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    Methine dyes containing a 5- or 6- membered carbocyclic or heterocyclic radical
    2.
    发明授权
    Methine dyes containing a 5- or 6- membered carbocyclic or heterocyclic radical 失效
    含有5-或6-元碳环或杂环基的甲基染料

    公开(公告)号：US5773623A

    公开(公告)日：1998-06-30

    申请号：US624332

    申请日：1996-03-29

    申请人： Andreas Johann Schmidt ,  Rudiger Sens

    发明人： Andreas Johann Schmidt ,  Rudiger Sens

    IPC分类号： C09B23/16 ,  B41M5/30 ,  B41M5/39 ,  C07C245/12 ,  C07D413/12 ,  C09B53/00 ,  C09B53/02 ,  C09B55/00 ,  D06P5/13 ,  C07D213/74 ,  B41M5/035 ,  B41M5/26

    CPC分类号： B41M5/39 ,  C09B53/02 ,  C09B55/009 ,  Y10S428/914

    摘要： Methine dyes of the formula ##STR1## where K is a 5- or 6-membered carbocyclic or heterocyclic radical, X is nitrogen or a radical of formula C--Q.sup.1, and Q.sup.1, Q.sup.2 and Q.sup.3 are each independently of the others hydrogen, C.sub.1 -C.sub.6 -alkyl with or without interruption by 1 or 2 oxygen atoms in ether function, benzyl, C.sub.3 -C.sub.8 -cycloalkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.4 -fluoroalkyl, C.sub.1 -C.sub.6 -alkoxy, benzyloxy, substituted or unsubstituted phenoxy, C.sub.1 -C.sub.6 -alkylthio, halogen, cyano, formylamino or a radical of the formula R.sup.3, --COR.sup.1, --CO--NHR.sup.1, --CO--NH--CO--R.sup.1, --CO--NH--CO--R.sup.4, --CO--NH--SO.sub.2 R.sup.4, --NH--CO--R.sup.1, --NH--CO--OR.sup.1, --NH--CO--NR.sup.1 R.sup.2, --NH--CSOR.sup.1, --NH--CS--NR.sup.1 R.sup.2, --NH--CO--R.sup.4, --NH--SO.sub.2 --R.sup.1, --NH--SO.sub.2 --R.sup.4 or --NH--SO.sub.2 --NR.sup.1 R.sup.2, where R.sup.1 and R.sup.2 are each independently of the other C.sub.1 -C.sub.13 -alkyl with or without substitution, C.sub.3 -C.sub.8 -cycloalkyl or substituted or unsubstituted phenyl, or else --NR.sup.1 R.sup.2 is amino, R.sup.3 is a nonaromatic heterocyclic radical and R.sup.4 is a heterocyclic radical or Q.sup.1 and Q.sup.2 are together with the carbon atoms to which they are attached a carbocyclic or heterocyclic ring, with the proviso that at least one of Q.sup.1, Q.sup.2 and Q.sup.3 is R.sup.3, are useful in thermal transfer.

    摘要翻译： 其中K为5-或6-元碳环或杂环基团的X为氮或式C-Q1基团，且Q 1，Q 2和Q 3各自独立地为氢，C 1 C 1-6 - 烷基，其具有或不具有醚功能中的1或2个氧原子的中断，苄基，C 3 -C 8 - 环烷基，取代或未取代的苯基，C 1 -C 4 - 氟烷基，C 1 -C 6 - 烷氧基，苄氧基，取代或未取代的苯氧基， C 1 -C 6烷硫基，卤素，氰基，甲酰氨基或式R 3，-COR 1，-CO-NHR 1，-CO-NH-CO-R 1，-CO-NH-CO-R 4，-CO-NH- SO2R4，-NH-CO-R1，-NH-CO-OR1，-NH-CO-NR1R2，-NH-CSOR1，-NH-CS-NR1R2，-NH-CO-R4，-NH-SO2-R1， NH-SO 2 -R 4或-NH-SO 2 -NR 1 R 2，其中R 1和R 2各自独立地为具有或不具有取代的其它C 1 -C 13烷基，C 3 -C 8环烷基或取代或未取代的苯基，或者-NR 1 R 2是氨基 ，R3是非芳族杂环基，R4是杂环基团，或者Q1和Q2与碳原子一起 ey连接碳环或杂环，条件是Q1，Q2和Q3中的至少一个为R3，可用于热转印。

    Mixture of indoaniline dyes in dye-donor element for thermal dye transfer
    5.
    发明授权
    Mixture of indoaniline dyes in dye-donor element for thermal dye transfer 失效
    染料供体元件中吲哚苯胺染料的混合物用于热染料转移

    公开(公告)号：US5340789A

    公开(公告)日：1994-08-23

    申请号：US169780

    申请日：1993-12-16

    申请人： Steven Evans ,  Noel R. Vanier

    发明人： Steven Evans ,  Noel R. Vanier

    IPC分类号： B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  C09B53/02 ,  C09B55/00 ,  C09B67/22 ,  B41M5/035 ,  B41M5/38

    CPC分类号： B41M5/39 ,  B41M5/3858 ,  C09B53/02 ,  C09B55/009 ,  C09B67/0034 ,  B41M2205/30 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/31786

    摘要： A cyan dye-donor element for thermal dye transfer imaging comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, wherein the dye comprises a mixture of at least three different 2-carbamoyl-4-[N-(p-aminoaryl)-imino]-1,4-naphthoquinone dyes, each of the dyes having the formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each individually represents a substituted or unsubstituted alkyl group of from 1 to about 6 carbon atoms, a substituted or unsubstituted cycloalkyl group of from about 5 to about 7 carbon atoms, a substituted or unsubstituted aryl group of from about 5 to about 10 carbon atoms or an allyl group;R.sup.2 and R.sup.3 may be combined together to form a 5- or 6-membered ring;R.sup.2 and/or R.sup.3 may be combined with one or two of X to form a 5- or 6-membered ring;R.sup.4 and X each individually represents hydrogen, a substituted or unsubstituted alkyl group of from about 1 to about 6 carbon atoms, halogen, --NHCOR.sup.1 or --NHSO.sub.2 R.sup.1 ; andn represents an integer from 1 to 4;with the proviso that at least one of the dyes is characterized by having R.sup.1 represent an unbranched alkyl group of from 2 to 4 carbon atoms, which may be substituted by an alkoxy group of from 1 to 4 carbon atoms, and/or having one or both of R.sup.2 and R.sup.3 represent a branched alkyl group of from 3 to 6 carbon atoms.

    摘要翻译： 一种用于热染料转移成像的青色染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，其中所述染料包含至少三种不同的2-氨基甲酰基-4- [N-（p - 氨基芳基） - 亚氨基] -1,4-萘醌染料，每种染料具有下式：其中R 1，R 2和R 3各自独立地表示取代或未取代的1至约6个碳原子的烷基， 取代或未取代的约5至约7个碳原子的环烷基，取代或未取代的约5至约10个碳原子的芳基或烯丙基; R2和R3可以组合在一起形成5-或6-元环; R2和/或R3可以与X中的一个或两个结合形成5-或6-元环; R 4和X各自独立地表示氢，取代或未取代的约1至约6个碳原子的烷基，卤素，-NHCOR 1或-NHSO 2 R 1; n表示1〜4的整数， 条件是至少一种染料的特征在于R1表示可以被1至4个碳原子的烷氧基取代的2至4个碳原子的无支链烷基，和/或具有一个或多个 R2和R3都表示3〜6个碳原子的支链烷基。

    Dye-donor element for use in thermal dye sublimation transfer
    6.
    发明授权
    Dye-donor element for use in thermal dye sublimation transfer 失效
    用于热染料升华转移的染料供体元件

    公开(公告)号：US5326666A

    公开(公告)日：1994-07-05

    申请号：US40610

    申请日：1993-03-31

    申请人： Luc Vanmaele ,  Wilhelmus Janssens

    发明人： Luc Vanmaele ,  Wilhelmus Janssens

    IPC分类号： B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/46 ,  C09B53/02 ,  G03C8/40 ,  G03C5/54 ,  G03C1/72 ,  G03C5/16

    CPC分类号： B41M5/465 ,  B41M5/39 ,  C09B53/02 ,  Y10S430/145 ,  Y10S430/165

    摘要： Dye-donor element for use according to thermal dye sublimation transfer, said dye-donor element comprising a support provided with a dye layer containing a dye dispersed in a polymeric binder, characterized in that said dye corresponds to the following formula (I) ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent hydrogen, halogen, nitro, an alkyl group, a cycloalkyl group, an aryl group, an alkoxy group, an aryloxy group, a alkylthio group, a arylthio group, an acylamino group, a sulfamoyl group, a carbamoyl group, which groups may be substituted, or R.sup.2 and R.sup.3 together can form a saturated or aromatic or heterocyclic ring fused-on the cyclohexadiene ring, which ring may be substituted;B represents ##STR2## wherein R.sup.4 -R.sup.11 are defined in the specification; K represents ##STR3## wherein: R.sup.12 and R.sup.13 (independently) represent hydrogen, an alkyl group, an aryl group, a heterocyclic group, which groups may be substituted, or R.sup.12 and R.sup.13 together represent the necessary atoms to close a heterocyclic ring, which ring may be substituted, or R.sup.12 and/or R.sup.13 together with R.sup.14 and/or R.sup.17 represent the necessary atoms to close a ring fused-on the benzene ring, which ring may be substituted;R.sup.14, R.sup.15, R.sup.16 and R.sup.17 are defined in the specification.

    摘要翻译： 用于根据热染料升华转移使用的染料供体元件，所述染料供体元件包括具有分散在聚合物粘合剂中的染料层的载体，其特征在于所述染料对应于下式（I） K代表其中R12和R13（独立地）代表氢，烷基，芳基，杂环基，这些基团可被取代，或R 12和R 13一起代表关闭杂环的必要原子，其中 R 12和/或R 13与R 14和/或R 17一起代表必要的原子以封闭稠合在苯环上的环，该环可被取代; R14，R15，R16和R17在说明书中定义。

    Chromogenic substrate to peroxidase enzymes
    7.
    发明授权
    Chromogenic substrate to peroxidase enzymes 失效
    显色底物与过氧化物酶

    公开(公告)号：US5043269A

    公开(公告)日：1991-08-27

    申请号：US156210

    申请日：1988-02-16

    申请人： Spyros Theodoropulos

    发明人： Spyros Theodoropulos

    IPC分类号： C09B53/02 ,  C12Q1/28

    CPC分类号： C12Q1/28 ,  C09B53/02 ,  C12Q2326/00 ,  C12Q2326/32 ,  Y10S436/904

    摘要： A novel chromogenic substrate to peroxidase enzymes is provided which is comprised of a mixture of a colorless mixture of two compounds, such as, 3-methyl-2-benzothiazolinone hydrazone and 2-hydroxy-2,4,6-cycloheptatrienone, which undergo an oxidative coupling in the presence of peroxidase and hydrogen peroxide forming a purple indamine dye. Under certain circumstances the dye will precipitate out from the buffered solution and thus provide a permanent record of the determination. The mixture is also stable and unaffected by oxygen of the air or by hydrogen peroxide.

    摘要翻译： 提供了一种新颖的过氧化物酶底物，其由两种化合物的无色混合物，如3-甲基-2-苯并噻唑啉酮腙和2-羟基-2,4,6-环庚三烯酮组成的混合物组成， 氧化偶联在过氧化物酶和过氧化氢存在下形成紫色印度胺染料。 在某些情况下，染料将从缓冲溶液中沉淀出来，从而提供测定的永久记录。 混合物也是稳定的，不受空气氧气或过氧化氢的影响。

    P-phenylene diamine derivatives
    8.
    发明授权
    P-phenylene diamine derivatives 失效
    对苯二胺衍生物

    公开(公告)号：US5041608A

    公开(公告)日：1991-08-20

    申请号：US366502

    申请日：1990-06-15

    申请人： Tsutomu Mano ,  Jiro Kawase ,  Daisuke Misu ,  Michio Obayashi

    发明人： Tsutomu Mano ,  Jiro Kawase ,  Daisuke Misu ,  Michio Obayashi

    IPC分类号： C09B53/02

    CPC分类号： A61K8/69 ,  A61K8/411 ,  A61Q5/10 ,  C09B53/02

    摘要： A dye composition for keratinous fibers comprising a specific type of trifluoromethylated aniline derivative, as a developer, and a coupling substance is disclosed. The composition provides high degree of saturation and vividness of colors as well as good fastness. Dyeing with the use of the dye composition ensures a variety of developer-coupling agent combinations, which can provide a wide variety of colors with a high degree of color saturation and vividness. The color produced possesses excellent light resistance, washing resistance, and wear resistance. Amoung the trifluoromethylated aniline derivative, used as a developer, a p-phenylenediamine-type trifluoromethylated aniline derivative of the following formula is a novel compound. ##STR1## in which X represents a specific type of mono- or polyhydroxyalkyl group, alkyl group, or other organic group.

    New chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said
    10.
    发明授权
    New chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said 失效
    新的氯代间苯二胺，它们用作角质纤维的氧化染色中的成色剂，含有这些化合物的头发的染色组合物和使用所述

    公开(公告)号：US4865618A

    公开(公告)日：1989-09-12

    申请号：US200399

    申请日：1988-05-31

    申请人： Alex Junino ,  Jean J. Vandenbossche ,  Herve Borowiak ,  Gerard Lang

    发明人： Alex Junino ,  Jean J. Vandenbossche ,  Herve Borowiak ,  Gerard Lang

    IPC分类号： A61K8/00 ,  A61K20060101 ,  A61K8/41 ,  A61Q5/10 ,  C07C20060101 ,  C07C215/20 ,  C07C217/84 ,  C09B53/02 ,  D06P1/32 ,  D06P3/04 ,  D06P3/14

    CPC分类号： A61K8/411 ,  A61Q5/10

    摘要： New chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said compositions.The invention relates to the compounds of formula: ##STR1## in which Z and Z' denote, independently of one another, an alkyl radical having from 1 to 4 carbon atoms or a hydroxyalkyl radical having from 2 to 4 carbon atoms, andR.sub.1 and R.sub.2 denote, independently of one another, a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms or a mono- or polyhydroxyalkyl radical having 2 or 3 carbon atoms, to their addition salts with an acid, and to their use by way of couplers for the oxidation dyeing of keratinous fibres, especially human hair.These compounds, when they are combined with paraphenylenediamines, surprisingly give beige to light brown hues or purple hues of greater or lesser redness, depending on the substitution of the 5-amino group of the chlorobenzene.

    摘要翻译： 新的氯代间苯二胺，它们用作角质纤维的氧化染色中的成色剂，含有这些化合物的头发的染色组合物和使用所述组合物的染色方法。 本发明涉及下式的化合物：其中Z和Z'彼此独立地表示具有1至4个碳原子的烷基或具有2至4个碳原子的羟烷基， 并且R 1和R 2彼此独立地表示氢原子，具有1至4个碳原子的烷基或具有2或3个碳原子的单羟基或多羟基烷基，与它们与酸的加成盐，以及它们 通过成色剂用于角质纤维，特别是人类头发的氧化染色。 这些化合物当与对苯二胺结合时，令人惊讶的是，由于取代氯苯的5-氨基，令人惊讶的是，它使浅棕色色调或更多或更少发红的紫色色调发亮。