Cluster compounds and methods of making the same

    公开(公告)号:US12103906B2

    公开(公告)日:2024-10-01

    申请号:US17443389

    申请日:2021-07-26

    CPC classification number: C07C303/34 C02F1/683 C07C211/04

    Abstract: Disclosed herein are clusters compounds that include at least one substituted amine sulfate and at least one substituted amine bisulfate molecule. The substituted amine sulfate molecule and the substituted amine bisulfate molecule may each include an ammonium moiety with at least one alkyl substituent. Optionally, the alkyl substituent can include 1 to 20 carbon atoms, 1 to 10 carbon atoms, or 1 to 6 carbon atoms. For example, the alkyl substituent can be a methyl, ethyl, propyl, butyl, or pentyl group. In some examples, the substituted amine sulfate molecule and the substituted amine bisulfate molecule each include an ammonium moiety with at least two alkyl substituents. Optionally, the two alkyl substituents are the same. Alternatively, however, the two alkyl substituents can be different.

    SCALABLE ANION CAPTURE MACROCYCLES
    3.
    发明公开

    公开(公告)号:US20240262839A1

    公开(公告)日:2024-08-08

    申请号:US18104469

    申请日:2021-10-13

    CPC classification number: C07D487/22 C02F1/683 C02F2101/12

    Abstract: The present disclosure concerns scalable single-pot synthesis, anion binding features, liquid-liquid extraction of salts of the triazolophane macrocycle of Formula (I):




    wherein the substituents R are independently selected from the group consisting of a linear and branched alkyl, a linear and branched alkyl substituted with an ionizable functional group such as an amine or carboxylic acid, a linear and branched alkoxy (R=—OR), an alkyl comprising —O(CH2CH2O)nCH3, where n is 1-20, an amide —CO—NR1R2, where R1 is any alkyl, organic substituent, R2 is any alkyl, organic substituent, wherein R1 and R2 may be identical or different, —OCO—R, wherein R is any alkyl, organic substituent, an aromatic ring and their substituted analogues, any length and sequence of natural and unnatural amino acids that make up a peptide chain, and —C≡C—R where R is any alkyl, organic substituent.

    METHOD FOR EXTRACTING SALTS AND TEMPERATURE-REGENERATED EXTRACTING COMPOSITION

    公开(公告)号:US20230382775A1

    公开(公告)日:2023-11-30

    申请号:US18365309

    申请日:2023-08-04

    Applicant: ADIONICS

    CPC classification number: C02F5/10 C22B3/381 C02F1/683 C22B3/44 C02F2101/10

    Abstract: A temperature-regenerated hydrophobic liquid composition includes an extracting molecule of a non-alkaline cationic species, a solvating molecule of a complimentary anionic species and a fluidizing agent. The extracting molecule of a non-alkaline cationic species is a macrocycle of which the ring is formed from 24-32 carbon atoms and has the following formula (I) or (II): wherein —n is an integer ranging from 5 to 8, —p is 1 or 2, —m is 3 or 4, —q and t, which may be identical or different, are 0, 1 or 2, —R is a tert-butyl, tert-octyl, O-methyl, O-ethyl, O-propyl, O-isopropyl, O-butyl, O-isobutyl, O-pentyl, O-hexyl, O-heptyl, O-octyl, or OCH2Phenyl group or a hydrogen atom, and —R′ and R″, which may be identical or different, are chosen from methyl, ethyl, propyl, isopropyl, butyl, isobutyl, heptyl and octyl groups or R′ and R″ together form a pyrrolidine, piperidine or morpholine ring.

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