公开(公告)号：US08927478B2

公开(公告)日：2015-01-06

申请号：US13060836

申请日：2009-08-26

Applicant: Gerd Reinhardt ,  Michael Best ,  Joachim Erbes

Inventor： Gerd Reinhardt ,  Michael Best ,  Joachim Erbes

IPC: C11D7/04 ,  C11D7/38 ,  C11D7/54 ,  C11D3/39 ,  C11D3/20

CPC classification number: C11D3/3932 ,  C11D3/2086 ,  C11D3/3905 ,  C11D3/391 ,  C11D3/3917

Abstract: The invention relates to the use of manganese oxalates in detergents and cleaning agents, in particular in cleaning agents containing peroxy compounds for hard surfaces.

Abstract translation: 本发明涉及草酸锰在洗涤剂和清洁剂中的用途，尤其涉及含有硬表面的过氧化合物的清洁剂。

公开(公告)号：US08907118B2

公开(公告)日：2014-12-09

申请号：US13816686

申请日：2011-08-06

Applicant: Melanie Sajitz ,  Gerd Reinhardt ,  Isabel Scheffer ,  Werner Janitschek ,  Ina Herrgen

Inventor： Melanie Sajitz ,  Gerd Reinhardt ,  Isabel Scheffer ,  Werner Janitschek ,  Ina Herrgen

IPC: C07C67/14

CPC classification number: C07C67/14 ,  C07C69/017 ,  C07C69/24 ,  C07C69/78

Abstract: The invention relates to a method for producing acyloxy benzoic acids of the formula (I), in which R1 is a linear or branched saturated alkyl group with 6 to 30 carbon atoms, a linear or branched mono- or polyunsaturated alkenyl group with 6 to 30 carbon atoms, or an aryl group with 6 to 30 carbon atoms. The acyloxy benzoic acids of the formula (I) are produced from para-hydroxy benzoic acid and a corresponding carboxylic acid halide in the presence of an alkali hydroxide.

Abstract translation: 本发明涉及一种制备式（I）的酰氧基苯甲酸的方法，其中R 1为具有6至30个碳原子的直链或支链饱和烷基，具有6至30个直链或支链单或多不饱和链烯基 碳原子或具有6至30个碳原子的芳基。 式（I）的酰氧基苯甲酸由对羟基苯甲酸和相应的羧酸卤化物在碱金属氢氧化物存在下制备。

公开(公告)号：US08883704B2

公开(公告)日：2014-11-11

申请号：US13263022

申请日：2010-04-01

Applicant: Georg Borchers ,  Gerd Reinhardt ,  Andreas Schottstedt

Inventor： Georg Borchers ,  Gerd Reinhardt ,  Andreas Schottstedt

IPC: C11D3/16 ,  C11D3/39 ,  C11D3/395 ,  C11D3/20

CPC classification number: C11D3/3932 ,  C11D3/2075 ,  C11D3/2079 ,  C11D3/3907 ,  C11D3/3917 ,  C11D3/3935

Abstract: The invention relates to co-granules containing a) at least one bleach activator, b) at least one metal-containing bleach catalyst, and c) at least 5 wt. % of at least one organic acid. The co-granules are easy to produce, have a high stability in storage and are advantageously suitable for producing cleaning products and detergents and especially products for cleaning crockery in a machine.

Abstract translation: 本发明涉及含有a）至少一种漂白活化剂，b）至少一种含金属的漂白催化剂和c）至少5wt。 ％的至少一种有机酸。 共颗粒易于生产，在储存中具有高稳定性，并且有利地适用于生产清洁产品和洗涤剂，特别是用于在机器中清洁陶器的产品。

公开(公告)号：US20140114073A1

公开(公告)日：2014-04-24

申请号：US13877567

申请日：2011-10-06

Applicant: Christian Sidot ,  Audrey Caron ,  Miriam Ladwig ,  Gerd Reinhardt

Inventor： Christian Sidot ,  Audrey Caron ,  Miriam Ladwig ,  Gerd Reinhardt

IPC: C07F15/02 ,  C07F13/00

CPC classification number: C07F15/02 ,  C07F13/00 ,  C07F13/005 ,  C07F15/025

Abstract: The invention relates to a method for producing metal complexes of formula (2) [MaLxXn]Ym (2), where M is a metal from the group consisting of Mn(II), Mn(III), Mn(IV), Fe(II), Fe(III) or Fe(IV), X is a coordinating compound selected from mono-, bi- or tri-charged anions or neutral molecules which can coordinate to a metal in mono-, bi- or tri-dentate form, Y represents a non-coordinating counter-ion which ensures charge equalization of the complex, L represents a ligand of formula (1) or the protonized or de-protonized form thereof, and a, x, n, m, R, R1, R2, R3 and z have the meanings described in claim 1. Said method is characterized in that the reaction of one or more ligands of formula (1) with an iron salt or manganese salt is carried out in an acetone/water mixture in a temperature range from 0 to 50° C. and for this purpose a solution or a suspension of the one or more ligands of formula (1) in acetone is brought in contact with an aqueous metal salt solution of the iron salt or manganese salt in the temperature range in which the reaction takes place.

Abstract translation: 本发明涉及一种制备式（2）[MaLxXn] Ym（2）的金属配合物的方法，其中M是由Mn（II），Mn（III），Mn（IV），Fe（ II），Fe（III）或Fe（IV），X是选自单，双或三电荷阴离子或中性分子的配位化合物，其可以以单，双或三齿形式与金属配位 ，Y表示非配位抗衡离子，其确保络合物的电荷均衡，L表示式（1）的配体或其质子化或去质子化形式，和a，x，n，m，R，R 1， R2，R3和z具有权利要求1所述的含义。所述方法的特征在于，式（1）的一种或多种配体与铁盐或锰盐的反应在丙酮/水混合物中在温度 范围为0至50℃，为此目的，将式（1）的一种或多种配体在丙酮中的溶液或悬浮液与铁盐水溶液的金属盐溶液接触 r锰盐在发生反应的温度范围内。

公开(公告)号：US20140005091A1

公开(公告)日：2014-01-02

申请号：US13982975

申请日：2012-02-03

Applicant: Gerd Reinhardt ,  Werner Janitschek ,  Miriam Ladwig

Inventor： Gerd Reinhardt ,  Werner Janitschek ,  Miriam Ladwig

IPC: C11D3/395

CPC classification number: C11D3/3951 ,  C11D1/00 ,  C11D3/386 ,  C11D3/3905 ,  C11D3/391 ,  C11D3/392 ,  C11D3/3932 ,  C11D3/43 ,  C11D7/32

Abstract: The invention relates to the use of manganese or iron complexes which, as well as a tetraoxolene unit, contain two macrocyclic, N-containing ligands, especially cyclen or cyclam ligands, in washing and cleaning compositions in the form of granules or powder or solution or suspension for bleaching of coloured stains both on textiles and on hard surfaces. The invention also relates to washing and cleaning compositions which comprise such complexes as bleach activators and to the use thereof for textile washing or for dishwashing detergents and other uses in personal care and other areas.

Abstract translation: 本发明涉及锰或铁络合物的用途以及四氧杂环己烷单元在颗粒或粉末或溶液形式的洗涤和清洁组合物中含有两个大环的含N配体，特别是环烯或环基配体，或 在纺织品和硬表面上漂白有色染料的悬浮液。 本发明还涉及洗涤和清洁组合物，其包含诸如漂白活化剂的复合物，以及其用于纺织品洗涤或餐具洗涤剂的用途以及个人护理和其它区域中的其它用途。

公开(公告)号：US20120202990A1

公开(公告)日：2012-08-09

申请号：US13394968

申请日：2010-09-10

Applicant: Gerd Reinhardt ,  Michael Best ,  Christian Sidot

Inventor： Gerd Reinhardt ,  Michael Best ,  Christian Sidot

IPC: C07F13/00

CPC classification number: C07F13/005 ,  B01J31/182 ,  B01J31/2208 ,  B01J2531/0216

Abstract: The invention relates to a method for producing manganese complex compounds of the general formula (1), wherein M, X, L, z, Y and q are defined as in claim 1. The method is characterized by the following steps: a) reacting one or more bivalent metal salts with the ligand L in water as the solvent to form a coordination compound from the one or more bivalent metal salt and the ligand L, the one or more bivalent metal salts being selected from bivalent manganese salts and iron salts and at least one bivalent metal salt being a bivalent manganese salt, b) oxidizing the coordination compound of step a) with an oxidant while at the same time maintaining a pH of 11 to 14, to transform the metal M from the bivalent to the trivalent and/or tetravalent form, c) reducing the pH of the reaction mixture to a pH of 4 to 9 and removing any metal oxides or metal hydroxides of the metal M formed and d) adding, at a pH of 4 to 9, a salt of the formula MezYq, wherein Me represents an alkali metal ion, ammonium ion or an alkanol ammonium ion, and Y, z and q are defined as in formula (1).

Abstract translation: 本发明涉及一种制备通式（1）的锰络合物的方法，其中M，X，L，Z，Y和q如权利要求1中所定义。该方法的特征在于以下步骤：a） 一种或多种二价金属盐与水中的配体L作为溶剂，以从一种或多种二价金属盐和配体L形成配位化合物，一种或多种二价金属盐选自二价锰盐和铁盐，以及 至少一种二价金属盐是二价锰盐，b）用氧化剂氧化步骤a）的配位化合物，同时保持pH为11至14，以将金属M从二价转化成三价和 /或四价形式，c）将反应混合物的pH降低至4至9的pH，并除去形成的金属M的任何金属氧化物或金属氢氧化物，以及d）在pH4至9的条件下，加入 式MezYq，其中Me表示碱金属离子，a 铵离子或烷醇铵离子，Y，Z和q如式（1）所定义。

公开(公告)号：US20100267600A1

公开(公告)日：2010-10-21

申请号：US12665011

申请日：2008-06-13

Applicant: Frank Richter ,  Nicole Nitschke ,  Gerd Reinhardt

Inventor： Frank Richter ,  Nicole Nitschke ,  Gerd Reinhardt

IPC: C11D3/34

CPC classification number: C11D1/37 ,  C11D1/143

Abstract: The invention discloses mixtures consisting of two or three surfactants from the group containing secondary alkane sulfonates, α-methyl ester sulfonates and φ-methyl ester sulfonates. Said mixtures exhibit a synergistic cleaning action in comparison to the respective individual surfactants.

Abstract translation: 本发明公开了由含有仲烷基磺酸盐，α-甲基酯磺酸盐和对甲基酯磺酸盐的两种或三种表面活性剂组成的混合物。 与相应的各个表面活性剂相比，所述混合物表现出协同的清洁作用。

公开(公告)号：US07504372B2

公开(公告)日：2009-03-17

申请号：US11662305

申请日：2005-09-03

Applicant: Gerd Reinhardt ,  Georg Borchers

Inventor： Gerd Reinhardt ,  Georg Borchers

IPC: C11D10/00

CPC classification number: C11D3/3935 ,  C11D3/3917 ,  C11D3/392 ,  C11D3/3945

Abstract: What are claimed are synergistically active bleach mixtures consisting ofa) a compound of the formula (1) in which n is 3, 4 or 5, and b) tetraacetylethylenediamine and/or 1,5-diacetyl-2,4-dioxo-1,3,5-hexa-hydrotriazine.

Abstract translation: 所要求的是协同活性漂白混合物，其由a）式（1）的化合物组成，其中n为3,4或5，b）四乙酰基乙二胺和/或1,5-二乙酰基-2,4-二氧代-1 ，3,5-hexa-hydrotriazine。

公开(公告)号：US07205267B2

公开(公告)日：2007-04-17

申请号：US11041468

申请日：2005-01-24

Applicant: Gerd Reinhardt ,  Ekaterina Jonas

Inventor： Gerd Reinhardt ,  Ekaterina Jonas

IPC: C11D3/26 ,  C11D3/28 ,  C11D3/39 ,  C11D3/395

CPC classification number: C11D3/168 ,  C11D3/3932

Abstract: The use is claimed of transition metal complexes of the formula (I) [M(L)Yn]Xm  (I) where M is a metal atom from the group of Mn and Fe, L is a ligand of the general formula (II) or (III) where R1, R2, R3 and R4 are the same or different and are each H, C1–C8-alkyl or C6–C12-alkaryl; X and Y are each an uncharged or anionic ligand from the group of CH3CN, chloride, bromide, nitrate, perchlorate, sulfate, citrate, hexafluorophosphate, trifluoromethanesulfonate, tetrafluoroborate, tetraphenylborate or an anion of organic acids having C1–C22 carbon atoms, n and m are each a number from 0 to 4 as bleach catalysts in laundry detergents and cleaning compositions.

Abstract translation: 要求使用下式的过渡金属络合物

公开(公告)号：US20050054554A1

公开(公告)日：2005-03-10

申请号：US10897703

申请日：2004-07-23

Applicant: Georg Borchers ,  Alexander Lerch ,  Gerd Reinhardt

Inventor： Georg Borchers ,  Alexander Lerch ,  Gerd Reinhardt

IPC: A61K8/00 ,  A61K8/66 ,  A61Q11/02 ,  C11D3/39 ,  C11D3/42 ,  C11D7/22 ,  C11D7/42 ,  C11D7/54 ,  C11D7/60 ,  C11D3/00

CPC classification number: C11D3/3935 ,  C11D3/3907 ,  C11D3/42

Abstract: Detergent additives which are in granule form and are composed essentially of a) an active substance for detergents and b) an optical brightener.

Abstract translation: 颗粒状洗涤剂添加剂，主要由a）用于洗涤剂的活性物质和b）荧光增白剂组成。