摘要:
An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and an acetate derivative including two or more substituted silyl groups as an additive. The organic electrolytic solution and the lithium battery employing the same relatively suppress a reduction decomposition of a polar solvent and decrease irreversible capacity in the first cycle. Thus, the charge/discharge efficiency, lifespan, and reliability of the battery can be improved.
摘要:
A composite anode active material includes a composite of a carbon-based anode active material, a metal-based anode active material and polymer particles. By increasing the conductivity of the composite anode active material, a lithium battery having a large capacity, high initial efficiency, high rate capability and improved cycle life performance can be obtained. An anode includes the composite anode active material and a lithium battery includes the anode.
摘要:
An anode active material and a lithium battery employing the same are provided. In one embodiment of the anode active material, a —(CH2CH2O)— repeating unit is bonded to the surface of metal particles that contain metals that can be alloyed with lithium. The repeating unit prevents reactions between the metal particles and the electrolyte solution. Also, due to its elasticity, the repeating unit absorbs part of the volume expansion of the metal particles. The repeating unit also prevents the metal particles from condensing, thereby enhancing dispersion properties. Accordingly, the inventive anode active material has high capacity and excellent capacity retention during repeated charging and discharging, thereby providing a lithium battery with a long cycle life.
摘要:
Provided are a porous anode active material, a method of preparing the same, and an anode and a lithium battery employing the same. The porous anode active material includes fine particles of metallic substance capable of forming a lithium alloy; a crystalline carboneous substance; and a porous carboneous material coating and attaching to the fine particles of metallic substance and the crystalline carboneous substance, the porous anode active material having pores exhibiting a bimodal size distribution with two pore diameter peaks as measured by a Barrett-Joyner-Halenda (BJH) pore size distribution from a nitrogen adsorption. The porous anode active material has the pores having a bimodal size distribution, and thus may efficiently remove a stress occurring due to a difference of expansion between a carboneous material and a metallic active material during charging and discharging. Further, the anode electrode and the lithium battery comprising the anode active material have excellent charge/discharge characteristics.
摘要:
An organic electrolytic solution includes a lithium salt; an organic solvent including a high dielectric constant solvent and a low boiling point solvent; and an additive of a hetero ring compound including a cyano group and an alkenyl group as substituents. The organic electrolytic solution and the lithium battery employing the organic electrolytic solution suppress the reduction decomposition of a polar solvent to improve the capacity retention ratio of the battery. Thus, the charge/discharge efficiency and lifespan of the battery can be improved.
摘要:
A composite anode active material including a transition metal; an intermetallic compound which includes the transition metal as one component and is capable of alloy formation with lithium; and carbon, where both the transition metal and the intermetallic compound have crystallinity, and the transition metal exists in a phase structurally separated from the intermetallic compound capable of alloy formation with lithium, where a content of the transition metal elements as both a metal and a component of the intermetallic compound may be less than 45 wt % based on the total weight of the transition metal and the intermetallic compound capable of alloy formation with lithium. The composite anode active material is a composite anode active material having a new structure, and includes a crystalline intermetallic compound, a crystalline transition metal, and carbon. In addition, an anode and lithium battery prepared using the composite anode active material have excellent charge-discharge characteristics.
摘要:
A composite anode active material includes a metal that may be alloyed with lithium, an intermetallic compound incapable of alloying with lithium, and a carbonaceous material, wherein the intermetallic compound exists in a phase structurally separated from the metal capable of alloying with lithium. Since the composite active material contains an intermetallic compound that does not form any alloy phase with lithium nor the metal capable of alloying with lithium but rather exists in a structurally separated phase, the composite active material exhibits excellent coulombic efficiency. Further, anode electrodes and lithium batteries including the composite anode active material exhibit improved charge and discharge characteristics.
摘要:
Organic electrolytic solutions and lithium batteries using the organic electrolytic solutions are provided. One organic electrolytic solution includes a lithium salt, a mixed organic solvent consisting of a high-dielectric constant solvent and a low-boiling point solvent, and a compound represented by Formula 1 or 2 as an additive. The organic electrolytic solution and the lithium battery using the organic electrolytic solution may inhibit the reductive cleavage reaction of a polar solvent, thereby increasing capacity retention of the battery, and improving charge-discharge efficiency and battery lifetime.
摘要:
Anode active materials, methods of producing the same and lithium batteries using the same are provided. More particularly, an anode active material having high capacity and excellent capacity retention, a method of producing the same and a lithium battery having a long lifespan using the same are provided. The anode active material comprises complex material particles comprising silicon and graphite, a carbon layer covering the surface of the complex material particles, and a silicon-metal alloy formed between the complex material particles and the amorphous carbon layer.
摘要:
An anode active material including a metal core and a coating layer formed on a surface of the metal core is provided. The coating layer includes a conductive metal material. The coating layer covering the metal core is carbon-based and includes a conductive metal material. The anode active material has good electron conductivity and elasticity, thereby enhancing charge/discharge capacity and reducing the stress caused by expansion of the carbon-based coating layer and the metal core during charge/discharge cycles. Direct contact between the metal core and the electrolyte solution is remarkably reduced. In addition, anodes and lithium batteries including the anode active material exhibit excellent charge/discharge characteristics, such as discharge capacity and initial charge/discharge efficiency.