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    Method for Producing Bi-Functional Ammonium Nitriles
    51.
    发明申请
    Method for Producing Bi-Functional Ammonium Nitriles 审中-公开
    双功能硝酸铵生产方法

    公开(公告)号：US20090023942A1

    公开(公告)日：2009-01-22

    申请号：US11885610

    申请日：2006-02-24

    Applicant: Gerd Reinhardt ,  Lars Cuypers

    Inventor： Gerd Reinhardt ,  Lars Cuypers

    IPC: C07C253/30 ,  C07C255/32

    CPC classification number: C11D3/3927 ,  C07C253/30 ,  C07C255/25

    Abstract: The invention relates to a method for producing bifunctional ammonium nitriles by reacting a dihalogenalkyl compound or a dihalogenaryl compound with a dialkylaminoacetonitrile in a polar, aprotic solvent. Bifunctional ammonium nitriles may be used as bleach activators in detergents and cleaners.

    Abstract translation: 本发明涉及通过在极性非质子溶剂中使二卤代烷基化合物或二卤代芳基化合物与二烷基氨基乙腈反应制备双官能铵腈的方法。 双功能铵腈可用作洗涤剂和清洁剂中的漂白活化剂。

    Method for Producing Bi-Functional Ammonium Nitriles
    52.
    发明申请
    Method for Producing Bi-Functional Ammonium Nitriles 审中-公开
    双功能硝酸铵生产方法

    公开(公告)号：US20080139838A1

    公开(公告)日：2008-06-12

    申请号：US11885609

    申请日：2006-02-24

    Applicant: Gerd Reinhardt ,  Hans Prehler ,  Lars Cuypers

    Inventor： Gerd Reinhardt ,  Hans Prehler ,  Lars Cuypers

    IPC: C07C255/24

    CPC classification number: C07C253/30 ,  C11D3/3927 ,  C07C255/25

    Abstract: The invention relates to a method for producing bifunctional ammonium nitriles of the following general formulae: by reacting a tertiary diamine with a cyanomethylene-group-transferring quaternizing agent in a polar, aprotic solvent. Bifunctional ammonium nitriles may be used as bleach activators in detergents and cleaners.

    Abstract translation: 本发明涉及以下通式生产双官能铵腈的方法：通过在极性的非质子溶剂中使叔二胺与氰基亚甲基转移季铵化剂反应。 双功能铵腈可用作洗涤剂和清洁剂中的漂白活化剂。

    Use of transition metal complexes having lactam ligands as bleaching catalysts
    54.
    发明授权
    Use of transition metal complexes having lactam ligands as bleaching catalysts 失效
    使用具有内酰胺配位体的过渡金属络合物作为漂白催化剂

    公开(公告)号：US07094745B2

    公开(公告)日：2006-08-22

    申请号：US10954425

    申请日：2004-09-30

    Applicant: Ekaterina Jonas ,  Gerd Reinhardt ,  Daniel Kewitz ,  Aylin Karadag

    Inventor： Ekaterina Jonas ,  Gerd Reinhardt ,  Daniel Kewitz ,  Aylin Karadag

    IPC: C11D7/26 ,  C11D7/32 ,  C11D7/38 ,  C11D7/54

    CPC classification number: C11D3/3932

    Abstract: The use of compounds of the formula (1) M(L)nXm  (1) in which M is a metal atom from the group consisting of Mn, Fe, Co, Ni, Mo and W, L is a ligand from the group consisting of the cyclic carboxamides (lactams), X is chloride, bromide, nitrate, perchlorate, citrate, hexafluorophosphate or anions of organic acids having C1–C22 carbon atoms and n is a number from 2 to 4 and m is a number from 0 to 4, as catalysts for peroxygen compounds, in particular in detergents, bleaches and cleaning agents, is claimed.

    Abstract translation: 使用式（1）的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> M（L）N （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中M是由Mn，Fe，Co，Ni，Mo组成的组中的金属原子， W，L是来自环状酰胺（内酰胺）的配体，X是氯化物，溴化物，硝酸盐，高氯酸盐，柠檬酸盐，六氟磷酸盐或具有C 1 -C 3的有机酸阴离子 > 22个碳原子，n为2〜4的数，m为0〜4的数，作为过氧化合物的催化剂，特别是洗涤剂，漂白剂和清洗剂。

    Cyclic sugar ketones as catalysts for peroxygen compounds
    55.
    发明授权
    Cyclic sugar ketones as catalysts for peroxygen compounds 失效
    循环糖酮作为过氧化合物的催化剂

    公开(公告)号：US06649085B2

    公开(公告)日：2003-11-18

    申请号：US09994091

    申请日：2001-11-16

    Applicant: Gerd Reinhardt ,  Nicole Reichardt

    Inventor： Gerd Reinhardt ,  Nicole Reichardt

    IPC: C07D31100

    CPC classification number: C11D3/3912

    Abstract: The use of cyclic sugar ketones of the formula in which R1 and R2 are hydrogen, C1-C22-alkyl, C2-C22-alkenyl or phenyl, R3 is C1-C4-alkoxy, phenyl-CH2—O— or a group of the formula R4 is hydrogen or R3 and R4 together are a group of the formula and n is zero or 1, as catalysts for peroxygen compounds.

    Abstract translation: R 1和R 2的环状糖酮的使用是氢，C 1 -C 22 - 烷基，C 2 -C 22 - 烯基或苯基，R 3是C 1 -C 4 - 烷氧基，苯基-CH 2 -O-或式R 4的基团是氢或R 3和R 4一起是下式的基团，n是0或1，作为过氧化合物的催化剂。

    Bleach systems comprising bis- and tris(.mu.-oxo)dimanganese complex salts
    58.
    发明授权
    Bleach systems comprising bis- and tris(.mu.-oxo)dimanganese complex salts 失效
    漂白体系包括双 - 和三（μ-氧）二亚胺盐

    公开(公告)号：US5942152A

    公开(公告)日：1999-08-24

    申请号：US775354

    申请日：1997-01-03

    Applicant: Ahmed Tafesh ,  Matthias Beller ,  Vera Friderichs ,  Gerd Reinhardt

    Inventor： Ahmed Tafesh ,  Matthias Beller ,  Vera Friderichs ,  Gerd Reinhardt

    IPC: D06L3/02 ,  C11D3/39 ,  C11D3/395 ,  C09K3/00

    CPC classification number: C11D3/3932

    Abstract: Bleach systems comprising bis- and tris(.mu.-oxo)dimanganese complex salts as catalystBis- and tris(.mu.-oxo)dimanganese complex salts of the formula�LMn(.mu.-O).sub.a (.mu.-OAc).sub.b MnL!.sup.x A.sub.yas catalysts for oxidizing organic compounds, in which formulaAc is a C.sub.2 -C.sub.8 -acyl group,a is 1, 2 or 3,b is 0 if a is 2 or 3 or is 2 if a is 1,x denotes the number of positive charges and is 2 or 3,A is an anion,y is the equivalent amount of anion A required to compensate the positive charges, andL is a ligand, preferably N,N'-bis(2-pyridylmethyl)-N-methylamine or N,N,N',N'-tetrakis(2-pyridylmethyl)-1,2-ethylenediamineare employed as catalysts in bleach systems for textile material.

    Abstract translation: 包含双 - 和三（μ-氧）二甘氨酸复合盐作为催化剂的漂白体系式[LMn（mu-O）a（mu -OAc）bMnL] xAy的催化剂双 - 和三（mu-氧）二亚胺盐复合盐作为催化剂 为了氧化有机化合物，其中式Ac为C2-C8-酰基，a为1,2或3，如果a为2或3，b为0，如果a为1，则b为0，x表示正电荷数 并且是2或3，A是阴离子，y是补偿正电荷所需的阴离子A的当量，L是配体，优选N，N'-双（2-吡啶基甲基）-N-甲胺或N N，N'，N'-四（2-吡啶基甲基）-1,2-乙二胺用作纺织材料漂白系统中的催化剂。

    Use of a water-soluble copolymers based on acrylamidoalkylenesulfonic acid as a detergent additive
    60.
    发明授权
    Use of a water-soluble copolymers based on acrylamidoalkylenesulfonic acid as a detergent additive 失效
    使用基于丙烯酰氨基烷基磺酸的水溶性共聚物作为洗涤剂添加剂

    公开(公告)号：US5607618A

    公开(公告)日：1997-03-04

    申请号：US109229

    申请日：1993-08-19

    Applicant: Werner Antwerpen ,  Martin Hille ,  Gerd Reinhardt

    Inventor： Werner Antwerpen ,  Martin Hille ,  Gerd Reinhardt

    IPC: C11D3/00 ,  C11D3/37 ,  C11D1/18

    CPC classification number: C11D3/378 ,  C11D3/0021

    Abstract: The present invention relates to the the use of water-soluble copolymers based on acrylamidoalkylenesulfonic acid, vinylacetamide and, if appropriate, other monomers, comprising5-90% by weight of structural units of the formula ##STR1## in which R.sup.1 is hydrogen or methyl,R.sup.2 is C.sub.2 -C.sub.10 -alkylene, preferably C.sub.2 -C.sub.6 -alkylene, particularly preferably C.sub.4 -alkylene, andMe is ammonium or an alkali metal ion,5-95% by weight of structural units of the formula ##STR2## in which R.sup.3 and R.sup.4 independently of one another are hydrogen, methyl or ethyl, or R.sup.3 and R.sup.4 together are a propylene group which, including a radical ##STR3## form a pyrrolidone radical, 0-90% by weight of structural units of the formula ##STR4## in which X is a halogen, preferably chloride,R.sup.5 and R.sup.6 independently of one another are C.sub.1 -C.sub.6 -alkyl, prefrably C.sub.1 -C.sub.3 -alkyl, in particular methyl or ethyl, and0-90% by weight of structural units of the formula --CHR.sup.7 -CHR.sup.8 --in whichR.sup.7 is hydrogen or methyl andR.sup.8 is CONH.sub.2, CON(CH.sub.3).sub.2, cyano, SO.sub.3 H, SO.sub.3 Me, C.sub.6 H.sub.4 SO.sub.3 H, C.sub.6 H.sub.4 SO.sub.3 Me, CH.sub.2 SO.sub.3 H, CH.sub.2 SO.sub.3 Mr, COOH, COOMe or an ester group COOR, in which R is C.sub.1 -C.sub.15 -alkyl, preferably C.sub.1 -C.sub.8 -alkyl,as a detergent additive for preventing reabsorption of detached dyestuffs and dyestuff degradation products.

    Abstract translation: 本发明涉及使用基于丙烯酰氨基烷基磺酸，乙烯基乙酰胺和适当的其它单体的水溶性共聚物，其包含5-90重量％的式（I）的结构单元，其中R 1是 氢或甲基，R 2是C 2 -C 10亚烷基，优选C 2 -C 6亚烷基，特别优选C 4亚烷基，Me是铵或碱金属离子，5-95重量％下式结构单元： （II），其中R 3和R 4彼此独立地是氢，甲基或乙基，或者R 3和R 4一起是丙烯基团，其包括基团形成吡咯烷酮基团，0-90重量％的结构单元 其中X是卤素，优选氯，R 5和R 6彼此独立的式（III）的化合物是C 1 -C 6烷基，优选C 1 -C 3 - 烷基，特别是甲基或乙基，以及0-90 重量％的式-CHR7-CHR8的结构单元，其中R 7是氢或甲基，R 8是CONH 2，CON（CH 3）2，氰基，SO 3 H，SO 3 Me，C 6 H 4 SO 3 H，C 6 H 4 SO 3 Me，CH 2 SO 3 H，CH 2 SO 3 Mr，COOH，COOMe或酯基COOR，其中R是C 1 -C 15烷基，优选C 1 -C 8烷基， 分离染料和染料降解产物的再吸收。

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