公开(公告)号：US20210171423A1

公开(公告)日：2021-06-10

申请号：US17181479

申请日：2021-02-22

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Glenn Matthies ,  Rajiv Ratna Singh ,  Terris Yang ,  Haiyou Wang ,  Ryan J. Hulse ,  Rajiv Banavali

IPC: C07C17/20 ,  C07C17/35 ,  B01J27/224

Abstract: The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25° C. to about 400° C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200° C. to about 600° C. to produce a final product stream comprising the trifluoroiodomethane.

公开(公告)号：US10696613B1

公开(公告)日：2020-06-30

申请号：US16506741

申请日：2019-07-09

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haridasan K. Nair ,  Rajiv Ratna Singh ,  Mark Makar

IPC: C07C17/25 ,  C07C21/18

Abstract: Disclosed are processes for the dechlorination of haloethanes comprising reacting in the gaseous phase a haloethane and reducing agent such as an alkene, an alkane, hydrogen or combinations of two or more of these, in the presence of a silicon-based catalyst.

公开(公告)号：US20200062679A1

公开(公告)日：2020-02-27

申请号：US16549412

申请日：2019-08-23

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Glenn Matthies ,  Rajiv Ratna Singh ,  Terris Yang ,  Haiyou Wang ,  Ryan J. Hulse ,  Rajiv Banavali

IPC: C07C17/20 ,  B01J27/224 ,  C07C17/35

Abstract: The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25° C. to about 400° C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200° C. to about 600° C. to produce a final product stream comprising the trifluoroiodomethane.

公开(公告)号：US20180072642A1

公开(公告)日：2018-03-15

申请号：US15709931

申请日：2017-09-20

Applicant: Honeywell International Inc.

Inventor： Rajiv Banavali ,  Haridasan K. Nair ,  Yian Zhai

IPC: C07C17/361 ,  C07C21/18

CPC classification number: C07C17/361 ,  Y02P20/582 ,  C07C21/18

Abstract: Disclosed is a process for the formation of a mixture of the compounds 2,3,3,3-tetrafluoropropene (HFO-1234yf) and vinylidene fluoride, comprising pyrolyzing 1,1,2-trifluoro-2-trifluoro-methyl-cyclobutane under conditions effective to produce a reaction product comprising HFO-1234yf and vinylidene fluoride in a 1234yf:vinylidene fluoride molar ratio of from about 0.5 to about 1.2.

公开(公告)号：US20170233316A1

公开(公告)日：2017-08-17

申请号：US15582981

申请日：2017-05-01

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Rajiv Banavali ,  Yian Zhai ,  Glenn Matthies

IPC: C07C17/275

CPC classification number: C07C17/275 ,  C07C2601/04 ,  C07C23/06

Abstract: The production of 1,1,2-trifluoro-2-(trifluoromethyl)cyclobutane (TFMCB). More specifically, the present invention relates to a process for making 1,1,2-trifluoro-2-(trifluoromethyl)cyclobutane via a continuous catalytic reaction from commercially available raw materials ethylene and hexafluoropropene.

公开(公告)号：US20170137353A1

公开(公告)日：2017-05-18

申请号：US15345695

申请日：2016-11-08

Applicant: Honeywell International Inc.

Inventor： Rajiv Banavali ,  Haridasan K. Nair ,  Yian Zhai

IPC: C07C17/361

CPC classification number: C07C17/361 ,  Y02P20/582 ,  C07C21/18

Abstract: Disclosed is a process for the formation of a mixture of the compounds 2,3,3,3-tetrafluoropropene (1234yf) and vinylidine fluoride, comprising pyrolyzing 1,1,2-trifluoro-2-trifluoro-methyl-cyclobutane under conditions effective to produce a reaction product comprising 1234yf and vinylidine fluoride in a 1234yf:vinylidine fluoride molar ratio of from about 0.5 to about 1.2.

公开(公告)号：US09061957B2

公开(公告)日：2015-06-23

申请号：US13746434

申请日：2013-01-22

Applicant: Honeywell International Inc.

Inventor： Sudip Mukhopadhyay ,  Haridasan K. Nair ,  Rajesh K. Dubey ,  Rajiv R. Singh ,  George A. Shia

IPC: C07C17/25 ,  C07C19/08 ,  C07C21/18 ,  C07C17/278 ,  C07C17/23

CPC classification number: C07C17/278 ,  C07C17/23 ,  C07C17/25 ,  C07C21/18 ,  C07C19/10

Abstract: Disclosed is a method for producing fluorinated organic compounds, including reacting CF2═CFCl with CH2FCl under conditions effective to produce a product composition including CF3CClFCH2Cl. The present invention also relates to the production of hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa−m  (I) to at least one compound of formula (II) CF3CZCHZ  (II). where each X is independently Cl, F, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a−m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a C1 addition agent under conditions effective to produce a compound of formula (I).

Abstract translation: 公开了一种生产氟化有机化合物的方法，包括在有效产生包含CF 3 CClFCH 2 Cl的产物组合物的条件下使CF 2 = CFCl与CH 2 FCl反应。 本发明还涉及氢氟丙烯的制备，其优选包括将至少一种式（I）化合物：CF 3 CF n CH m X a-m（I）转化为至少一种式（II）CF 3 CZCHZ（II）化合物。 其中每个X独立地为Cl，F，I或Br; 每个Z独立地为H或F; n为1或2; m为1,2或3，条件是当n为1时，m为1或2; a为2或3，a-m≥0。 某些实施方案包括在有效产生式（I）化合物的条件下使氟化C 2烯烃如四氟乙烯与C1加成剂反应的步骤。

公开(公告)号：US20150045588A1

公开(公告)日：2015-02-12

申请号：US14330659

申请日：2014-07-14

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Andrew Joseph Poss ,  David Nalewajek ,  Yian Zhai

IPC: C07C17/25 ,  C07C17/281

CPC classification number: C07C17/25 ,  C07C17/10 ,  C07C17/275 ,  C07C17/278 ,  C07C17/281 ,  C07C21/18 ,  C07C19/10

Abstract: The present invention provides routes for making 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) from commercially available raw materials. More specifically, this invention provides routes for HCFO-1233zd from inexpensive and commercially available trifluoromethane (HFC-23).

Abstract translation: 本发明提供从市售原料制备1-氯-3,3,3-三氟丙烯（HCFO-1233zd）的途径。 更具体地说，本发明提供了廉价且市售的三氟甲烷（HFC-23）的HCFO-1233zd路线。

公开(公告)号：US08889924B2

公开(公告)日：2014-11-18

申请号：US13757911

申请日：2013-02-04

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Rajiv Ratna Singh ,  Andrew Joseph Poss ,  David Nalewajek

IPC: C07C17/25 ,  C07C17/278 ,  C07C19/01 ,  C07C19/08 ,  C07C19/10 ,  C07C21/06 ,  C07C21/18 ,  C07C17/20

CPC classification number: C07C17/25 ,  C07C17/206 ,  C07C17/278 ,  C07C19/08 ,  C07C19/10 ,  C07C21/06 ,  C07C21/18 ,  C07C19/01

Abstract: The present invention provides a simple three step process for the production of 1,3,3,3-tetrafluoropropene (HFO-1234ze). In the first step, carbon tetrachloride is added to vinyl fluoride to afford the compound CCl3CH2CHClF (HCFC-241fb). HCFC-241fb is then fluorinated with anhydrous HF to afford CF3CH2CHClF (HCFC-244fa) in the second step. Dehydrochlorination of HCFC-244fa, in the third step, affords the desired product, CF3CH═CHF (HFO-1234ze). Following similar chemistry, vinyl chloride may be used in place of vinyl fluoride.

Abstract translation: 本发明提供了制备1,3,3,3-四氟丙烯（HFO-1234ze）的简单的三步法。 在第一步中，将四氯化碳加入到氟乙烯中，得到化合物CCl 3 CH 2 CHClF（HCFC-241fb）。 然后用无水HF将HCFC-241fb氟化，得到第二步中的CF 3 CH 2 CHClF（HCFC-244fa）。 在第三步中HCFC-244fa的脱氯化氢提供所需产物，CF 3 CH = CHF（HFO-1234ze）。 在类似的化学反应之后，可以使用氯乙烯代替氟乙烯。