公开(公告)号：US07704927B2

公开(公告)日：2010-04-27

申请号：US12115603

申请日：2008-05-06

申请人： Qi Qu ,  Xiaolan Wang

发明人： Qi Qu ,  Xiaolan Wang

IPC分类号： C09K8/26 ,  C09K8/72 ,  E21B43/28

CPC分类号： C09K8/68 ,  C09K8/72

摘要： Methods and compositions useful in acidizing a subterranean formation with an oil-in-water emulsion that includes a sulfonate ester, a fluoride salt, a proppant, and water. The reaction of the ester and fluoride salt is delayed so that hydrofluoric acid is produced in-situ.

摘要翻译： 可用于使用包含磺酸酯，氟化物盐，支撑剂和水的水包油乳液酸化地层的方法和组合物。 酯和氟化物盐的反应被延迟，从而原位产生氢氟酸。

公开(公告)号：US20090253595A1

公开(公告)日：2009-10-08

申请号：US12062278

申请日：2008-04-03

申请人： Qi Qu ,  Frances DeBenedictis ,  Xiaolan Wang

发明人： Qi Qu ,  Frances DeBenedictis ,  Xiaolan Wang

IPC分类号： C09K8/86

CPC分类号： C09K8/602 ,  C09K8/04 ,  C09K8/52 ,  C09K8/68

摘要： This invention provides compositions comprising an aqueous well fluid and at least one nonionic acetylenic alcoholic surfactant. The compositions may further comprise at least one fluoroaliphatic surfactant. Methods for recovery of aqueous well fluids involving the use of at least one nonionic acetylenic alcoholic surfactant are also provided, and these methods may further comprise the use of at least one fluoroaliphatic surfactant.

摘要翻译： 本发明提供了包含水性井液和至少一种非离子炔属醇表面活性剂的组合物。 组合物还可以包含至少一种氟代脂族表面活性剂。 还提供了涉及使用至少一种非离子炔属醇类表面活性剂的含水井液的回收方法，并且这些方法还可以包括使用至少一种氟代脂族表面活性剂。

公开(公告)号：US20090131285A1

公开(公告)日：2009-05-21

申请号：US12271667

申请日：2008-11-14

申请人： Xiaolan Wang ,  Qi Qu ,  Joel L. Boles

发明人： Xiaolan Wang ,  Qi Qu ,  Joel L. Boles

IPC分类号： C09K8/60

CPC分类号： C09K8/72

摘要： An oil or gas well penetrating a subterranean formation, such as a carbonate formation, is treated with a well treatment fluid which contains an organic ester. The fluid may be an oil-in-water emulsion of the organic ester and an emulsifier or a homogeneous solution of organic ester and a water/mutual solvent solution. Acid is produced in-situ by hydrolysis of the organic ester.

摘要翻译： 穿透地下地层（如碳酸盐岩层）的油井或气井用含有有机酯的井处理液处理。 流体可以是有机酯的水包油乳液和乳化剂或有机酯和水/互溶剂溶液的均匀溶液。 通过水解有机酯原位产生酸。

公开(公告)号：US20070265171A1

公开(公告)日：2007-11-15

申请号：US11820085

申请日：2007-06-18

申请人： Paul Javora ,  Brian Beall ,  Mark Vorderburggen ,  Qi Qu ,  Sandra Berry

发明人： Paul Javora ,  Brian Beall ,  Mark Vorderburggen ,  Qi Qu ,  Sandra Berry

IPC分类号： C09K8/52

CPC分类号： C09K8/52 ,  C09K8/524 ,  Y10S507/905 ,  Y10S507/929

摘要： Fluid producing or injecting wells may be treated with a water-in-oil emulsion for the removal or inhibition of unwanted particulates, including pipe dope, asphaltenes and paraffins. In addition, such emulsions are effective in the displacement of oil base drilling muds and/or residues from such muds from wells. The emulsion may also be used to break the interfacial and/or rheological properties of oil base mud and synthetic oil base mud filter cakes, and act as a demulsifier to break the water-in-oil emulsion present in such oil base and synthetic oil base muds. The water-in-oil emulsions may optionally contain a dispersing agent as well as a surfactant.

摘要翻译： 流体生产或注入井可用油包水乳液处理，以除去或抑制不需要的颗粒，包括管道涂料，沥青质和石蜡。 此外，这种乳液在油井钻井泥浆和/或来自井的这种泥浆的残留物的位移中是有效的。 该乳液也可用于破坏油基泥浆和合成油基泥浆滤饼的界面和/或流变性能，并且用作破乳剂以破坏这种油基和合成油基中存在的油包水乳液 泥土 油包水乳液可以任选地含有分散剂以及表面活性剂。

公开(公告)号：US20070167542A1

公开(公告)日：2007-07-19

申请号：US11589461

申请日：2006-10-30

申请人： Cristian Lopez ,  Xiaolan Wang ,  Qi Qu ,  Paul Javora

发明人： Cristian Lopez ,  Xiaolan Wang ,  Qi Qu ,  Paul Javora

IPC分类号： B01F17/00

CPC分类号： E21B36/003 ,  C09K8/592

摘要： A thermal insulating packer fluid contains at least one water superabsorbent polymer and optionally water and/or brine, and a viscosifying polymer. The composition is capable of inhibiting unwanted heat loss from production tubing or uncontrolled heat transfer to outer annuli. The viscosity of the composition is sufficient to reduce the convection flow velocity within the annulus.

摘要翻译： 绝热封隔器流体包含至少一种水超吸收性聚合物和任选的水和/或盐水，以及增粘聚合物。 该组合物能够抑制生产管道不期望的热损失或不受控制的热传递至外环。 组合物的粘度足以降低环形空间内的对流流速。

公开(公告)号：US07172703B2

公开(公告)日：2007-02-06

申请号：US11145281

申请日：2005-06-03

申请人： Paul H. Javora ,  Qi Qu

发明人： Paul H. Javora ,  Qi Qu

IPC分类号： B01D15/00

CPC分类号： E21B21/068 ,  B01D19/04 ,  B01J45/00 ,  C02F1/28 ,  C02F1/66 ,  C02F1/683 ,  C02F1/72 ,  C02F9/00 ,  C02F2101/20 ,  C02F2103/08 ,  Y10S210/912

摘要： A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and/or non-zinc heavy metals; and (ii) calcium and zinc. The chelant is of the formula: and may be either a neutral compound, a corresponding salt, or a corresponding quaternary salt, wherein: D is F—A (Y3)u(Y4)v; R is independently selected from Cp or CpC(O); Cp is a C1–C36 hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2 groups; each A is independently selected from —N and —P; Y1 is independently selected from J, —[(F)—A(J)]wY6 and R; J, R1, Y2, Y3, Y4, Y5 and Y6 are independently selected from the group consisting of —H, R, —(F)nCO2Z and —(CH2)nPO(OZ)2; each F is independently selected from a C1–C12 hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2 groups; Z is —H or a balanced counterion of an alkali or alkaline earth metal or NH4+; m is 0 to 7; n is 1 to 7; r+s+t is 1 or 2; u+v is 1 or 2; and w is 0 to 7 provided when m is 0, no more than one of R1, Y1, Y2 and Y5 can be —H.

公开(公告)号：US07144844B2

公开(公告)日：2006-12-05

申请号：US10846994

申请日：2004-05-14

申请人： Qi Qu ,  David Alleman

发明人： Qi Qu ,  David Alleman

IPC分类号： C09K8/68

CPC分类号： C09K8/74 ,  C09K8/601 ,  C09K8/602 ,  C09K8/76 ,  C09K2208/26 ,  C09K2208/30 ,  Y10S507/922

摘要： A process for enhancing the productivity of a formation consists of introducing into the formation a viscoelastic fluid which contains at least one surfactant, at least one quaternary amine polyelectrolyte, water, and a non-aqueous solvent. The surfactant forms aggregation structures or vesicles. The fluid, which significantly enhances fluid viscosity and thermal stability, is particularly effective as a diverting fluid to divert an acid treatment package from a high permeability or undamaged portion of a formation to a low permeability or damaged portion of a formation as well as a fracturing fluid. In addition, the fluid is useful for sand control completion.

摘要翻译： 提高地层生产率的方法包括向地层中引入含有至少一种表面活性剂，至少一种季胺聚电解质，水和非水溶剂的粘弹性流体。 表面活性剂形成聚集结构或囊泡。 显着增强流体粘度和热稳定性的流体作为将酸处理包从地层的高渗透性或未损坏部分转移到地层的低渗透性或损坏部分以及压裂的转向流体是特别有效的 流体。 此外，该流体可用于防砂完成。

公开(公告)号：US20060223713A1

公开(公告)日：2006-10-05

申请号：US11098967

申请日：2005-04-05

申请人： Marek Pakulski ,  Qi Qu ,  Rick Pearcy

发明人： Marek Pakulski ,  Qi Qu ,  Rick Pearcy

IPC分类号： C09K8/32 ,  C09K8/22

CPC分类号： C09K8/52

摘要： Compositions for inhibiting the formation and/or growth of gas hydrates contain at least one low dosage kinetic hydrate inhibitor and at least one thermodynamic hydrate inhibitor. Kinetic hydrate inhibitors include aminated polyalkylene glycols of the formula: R1R2N[(A)a—(B)b—(A)c—(CH2)d—CH(R)—NR1]nR2  (I) wherein: each A is independently selected from —CH2CH(CH3)O— or —CH(CH3)CH2O—; B is —CH2CH2O—; a+b+c is from 1 to about 100; R is —H or CH3 each R1 and R2 are independently selected from the group consisting of —H, —CH3, —CH2—CH2—OH and CH(CH3)—CH2—OH; d is from 1 to about 6; and n is from 1 to about 4. Such gas hydrate inhibitor compositions are particularly efficacious in the treatment of media susceptible to gas hydrate formation that may occur during the extraction of natural gas and petroleum fluids, such as low boiling hydrocarbons, from a producing well, during transportation of such gas and fluids, and during processing of such gas and fluids.

摘要翻译： 用于抑制气体水合物的形成和/或生长的组合物含有至少一种低剂量动力学水合物抑制剂和至少一种热力学水合物抑制剂。 活性水合物抑制剂包括下列化学式的胺化聚亚烷基二醇：<？in-line-formula description =“In-line formula”end =“lead”？> R＆lt; 2＆lt; 2＆gt; 2 - （A） - （CH 2） - （B）b - （A） -CH（R）-NR 1 H 2 R 2（I） 式描述=“In-line Formulas”end =“tail”？>其中：A各自独立地选自-CH 2 CH（CH 3 CH 3）O-或 - CH（CH 3 CH 2）CH 2 O-; B是-CH 2 CH 2 O 2; a + b + c为1至约100; R是-H或CH 3，每个R 1和R 2各自独立地选自-H，-CH 2， 3个，-CH 2 CH 2 CH 2，和CH（CH 3）2 CH 2。 -OH; d为1〜6; 并且n为1至约4.这种气体水合物抑制剂组合物特别有效地用于处理在从生产井中提取天然气和石油流体（例如低沸点烃）期间可能发生的天然气水合物形成易受影响的介质 在运输这种气体和流体期间以及在处理这种气体和流体期间。

公开(公告)号：US20060065396A1

公开(公告)日：2006-03-30

申请号：US11199378

申请日：2005-08-09

申请人： Jeffrey Dawson ,  Leonard Kalfayan ,  Paul Javora ,  Mark Vorderbruggen ,  Joseph Kirk ,  Qi Qu

发明人： Jeffrey Dawson ,  Leonard Kalfayan ,  Paul Javora ,  Mark Vorderbruggen ,  Joseph Kirk ,  Qi Qu

IPC分类号： E21B43/22

CPC分类号： C09K8/508 ,  C09K8/512 ,  C09K8/52 ,  C09K2208/22

摘要： The present invention relates to compositions of aqueous compositions comprising relative permeability modifier (RPM) macromolecules and one or more formation damage control additives, for use in treating hydrocarbon-producing wells, formations, and equipment, as well as methods for the use of such compositions. Such compositions, comprising the RPM macromolecule and the one or more formation damage control additive, such as a scale control agent, can result in the formation of a composition wherein the components exhibit a “synergistic” effect, whereby the ability of the formation damage control additive to prevent formation damage is enhanced relative to the use of the same additive separately.

摘要翻译： 本发明涉及包含相对渗透性调节剂（RPM）大分子和一种或多种用于处理产油井，地层和设备的地层损伤控制添加剂的含水组合物的组合物，以及使用这种组合物的方法 。 包含RPM大分子和一种或多种地层损伤控制添加剂如鳞屑控制剂的组合物可导致组合物的形成，其中组分表现出“协同”效应，由此地层损伤控制的能力 相对于单独使用相同的添加剂，增加了防止地层损伤的添加剂。

公开(公告)号：US20050037928A1

公开(公告)日：2005-02-17

申请号：US10846994

申请日：2004-05-14

申请人： Qi Qu ,  David Alleman

发明人： Qi Qu ,  David Alleman

IPC分类号： C09K8/60 ,  C09K8/76 ,  C09K7/02

CPC分类号： C09K8/74 ,  C09K8/601 ,  C09K8/602 ,  C09K8/76 ,  C09K2208/26 ,  C09K2208/30 ,  Y10S507/922

摘要： A process for enhancing the productivity of a formation consists of introducing into the formation a viscoelastic fluid which contains at least one surfactant, at least one quaternary amine polyelectrolyte, water, and a non-aqueous solvent. The surfactant forms aggregation structures or vesicles. The fluid, which significantly enhances fluid viscosity and thermal stability, is particularly effective as a diverting fluid to divert an acid treatment package from a high permeability or damaged portion of a formation to a low permeability or undamaged portion of a formation as well as a fracturing fluid. In addition, the fluid is useful for sand control completion.

摘要翻译： 提高地层生产率的方法包括向地层中引入含有至少一种表面活性剂，至少一种季胺聚电解质，水和非水溶剂的粘弹性流体。 表面活性剂形成聚集结构或囊泡。 显着提高流体粘度和热稳定性的流体作为将酸处理包从地层的高渗透性或损坏部分转移到地层的低渗透性或未损伤部分以及压裂的转向流体是特别有效的 流体。 此外，该流体可用于防砂完成。