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95 条记录 (耗时 0.036 秒)

    Novel motor fuel alkylation process
    51.
    发明授权
    Novel motor fuel alkylation process 失效
    新型汽油燃料烷基化工艺

    公开(公告)号：US4677245A

    公开(公告)日：1987-06-30

    申请号：US927462

    申请日：1986-11-06

    申请人： Joseph A. Kocal ,  Tamotsu Imai

    发明人： Joseph A. Kocal ,  Tamotsu Imai

    IPC分类号： B01J27/12 ,  B01J31/02 ,  B01J31/40 ,  C07C2/62 ,  C07C2/58

    CPC分类号： B01J27/12 ,  B01J31/0204 ,  B01J31/40 ,  C07C2/62 ,  B01J2231/323 ,  C07C2527/1206 ,  C07C2531/02 ,  Y02P20/584

    摘要： A novel hydrocarbon alkylation process is disclosed wherein the feed hydrocarbons are dried to maintain the water content of the alkylation catalyst at less than 2.0 wt. %, where said alkylation catalyst is comprised of a mineral acid and an ether component selected from the group consisting of tert-butyl ether, methylphenyl ether, tert amylmethyl ether (TAME), or methyl tert-butyl ether (MTBE). This process also incorporates a method of regenerating at least a portion of the alkylation catalyst to prevent build-up of more than 15 wt. % of polymer products therein.

    摘要翻译： 公开了一种新的烃烷基化方法，其中进料烃被干燥以将烷基化催化剂的水含量保持在小于2.0wt。 ％，其中所述烷基化催化剂由无机酸和选自叔丁基醚，甲基苯基醚，叔戊基甲基醚（TAME）或甲基叔丁基醚（MTBE）的醚组分组成。 该方法还包括再生烷基化催化剂的至少一部分的方法，以防止累积超过15wt。 ％的聚合物产品。

    Hydration of olefins
    53.
    发明授权
    Hydration of olefins 失效
    烯烃的水合

    公开(公告)号：US4465874A

    公开(公告)日：1984-08-14

    申请号：US455354

    申请日：1983-01-03

    申请人： Joseph A. Kocal

    发明人： Joseph A. Kocal

    IPC分类号： C07C29/04 ,  C07C31/125

    CPC分类号： C07C29/04

    摘要： Olefins containing from 2 to about 6 carbon atoms may be directly hydrated by treatment with water in the presence of a catalyst comprising an alpha-zirconium phosphate. The use of this catalyst which possesses desirable thermal stability characteristics will enable the reaction to be effected at higher operating conditions than is possible when utilizing other catalysts.

    摘要翻译： 含有2至约6个碳原子的烯烃可通过在含有α-磷酸锆的催化剂存在下用水处理直接水合。 具有所需热稳定性特征的该催化剂的使用将使反应能够在比使用其它催化剂时更高的操作条件下进行。

    Process for oxidizing alkyl aromatic compounds
    54.
    发明授权
    Process for oxidizing alkyl aromatic compounds 有权
    氧化烷基芳族化合物的方法

    公开(公告)号：US08884054B2

    公开(公告)日：2014-11-11

    申请号：US13155519

    申请日：2011-06-08

    申请人： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

    发明人： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

    IPC分类号： C07C51/16 ,  C07C51/265

    CPC分类号： C07C51/265 ,  C07C63/16 ,  C07C63/24 ,  C07C63/26 ,  C07C63/06

    摘要： A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, and a catalyst; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an ionic liquid selected from the group consisting of an imidazolium ionic liquid, a pyridinium ionic liquid, a phosphonium ionic liquid, a tetra alkyl ammonium ionic liquid, and combinations thereof. The catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium.

    摘要翻译： 用于氧化烷基 - 芳族化合物的方法和混合物包括形成包含烷基 - 芳族化合物，溶剂，溴源和催化剂的混合物; 以及在氧化条件下使所述混合物与氧化剂接触以产生包含芳族醛，芳族醇，芳族酮和芳族羧酸中的至少一种的氧化产物。 溶剂包括具有1至7个碳原子的羧酸和选自咪唑鎓离子液体，吡啶鎓离子液体，鏻离子液体，四烷基铵离子液体及其组合的离子液体。 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。

    Solid terephthalic acid composition
    55.
    发明授权
    Solid terephthalic acid composition 有权
    固体对苯二甲酸组成

    公开(公告)号：US08835678B2

    公开(公告)日：2014-09-16

    申请号：US13155568

    申请日：2011-06-08

    申请人： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

    发明人： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

    IPC分类号： C07C63/26 ,  C07C51/265 ,  C07C51/43

    CPC分类号： C07C51/265 ,  C07C51/43 ,  C07C63/26

    摘要： A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.

    摘要翻译： 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯，溶剂，溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸，对甲苯甲酸，4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。

    Process for generation of polyols from saccharide containing feedstock
    58.
    发明授权
    Process for generation of polyols from saccharide containing feedstock 有权
    从含糖原料生成多元醇的方法

    公开(公告)号：US08222463B2

    公开(公告)日：2012-07-17

    申请号：US13193072

    申请日：2011-07-28

    申请人： Tom N. Kalnes ,  Joseph A. Kocal ,  John Q. Chen

    发明人： Tom N. Kalnes ,  Joseph A. Kocal ,  John Q. Chen

    IPC分类号： C07C29/00 ,  C07C31/18

    CPC分类号： C07C29/132 ,  C07C31/20

    摘要： A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. The process involves, contacting hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one metal component with an oxidation state greater than or equal to 2+.

    摘要翻译： 以包含糖的原料产生至少一种多元醇的方法以连续或间歇方式进行。 该方法涉及使氢，水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。 催化剂体系包含至少一种氧化态大于或等于2+的金属组分。

    Process for generation of polyols from saccharides
    59.
    发明授权
    Process for generation of polyols from saccharides 有权
    由糖生成多元醇的方法

    公开(公告)号：US08222462B2

    公开(公告)日：2012-07-17

    申请号：US13192970

    申请日：2011-07-28

    申请人： Tom N. Kalnes ,  Joseph A. Kocal ,  John Q. Chen

    发明人： Tom N. Kalnes ,  Joseph A. Kocal ,  John Q. Chen

    IPC分类号： C07C29/00 ,  C07C31/18

    CPC分类号： C07C29/00 ,  C07C31/202 ,  C07C31/205

    摘要： A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. The process involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.

    摘要翻译： 以包含糖的原料生成至少一种多元醇的方法以连续或间歇的方式进行。 该方法包括使氢，水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。 催化剂体系包含至少一种未负载的组分和至少一种负载的组分。

    SOLID TEREPHTHALIC ACID COMPOSITION
    60.
    发明申请
    SOLID TEREPHTHALIC ACID COMPOSITION 有权
    固体正庚酸组合物

    公开(公告)号：US20120004455A1

    公开(公告)日：2012-01-05

    申请号：US13155568

    申请日：2011-06-08

    申请人： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

    发明人： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

    IPC分类号： C07C63/26

    CPC分类号： C07C51/265 ,  C07C51/43 ,  C07C63/26

    摘要： A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.

    摘要翻译： 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯，溶剂，溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸，对甲苯甲酸，4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。