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    Diphenylamines for dyeing keratinous fibers
    51.
    发明授权
    Diphenylamines for dyeing keratinous fibers 失效
    用于染色角质纤维的二苯胺

    公开(公告)号：US4112229A

    公开(公告)日：1978-09-05

    申请号：US798011

    申请日：1977-05-18

    申请人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    发明人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    IPC分类号： A61K8/41 ,  A61Q5/10 ,  C07C275/40 ,  C09B53/02 ,  C07D265/14

    CPC分类号： C07C275/40 ,  A61K8/413 ,  A61Q5/10 ,  C09B53/02

    摘要： Diphenylamines of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently represent hydrogen, halogen or lower alkyl containing 1-4 carbon atoms with at least one of R.sub.1 and R.sub.2 being other than hydrogen; R.sub.3, R.sub.4, R.sub.5, R.sub.6, and R.sub.7 each independently represent hydrogen or lower alkyl optionally substituted with hydroxy, carbamyl, piperidinyl or acylamino; R.sub.3 and R.sub.6 or R.sub.4 and R.sub.7 also optionally forming together with the carbon and nitrogen atoms to which they are attached, a dihydrooxazine or pyrroline heterocycle; and Z represents amino, acylamino or hydroxy; and the acid salts of said diphenylamines. These diphenylamines are usefully employed in cosmetic compositions for the hair including hair dye compositions and hair setting lotion compositions.

    摘要翻译： 其中R 1和R 2各自独立地表示氢，卤素或含有1-4个碳原子的低级烷基，其中R 1和R 2中的至少一个不是氢; R3，R4，R5，R6和R7各自独立地表示氢或任选被羟基，氨基甲酰基，哌啶基或酰基氨基取代的低级烷基; R 3和R 6或R 4和R 7还任选地与它们所连接的碳原子和氮原子一起形成，二氢恶嗪或吡咯啉杂环; Z表示氨基，酰氨基或羟基; 和所述二苯胺的酸式盐。 这些二苯胺可用于头发的化妆品组合物中，包括染发组合物和头发定型洗剂组合物。

    4,4-Disubstituted diphenylamines in dye compositions for keratinic fibers
    54.
    发明授权
    4,4-Disubstituted diphenylamines in dye compositions for keratinic fibers 失效
    用于角质纤维的染料组合物中的4,4-二取代的二苯胺

    公开(公告)号：US4054147A

    公开(公告)日：1977-10-18

    申请号：US551662

    申请日：1975-02-21

    申请人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    发明人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    IPC分类号： A61K8/41 ,  A61Q5/10 ,  C07C275/40 ,  A61K7/13

    CPC分类号： A61K8/415 ,  A61K8/413 ,  A61Q5/10 ,  C07C275/40 ,  Y10S424/01 ,  Y10S424/02

    摘要： Diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, amino, lower alkyl amino, acylamino, lower carbamylalkyl amino, lower hydroxyalkyl amino, lower carbalkoxy amino and ureido;R.sub.2 and R.sub.3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, acylamino and ureido;R.sub.5 represents a member selected from the group consisting of hydrogen, halogen, lower alkyl and lower alkoxy;R.sub.6 represents a member selected from the group consisting of lower hydroxyalkyl, lower amino alkyl, lower acylamino alkyl, lower mesylamino alkyl, lower carbamylalkyl, lower sulfoalkyl, lower piperidinoalkyl, lower morpholinoalkyl, lower mono alkyl lower amino alkyl and lower dialkyl lower amino alkyl; andR.sub.7 represents a member selected from the group consisting of lower alkyl, lower hydroxyalkyl, lower aminoalkyl, lower acylamino alkyl, lower mesylamino alkyl, lower carbamyl alkyl, lower sulfoalkyl, lower piperidinoalkyl, lower morpholinoalkyl, lower monoalkyl lower amino alkyl and lower dialkyl lower amino alkyl, each of said alkyl and alkoxy moieties containing 1-6 carbon atoms and each of said acyl moieties representing R-CO- wherein R is selected from the group consisting of an aliphatic and aromatic group.The said diphenylamine is usefully employed in a dye composition for dyeing keratinic fibers.

    摘要翻译： 其中R 1和R 4各自独立地表示选自氢，卤素，低级烷基，低级烷氧基，氨基，低级烷基氨基，酰氨基，低级氨基甲酰基烷基氨基，低级羟烷基氨基，低级烷氧基 氨基和脲基; R2和R3各自独立地表示选自氢，卤素，低级烷基，低级烷氧基，酰氨基和脲基的成员; R5表示选自氢，卤素，低级烷基和低级烷氧基的成员; R6代表选自低级羟烷基，低级氨基烷基，低级酰氨基烷基，下甲磺酰氨基烷基，低级氨基甲酰基烷基，低级磺基烷基，低级哌啶子基烷基，低级吗啉代烷基，低级单烷基低级氨基烷基和低级二烷基低级氨基烷基的成员。 并且R 7表示选自低级烷基，低级羟烷基，低级氨基烷基，低级酰氨基烷基，下甲磺酰氨基烷基，低级氨基甲酰基烷基，低级磺基烷基，低级哌啶子基烷基，低级吗啉代烷基，低级单烷基低级氨基烷基和低级二烷基低级 氨基烷基，所述烷基和烷氧基部分各自含有1-6个碳原子，并且每个所述酰基部分代表R-CO-，其中R选自脂族和芳族基团。

    Indoanilines
    55.
    发明授权
    Indoanilines 失效
    印度尼西亚

    公开(公告)号：US4046786A

    公开(公告)日：1977-09-06

    申请号：US619477

    申请日：1975-10-03

    申请人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    发明人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    IPC分类号： A61K8/41 ,  A61Q5/10 ,  C07C275/26 ,  C07D295/13 ,  C07D295/135 ,  C07C119/12 ,  C07C127/17 ,  C07C143/75

    CPC分类号： C07D295/135 ,  A61K8/413 ,  A61Q5/10 ,  C07C275/26 ,  C07D295/13 ,  Y10S424/01 ,  Y10S424/02

    摘要： Indoaniline of the formula ##STR1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy;R.sub.2 represents alkyl, hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinoalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl) and mesylaminoalkyl;R.sub.3 represents hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinoalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl), mesylaminoalkyl; or R.sub.2 and R.sub.3 together form with the nitrogen atom to which they are attached a heterocycle selected from piperidino or morpholino;R.sub.4, r.sub.5 and R.sub.6 each independently represents hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino, and R.sub.5 can also represent amino, alkylamino, hydroxyalkylamino or carbamylalkylamino. The alkyl and alkoxy groups above can contain from 1 to 6 carbon atoms and the acyl group can contain from 2 to 7 carbon atoms. The present invention also relates to a process for the preparation of the above indoanilines and to dye compositions for keratinic fibers, and in particular living human hair, containing said indoanilines.

    摘要翻译： 其中R 1表示氢，卤素，烷基或烷氧基; R 2表示烷基，羟基烷基，氨基甲酰基烷基，哌啶子基烷基，吗啉代烷基，磺基烷基，二烷基氨基烷基，酰氨基烷基（优选乙酰氨基烷基或苯甲酰基氨基烷基）和甲磺酰氨基烷基; R 3表示羟烷基，氨基甲酰基烷基，哌啶子基烷基，吗啉代烷基，磺基烷基，二烷基氨基烷基，酰氨基烷基（优选乙酰氨基烷基或苯甲酰氨基烷基），甲磺酰氨基烷基; 或者R 2和R 3与它们所连接的氮原子一起形成选自哌啶子基或吗啉代的杂环; R 4，R 5和R 6各自独立地表示氢，卤素，烷基，烷氧基，酰氨基，脲基或烷氧基氨基，R 5也可以表示氨基，烷基氨基，羟基烷基氨基或氨基甲酰基烷基氨基。 上述烷基和烷氧基可含有1至6个碳原子，酰基可含有2至7个碳原子。 本发明还涉及制备上述吲哚苯胺的方法和用于角蛋白纤维的染色组合物，特别是包含所述吲哚苯胺的活人的头发。

    Diphenylamines for dyeing keratinic fibers
    58.
    发明授权
    Diphenylamines for dyeing keratinic fibers 失效
    用于染色角蛋白纤维的二苯胺

    公开(公告)号：US4008043A

    公开(公告)日：1977-02-15

    申请号：US551627

    申请日：1975-02-21

    申请人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    发明人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    IPC分类号： A61K8/41 ,  A61Q5/10 ,  C07C275/40 ,  A61K7/13

    CPC分类号： A61K8/415 ,  A61K8/413 ,  A61Q5/10 ,  C07C275/40

    摘要： Diphenylamine of the formula: ##STR1## wherein R.sub.1 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, amino, N-lower alkyl amino wherein the alkyl moiety has 1-6 carbon atoms, N-lower hydroxy alkyl amino wherein the alkyl moiety has 1-6 carbon atoms, N-lower carbamylalkyl amino wherein the alkyl moiety has 1-6 carbon atoms, acylamino, wherein the acyl moiety has 2-7 carbon atoms, ureido and carbalkoxyamino wherein the alkoxy moiety has 1-6 carbon atoms;R.sub.2 and R.sub.3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, acylamino wherein the acyl moiety has 2-7 carbon atoms and ureido;R.sub.5 and R.sub.6 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms and lower alkoxy having 1-6 carbon atoms with the proviso that when both R.sub.5 and R.sub.6 are other than hydrogen at least one of R.sub.5 and R.sub.6 occupies a position meta to --NHR.sub.7 ; andR.sub.7 represents a member selected from the group consisting of alkyl having 1-6 carbon atoms, hydroxy alkyl having 1-6 carbon atoms, amino alkyl having 1-6 carbon atoms, acylamino alkyl wherein the acyl moiety has 2-7 carbon atoms and the alkyl moiety has 1-6 carbon atoms, mesylamino alkyl having 1-6 carbon atoms, carbamyl alkyl having 1-6 carbon atoms, sulfo alkyl having 1-6 carbon atoms, piperidino alkyl having 1-6 carbon atoms, morpholino alkyl having 1-6 carbon atoms, mono alkyl amino alkyl wherein each alkyl moiety has 1-6 carbon atoms, dialkyl amino alkyl wherein each alkyl moiety has 1-6 carbon atoms.The said diphenylamine is usefully employed in a dye composition for dyeing keratinic fibers.

    摘要翻译： 具有下式的二苯胺：其中R 1和R 4各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基，氨基， 其中烷基部分具有1-6个碳原子的N-低级烷基氨基，其中烷基部分具有1-6个碳原子的N-羟基烷基氨基，其中烷基部分具有1-6个碳原子的N-低级氨基甲酰基烷基氨基，酰基氨基 其中酰基部分具有2-7个碳原子，脲基和烷氧基氨基，其中烷氧基部分具有1-6个碳原子; R2和R3各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基，酰基氨基，其中酰基部分具有2-7个碳原子和脲基的成员; R 5和R 6各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基和具有1-6个碳原子的低级烷氧基的成员，条件是当R 5和R 6至少不同于氢时， R5和R6之一占据了对-NHR7的位置; 并且R 7表示选自1-6个碳原子的烷基，具有1-6个碳原子的羟基烷基，具有1-6个碳原子的氨基烷基，酰基部分具有2-7个碳原子的酰基氨基烷基和 烷基部分具有1-6个碳原子，具有1-6个碳原子的甲磺酰氨基烷基，具有1-6个碳原子的氨基甲酰基烷基，具有1-6个碳原子的磺基烷基，具有1-6个碳原子的哌啶子基烷基，具有1个碳原子的吗啉代烷基 -6个碳原子，其中每个烷基部分具有1-6个碳原子的单烷基氨基烷基，其中每个烷基部分具有1-6个碳原子的二烷基氨基烷基。