; and a second-stage polymerization step of continuing the polymerization reaction.

    Polyarylene sulfide production method and polyarylene sulfide production apparatus

    公开(公告)号:US09908974B2

    公开(公告)日:2018-03-06

    申请号:US15303032

    申请日:2015-04-21

    摘要: The present invention provides a production method and a production apparatus for a polyarylene sulfide (PAS), thus the formation of a floating polymer and the leakage of the floating polymer to the outside of the vessel in a washing step are prevented, to achieve steady production of the polymer with high quality, to improve the yield of the polymer and to reduce environmental load, wherein the floating polymer refers to a particles of the polymer which are floating on the surface of a washing solution, in the upper part of the inside of a washing vessel, as a result of the adhesion of a gas onto the surface of the particles of the polymer.The present invention provides a production method for a PAS comprising step (I), performing polymerization, step (II), separating and collecting a polymer, step (III), washing a slurry, and step (IV), collecting the polymer after washing, wherein an aqueous medium is sprayed onto a PAS floating on the surface of the aqueous washing solution in the upper part of the inside of the washing vessel in step (III) (step (IIIa), washing a slurry using a counter current, and/or step (IIIb), treating a slurry with acid using a counter current, or the like); and a production apparatus for a PAS comprising a washing device (counter current washing device and/or a counter current contact/acid treatment device or the like) having an aqueous medium spray means.