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公开(公告)号:US20210226220A1
公开(公告)日:2021-07-22
申请号:US17225570
申请日:2021-04-08
IPC分类号: H01M4/62 , C08G75/0209 , H01M4/131 , H01M4/50 , H01M4/58 , H01M4/06 , H01M6/18 , H01M4/36 , H01M10/054 , H01M10/26 , H01M4/38 , H01M4/04 , H01M4/48 , H01M4/24 , H01M10/0565
摘要: The invention features an electrochemical cell having an anode and a cathode; wherein at least one of the anode and cathode includes a solid ionically conducting polymer material that can ionically conduct hydroxyl ions.
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公开(公告)号:US20200231784A1
公开(公告)日:2020-07-23
申请号:US16634175
申请日:2017-08-02
发明人: Raleigh L. DAVIS , Keshav S. GAUTAM
IPC分类号: C08K7/14 , C08G75/0209 , C08G65/40 , C08G63/183
摘要: Described herein are reinforced thermoplastic polymer compositions including a flat, low-dielectric glass (“D-glass”) fiber. D-glass fiber compositions with a flat morphology provide for polymer compositions having significantly reduced shrinkage and excellent mechanical and dielectric performance. While the flat D-glass fibers can be desirably incorporated into polyester polymers, poly(aryl ether sulfone) polymers, poly(aryl ether ketone) polymers and a polyphenylene sulfide polymers.
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公开(公告)号:US10647817B2
公开(公告)日:2020-05-12
申请号:US15761120
申请日:2016-09-30
申请人: Kureha Corporation
发明人: Akihiro Konno , Ken-Ichi Takaki , Haruki Mokudai , Hiroyuki Sato
IPC分类号: C08G75/025 , C08G75/0209
摘要: The present invention is to provide a method that can produce polyarylene sulfide having a high viscosity at a high yield. The method of producing polyarylene sulfide according to an embodiment of the present invention includes: a preparation step of preparing a mixture containing an organic amide solvent, a sulfur source, a dihalo aromatic compound, and an alkali metal hydroxide; a first-stage polymerization step of initiating a polymerization reaction by heating the mixture and producing a prepolymer until a pH of a reaction system reaches a range of 10 to 11; and a second-stage polymerization step of continuing the polymerization reaction.
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公开(公告)号:US20200024402A1
公开(公告)日:2020-01-23
申请号:US16481721
申请日:2018-02-05
申请人: Kureha Corporation
发明人: Akihiro KONNO , Ken-ichi TAKAKI
IPC分类号: C08G75/0209 , C08G75/0254
摘要: To provide a method for producing granular polyarylene sulfide (hereinafter, PAS), the method capable of providing granular PAS having high particle strength and low melt viscosity in high yield without using special additives and the like; and granular PAS.A method according to the present invention is a method for producing granular PAS having a melt viscosity of from 1 to 30 Pa.s, which is measured at a temperature of 310° C. and a shear rate of 1216/s, by polymerizing a sulfur source and a dihalo aromatic compound in an organic amide solvent.
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公开(公告)号:US20190367682A1
公开(公告)日:2019-12-05
申请号:US16099587
申请日:2018-02-05
申请人: Kureha Corporation
发明人: KENJI SUZUKI , MICHIHISA MIYAHARA , HIROSHI SAKABE
IPC分类号: C08G75/0259 , C08G75/0209
摘要: The production method of the present invention includes: a supplying step of supplying reaction raw materials to at least one of a plurality of reaction vessels mutually communicated through a gas phase; a polymerizing step of carrying out a polymerization reaction; and a step of removing at least some of the water present in the reaction vessels. Each of the steps is carried out in parallel, and a reaction mixture is transferred sequentially between the reaction vessels. The total amount of water contained in the reaction raw materials in at least one of the reaction vessels to which the reaction raw materials are supplied is 3 moles or more per mole of the sulfur source, and the internal temperature of at least one of the reaction vessels to which the reaction raw materials are supplied is from 180° C. to 300° C.
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公开(公告)号:US20190367679A1
公开(公告)日:2019-12-05
申请号:US16099538
申请日:2018-02-05
申请人: Kureha Corporation
发明人: Kenji SUZUKI , Michihisa MIYAHARA , Hiroshi SAKABE
IPC分类号: C08G75/0209 , C08G75/0259
摘要: The production method of the present invention includes: a supplying step of supplying reaction raw materials to at least one of a plurality of reaction vessels that mutually communicate through a gas phase; a polymerizing step of carrying out a polymerization reaction; and a step of removing at least some of the water present in the reaction vessels. Each of the steps is carried out in parallel, and a reaction mixture is transferred sequentially between the reaction vessels. The amount of water contained in the reaction mixture in at least one of the reaction vessels is from 0.1 moles to less than 3 moles per mole of a sulfur source, and the total amount of water contained in the reaction raw materials that are supplied is 3 moles or more per mole of the sulfur source.
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公开(公告)号:US10294330B2
公开(公告)日:2019-05-21
申请号:US15748584
申请日:2016-07-22
发明人: Hidenobu Takao , Shu Kaiho , Shunsuke Horiuchi
IPC分类号: C08K3/08 , C08L81/02 , C08G75/0209
摘要: A polyphenylene sulfide resin composition includes a polyphenylene sulfide resin (a) of 90 to 50% by weight and a polyphenylene sulfide resin (b) and/or a polyphenylene sulfide resin (c) of the total of 10 to 50% by weight blended with the polyphenylene sulfide resin (a), relative to the total of the polyphenylene sulfide resins (a) to (c) as 100% by weight, in which the polyphenylene sulfide resin composition has a change rate of viscosity of 1.5 times or less when the composition is heated at 320° C. for 5 hours.
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公开(公告)号:US20180265636A1
公开(公告)日:2018-09-20
申请号:US15761120
申请日:2016-09-30
申请人: Kureha Corporation
发明人: AKIHIRO KONNO , KEN-ICHI TAKAKI , HARUKI MOKUDAI , HIROYUKI SATO
IPC分类号: C08G75/025 , C08G75/0209
CPC分类号: C08G75/025 , C08G75/0209
摘要: The present invention is to provide a method that can produce polyarylene sulfide having a high viscosity at a high yield. The method of producing polyarylene sulfide according to an embodiment of the present invention includes: a preparation step of preparing a mixture containing an organic amide solvent, a sulfur source, a dihalo aromatic compound, and an alkali metal hydroxide; a first-stage polymerization step of initiating a polymerization reaction by heating the mixture and producing a prepolymer until a pH of a reaction system reaches a range of 10 to 11; and a second-stage polymerization step of continuing the polymerization reaction.
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公开(公告)号:US10010857B2
公开(公告)日:2018-07-03
申请号:US15512983
申请日:2015-09-18
申请人: Kureha Corporation
IPC分类号: C08G75/14 , B01J19/24 , C08G75/0209 , C08G75/0263 , C08G75/0281
CPC分类号: B01J19/2415 , B01J4/001 , B01J19/006 , B01J19/0066 , B01J19/18 , B01J2219/00768 , B01J2219/00779 , C08G75/02 , C08G75/0209 , C08G75/0263 , C08G75/0281 , C08G75/14 , C08G85/00
摘要: The present invention provides an a polyarylene sulfide (PAS) production device provided with a supply tube for loading corrosive materials such as a strong alkali into a reaction vessel, wherein prescribed amounts of various raw materials or the like can be accurately loaded into the reaction vessel without causing decreases in production efficiency due to the replacement of the supply tube or the repair of the reaction vessel in response to the corrosion of the supply tube or the like.The present invention is a production device, and a PAS production device, in particular, provided with a reaction vessel equipped with one or a plurality of supply tubes, at least one of the supply tubes having an insert pipe, which is preferably detachable, to be inserted into an outer supply tube; and a tip opening of the insert pipe being positioned further inward than an inside wall of the reaction vessel.
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公开(公告)号:US09908974B2
公开(公告)日:2018-03-06
申请号:US15303032
申请日:2015-04-21
申请人: Kureha Corporation
IPC分类号: C08G75/04 , C08G75/0281 , C08G75/0254 , C08G75/0213 , B01D29/11 , B01D29/66 , B08B3/04 , C08G75/0209 , C08G75/0259
CPC分类号: C08G75/0281 , B01D29/11 , B01D29/66 , B08B3/04 , C08G75/0209 , C08G75/0213 , C08G75/0254 , C08G75/0259 , C08G75/04
摘要: The present invention provides a production method and a production apparatus for a polyarylene sulfide (PAS), thus the formation of a floating polymer and the leakage of the floating polymer to the outside of the vessel in a washing step are prevented, to achieve steady production of the polymer with high quality, to improve the yield of the polymer and to reduce environmental load, wherein the floating polymer refers to a particles of the polymer which are floating on the surface of a washing solution, in the upper part of the inside of a washing vessel, as a result of the adhesion of a gas onto the surface of the particles of the polymer.The present invention provides a production method for a PAS comprising step (I), performing polymerization, step (II), separating and collecting a polymer, step (III), washing a slurry, and step (IV), collecting the polymer after washing, wherein an aqueous medium is sprayed onto a PAS floating on the surface of the aqueous washing solution in the upper part of the inside of the washing vessel in step (III) (step (IIIa), washing a slurry using a counter current, and/or step (IIIb), treating a slurry with acid using a counter current, or the like); and a production apparatus for a PAS comprising a washing device (counter current washing device and/or a counter current contact/acid treatment device or the like) having an aqueous medium spray means.
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