STABILIZED N,N-DIETHYL-P-PHENYLENEDIAMINE SOLUTION AND METHOD FOR DETECTING CHLORINE

    公开(公告)号:US20240219309A1

    公开(公告)日:2024-07-04

    申请号:US18090163

    申请日:2022-12-28

    Applicant: HACH COMPANY

    Inventor: Douglas ROYER

    CPC classification number: G01N21/78 G01N33/18

    Abstract: A reagent for chlorine analysis includes N,N-diethyl-p-phenylenediamine (DPD), an inorganic chloride salt at a concentration of 0.5 M or more, and water. Additionally, a method for detecting chlorine in an aqueous sample includes subjecting a test sample to photometry. The test sample includes the aqueous sample; and a DPD reagent that includes DPD, an inorganic chloride salt at a concentration of 0.5 M or more, and water. The reagent and detection method can be used with minimal or no strong acids.

    Zinc measurement
    52.
    发明授权

    公开(公告)号:US12019021B2

    公开(公告)日:2024-06-25

    申请号:US16883595

    申请日:2020-05-26

    Applicant: Hach Company

    CPC classification number: G01N21/643 G01N2021/6439

    Abstract: An embodiment provides a method for measuring zinc in a solution, including: preparing an indicator solution; introducing the indicator solution to a solution, wherein the solution contains an amount of zinc and the introducing causes a change in fluorescence of the solution in response to the indicator solution reacting with the zinc; and measuring the amount of zinc in the solution by measuring a change in intensity of the fluorescence. Other aspects are described and claimed.

    DIFFERENTIAL PROBE WITH LOW-SLOPE COMPONENT
    54.
    发明公开

    公开(公告)号:US20230213469A1

    公开(公告)日:2023-07-06

    申请号:US17569076

    申请日:2022-01-05

    Applicant: Hach Company

    CPC classification number: G01N27/302 G01N27/301 G01N27/333

    Abstract: An embodiment provides a method for measuring an analyte of a sample, including: introducing a sample to a sample region of a measurement device; the measurement device comprising: a measurement electrode and a ground electrode contacting the sample; a low-slope reference electrode in a reference electrode assembly having an electrolyte solution, wherein the electrolyte solution is in contact with the low-slope reference electrode; wherein the electrolyte solution is electrically coupled to the sample via at least one junction; and measuring a first potential between the measurement electrode and the ground electrode; measuring a second potential between the low-slope reference electrode and the ground electrode; determining an analyte in the sample by comparing the first potential and the second potential. Other aspects are described and claimed.

    Zinc and copper measurement
    55.
    发明授权

    公开(公告)号:US11549884B2

    公开(公告)日:2023-01-10

    申请号:US17020154

    申请日:2020-09-14

    Applicant: Hach Company

    Abstract: An embodiment provides a method for measuring zinc and copper in an aqueous sample, including: reducing an aqueous sample containing an amount of zinc and an amount of copper with a reducing agent; buffering the reduced aqueous sample; chelating the amount of copper in the buffered aqueous sample with a copper(I) chelating agent; measuring the amount of copper in the aqueous sample by measuring a first change in intensity of the absorbance of the copper chelated aqueous sample; chelating the amount of zinc in the buffered aqueous sample with a zinc(II) chelating agent; and measuring the amount of zinc in the aqueous sample by measuring a second change in intensity of the absorbance of the zinc chelated aqueous sample. Other aspects are described and claimed.

    REDUCING AGENT FOR ARSENIC MEASUREMENT

    公开(公告)号:US20220397534A1

    公开(公告)日:2022-12-15

    申请号:US17345359

    申请日:2021-06-11

    Applicant: Hach Company

    Inventor: Douglas F. Royer

    Abstract: An embodiment provides a method for measuring arsenic in a sample, showing marked increase in sensitivity over previous methods including: preparing a compound of metal-plated zinc and zinc; introducing the compound to an acidified sample, wherein the sample contains an amount of arsenic, wherein the compound reduces the amount of arsenic to produce arsine gas; wherein sufficient hydrogen gas is produced to purge the sample solution; wherein the arsine gas is completely purged from the sample and captured on a test pad, wherein the pad comprises mercuric bromide, wherein the capturing produces a color change of the pad; and measuring the amount of arsenic in the sample by measuring the color change of the pad. Other aspects are described and claimed.

    CHEMISTRY/INSTRUMENT PARAMETER COLOR MAINTENANCE

    公开(公告)号:US20220334098A1

    公开(公告)日:2022-10-20

    申请号:US17621024

    申请日:2020-08-19

    Applicant: Hach Company

    Abstract: The invention provides a method for selecting a color for a chemistry or instrument based upon a parameter of a test, the method including: identifying a color corresponding to a parameter of a test for the parameter; selecting, if the color corresponding to the parameter has not previously been used for another parameter, the color for designating a chemistry or an instrument as corresponding to the parameter; selecting, if the color corresponding to the parameter has previously been used for another parameter, a different color other than the color for designating a chemistry or an instrument as corresponding to the parameter, wherein the selecting a color other than the color comprises identifying a color having a measure of change in visual perception of the different color against other previously selected colors a predetermined value from the other previously selected colors; and utilizing the selected colors for parameters across both chemistries (102, 104, 105) and instruments (101, 103) that are utilized in tests for the parameters.

    Real-time management of device maintenance

    公开(公告)号:US11431596B1

    公开(公告)日:2022-08-30

    申请号:US17174945

    申请日:2021-02-12

    Applicant: Hach Company

    Abstract: An embodiment provides a method for real-time management of device maintenance utilizing quality metrics defined based upon inputs of the device, the method including: receiving inputs corresponding to a particular device, wherein the particular device provides measurements of a parameter of a fluid; generating, from the inputs, quality metrics for and unique to the particular device; monitoring the particular device while the particular device is deployed, wherein the monitoring occurs in view of the quality metrics; and triggering, responsive to detecting information corresponding to the particular device is violating at least one of the quality metrics, a notification to a user to perform an action corresponding to the particular device.

    Dissolved oxygen measurement
    59.
    发明授权

    公开(公告)号:US11268943B2

    公开(公告)日:2022-03-08

    申请号:US16128326

    申请日:2018-09-11

    Applicant: Hach Company

    Abstract: An embodiment provides a method for measuring dissolved oxygen of an aqueous sample, including: introducing an aqueous sample into a measurement device comprising at least two dissolved oxygen sensors, wherein at least one of the at least two dissolved sensors comprises a trend sensor and at least another of the at least two dissolved sensors comprises a reference sensor; measuring a first value of dissolved oxygen using the trend sensor, wherein the trend sensor samples at a trend frequency; measuring a second value of dissolved oxygen from a reference sensor, wherein the reference sensor samples at a reference frequency, the reference frequency being less than the trend frequency; and correcting the first value of dissolved oxygen based upon the second value of dissolved oxygen. Other aspects are described and claimed.

    pH ELECTRODE WITH CARBON REGION
    60.
    发明申请

    公开(公告)号:US20210252644A1

    公开(公告)日:2021-08-19

    申请号:US17126730

    申请日:2020-12-18

    Applicant: Hach Company

    Inventor: Zoë Duncan

    Abstract: An embodiment provides a method for manufacturing a pH electrode with a carbon region, including: determining at least one pulse overlap modification for a laser pulse used when machining the carbon region; selecting a pattern for machining the carbon region; and machining a sp2 carbon region having the at least one pulse overlap modification and in the selected pattern by pulsing a laser onto a BDD electrode surface in the selected pattern with the at least one pulse overlap modification. Other aspects are described and claimed.

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