公开(公告)号：US5106941A

公开(公告)日：1992-04-21

申请号：US719444

申请日：1991-06-24

Applicant: Waylon L. Jenkins ,  Gerry F. Rhodes ,  Mark Rule

Inventor： Waylon L. Jenkins ,  Gerry F. Rhodes ,  Mark Rule

IPC: C08G63/88 ,  C08K3/34

CPC classification number: C08G63/88 ,  C08K3/34

Abstract: A process for preparing a crystalline poly(cyclohexanedimethylene terephthalate) comprising(A) preparing an admixture of molten poly(cyclohexanedimethylene terephthalate) and a 4A zeolite, and(b) cooling the admixture at a rate less than about 1000.degree. C. per minute to a temperature less than about 80.degree. C.

Abstract translation: 一种制备结晶聚（环己烷二亚甲基对苯二甲酸酯）的方法，其包括（A）制备熔融的聚（环己烷二亚甲基对苯二甲酸酯）和4A沸石的混合物，和（b）以低于约1000℃/分钟的速率将该混合物冷却至 温度低于约80℃

公开(公告)号：US5064937A

公开(公告)日：1991-11-12

申请号：US534338

申请日：1990-06-06

Applicant: David R. Fagerburg ,  Joseph J. Watkins ,  Paul B. Lawrence ,  Mark Rule

Inventor： David R. Fagerburg ,  Joseph J. Watkins ,  Paul B. Lawrence ,  Mark Rule

IPC: C08G75/14

CPC classification number: C08G75/14

Abstract: A process for preparing a polymer having repeating units corresponding to the structure ##STR1## wherein y is in the range of 0.005 to 0.15, x is in the range of 0.02 to 0.25, n is at least 200, and R a divalent aromatic radial. The polymer is prepared by reacting a diiodoaromatic compound and elemental sulfur.

Abstract translation: 制备具有对应于结构图像的重复单元的聚合物的方法，其中y在0.005至0.15的范围内，x在0.02至0.25的范围内，n至少为200，R为二价芳族的径向。 聚合物是通过使二碘代芳族化合物与元素硫反应来制备的。

公开(公告)号：US5026824A

公开(公告)日：1991-06-25

申请号：US522495

申请日：1990-05-14

Applicant: Mark Rule ,  Jerry S. Fauver ,  David R. Fagerburg ,  Paul B. Lawrence ,  Joseph J. Watkins

Inventor： Mark Rule ,  Jerry S. Fauver ,  David R. Fagerburg ,  Paul B. Lawrence ,  Joseph J. Watkins

IPC: C08G75/02 ,  C08G75/14

CPC classification number: C08G75/0236 ,  C08G75/0263 ,  C08G75/14

Abstract: A process for preparing a polymer having repeating units corresponding to the structure ##STR1## wherein R is ##STR2## y is in the range of 0.005 to 0.10, x is in the range of 0.01 to 0.50 when R is ##STR3## x is in the range of 0.01 to 0.30 when R is ##STR4## and n is at least 200. The polymer is prepared by reacting a diiodoaromatic compound and elemental sulfur.

Abstract translation: 制备具有对应于结构> TR图像的重复单元的聚合物的方法，其中R为0.005至0.10，x在0.01至0.50的范围内，当 当R为且n为至少200时，R为，x为0.01至0.30的范围。聚合物通过使二碘代芳族化合物与元素硫反应制备。

公开(公告)号：US4885423A

公开(公告)日：1989-12-05

申请号：US350667

申请日：1989-05-11

Applicant: Mark Rule

Inventor： Mark Rule

IPC: C07C17/26

CPC classification number: C07C17/269

Abstract: A process for preparation of an aromatic dimer compound corresponding to the structureIxAr-ArIxwherein x is 0, 1, 2, 3, 4, or 5 and Ar is a divalent aromatic radical containing 6 to 14 carbon atoms comprising contacting, at a sufficient temperature and pressure in the absence of carbon monoxide and in the absence of an alkali metal compound or an alkaline earth metal compound, platinum and an aromatic iodide compound corresponding to the structureAr-Ixwhere Ar is a monovalent aromatic radical and x is 1, 2, 3, 4, 5, or 6.

Abstract translation: 制备对应于结构IxAr-ArIx的芳族二聚体化合物的方法，其中x为0,1,2,3,4或5，Ar为含有6至14个碳原子的二价芳基，包括以足够的 在不存在一氧化碳的情况下，在不存在碱金属化合物或碱土金属化合物的情况下，对应于结构Ar-Ix的铂和芳香族碘化合物，其中Ar是一价芳族基，x是1， 2，3，4，5或6。

公开(公告)号：US4859762A

公开(公告)日：1989-08-22

申请号：US308924

申请日：1989-02-13

Applicant: Mark Rule ,  David R. Fagerburg ,  Joseph J. Watkins

Inventor： Mark Rule ,  David R. Fagerburg ,  Joseph J. Watkins

IPC: C08G75/02

CPC classification number: C08G75/0263 ,  C08G75/0222

Abstract: A process for preparing a copoly(arylene sulfide) corresponding to the structure[(--A--S--).sub.1-x (--A--S--S--).sub.x ].sub.nwherein x is in the range of 0.5 to 0.001 by reacting a mixture of a diiodoaromatic compound and elemental sulfur in the absence of a basic material and in the presence of a catalytic amount of an organic amine-containing compound.

Abstract translation: 制备对应于[（-AS-）1-x（-ASS-）x] n结构的共聚（亚芳基硫醚）的方法，其中x为0.5至0.001的范围内，通过使二碘代芳族化合物和 在不存在碱性物质的情况下和在催化量的含有机胺化合物存在下的元素硫。

公开(公告)号：US4855514A

公开(公告)日：1989-08-08

申请号：US232964

申请日：1988-08-17

Applicant: Mark Rule ,  Regina M. Moncier

Inventor： Mark Rule ,  Regina M. Moncier

IPC: C07C29/38 ,  C07C37/62

CPC classification number: C07C37/62

Abstract: A process for producing iodophenols which comprises contacting phenol, a source of iodine and molecular oxygen in an aqueous medium to produce an iodophenol.

Abstract translation: 一种生产碘酚的方法，其包括使苯酚，碘源和分子氧在水性介质中接触以产生碘苯酚。

公开(公告)号：US4851564A

公开(公告)日：1989-07-25

申请号：US158973

申请日：1988-02-22

Applicant: Guy R. Steinmetz ,  Mark Rule

Inventor： Guy R. Steinmetz ,  Mark Rule

IPC: C07C69/76

CPC classification number: C07C69/76

Abstract: Disclosed is a process for the co-production of aromatic carboxylates and alkyl iodides by the carbonylation of aromatic iodides in the presence of an alkanol and a rhodium catalyst.

Abstract translation: 公开了在烷醇和铑催化剂存在下通过芳族碘化物的羰基化共同生产芳族羧酸盐和烷基碘化物的方法。

公开(公告)号：US4778918A

公开(公告)日：1988-10-18

申请号：US115292

申请日：1987-11-02

Applicant: Guy R. Steinmetz ,  Mark Rule ,  Victor H. Agreda ,  Lanney C. Treece

Inventor： Guy R. Steinmetz ,  Mark Rule ,  Victor H. Agreda ,  Lanney C. Treece

IPC: B01J27/13 ,  C07B61/00 ,  C07C17/093 ,  C07C17/16 ,  C07C17/18 ,  C07C19/07 ,  C07C67/00 ,  C07C67/36 ,  C07C69/76 ,  C07C17/00

CPC classification number: C07C17/093

Abstract: Disclosed is a process for the co-production of aromatic carboxylic esters and alkyl iodides by the carbonylation of aromatic iodides in the presence of an ether and a rhodium catalyst.

Abstract translation: 公开了通过在醚和铑催化剂的存在下芳族碘化物的羰基化来共同生产芳族羧酸酯和烷基碘的方法。

公开(公告)号：US4705890A

公开(公告)日：1987-11-10

申请号：US26916

申请日：1987-03-17

Applicant: Guy R. Steinmetz ,  Mark Rule

Inventor： Guy R. Steinmetz ,  Mark Rule

IPC: C07C51/10

CPC classification number: C07C51/10

Abstract: Disclosed is a process for production of aromatic carboxylic acids by the carbonylation of aromatic iodides in the presence of a ruthenium catalyst, a Bronsted base, and an iodide promoter.

Abstract translation: 公开了在钌催化剂，Bronsted碱和碘化物促进剂的存在下通过芳族碘化物的羰基化生产芳族羧酸的方法。

公开(公告)号：US4481314A

公开(公告)日：1984-11-06

申请号：US509112

申请日：1983-06-29

Applicant: Mark Rule

Inventor： Mark Rule

IPC: C08K5/18 ,  C08K5/42 ,  C09K15/24

CPC classification number: C08K5/18 ,  Y10S430/145 ,  Y10S430/146

Abstract: Disclosed are novel anthraquinone compounds containing tetra-p-phenylenediamine substituents, particularly useful in molding type polyester compositions and possessing strong infrared absorptivity. This property renders these compounds attractive as additives for increasing the infrared energy absorptivity of polyesters either from high intensity quartz lamps or from certain laser systems. These compounds are particularly useful in bottle polyester material for increasing the blow-mold parison reheat rate, and in the printing of plastic articles with lasers.

Abstract translation: 公开了含有四对苯二胺取代基的新型蒽醌化合物，特别适用于成型型聚酯组合物并且具有强的红外吸收性。 这种性质使得这些化合物作为增加聚酯的红外能量吸收性的添加剂是有吸引力的，或者来自高强度石英灯或来自某些激光系统。 这些化合物特别适用于瓶聚酯材料，用于增加吹模型坯再加热速率，以及在用激光打印塑料制品时。