R-Fe-B sintered magnet and making method

    公开(公告)号:US11315710B2

    公开(公告)日:2022-04-26

    申请号:US15617510

    申请日:2017-06-08

    摘要: An R—Fe—B base sintered magnet is provided consisting essentially of R (which is at least two rare earth elements and essentially contains Nd and Pr), M1 which is at least two of Si, Al, Mn, Ni, Cu, Zn, Ga, Ge, Pd, Ag, Cd, In, Sn, Sb, Pt, Au, Hg, Pb, and Bi, M2 which is at least one of Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, and W, boron, and the balance of Fe, and containing an intermetallic compound R2(Fe,(Co))14B as a main phase. The magnet contains an R—Fe(Co)-M1 phase as a grain boundary phase, the R—Fe(Co)-M1 phase contains A phase which is crystalline with crystallites of at least 10 nm formed at grain boundary triple junctions, and B phase which is amorphous and/or nanocrystalline with crystallites of less than 10 nm formed at intergranular grain boundaries and optionally grain boundary triple junctions.

    R-T-B based permanent magnet
    53.
    发明授权

    公开(公告)号:US11309108B2

    公开(公告)日:2022-04-19

    申请号:US16818308

    申请日:2020-03-13

    申请人: TDK Corporation

    发明人: Hikaru Kudo

    摘要: A permanent magnet includes Nd, Fe, B, and Ga and contains a first T rich phase 1, a second T rich phase 3, and a T poor phase 5 as grain boundary phases, the first T rich phase 1 satisfies 1.7≤[T]/[R]≤3.0, the second T rich phase 3 satisfies 0.8≤[T]/[R]≤1.5, the T poor phase 5 satisfies 0.0≤[T]/[R]≤0.6, and the following Formulas 4 and 5 are satisfied. [T] represents the concentration (atom %) of Fe and Co, [R] represents the concentration (atom %) of Nd, Pr, Tb, and Dy, S1 represents the area of the first T rich phase 1 exposed at a cross-section of the permanent magnet, S2 represents the area of the second T rich phase 3 exposed at the cross-section, and S3 represents the area of the T poor phase 5 exposed at the cross-section. 0.30≤(S1+S2)/(S1+S2+S3)≤0.80  (4) 0.20≤S2/(S1+S2)≤0.80  (5)

    Iron-based nanoparticles and grains

    公开(公告)号:US11161175B2

    公开(公告)日:2021-11-02

    申请号:US16340031

    申请日:2017-10-06

    摘要: Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.

    R-T-B BASED PERMANENT MAGNET
    59.
    发明申请

    公开(公告)号:US20210304929A1

    公开(公告)日:2021-09-30

    申请号:US17202424

    申请日:2021-03-16

    申请人: TDK Corporation

    摘要: Provided is a permanent magnet including a rare-earth element R (such as Nd), a transition metal element T (such as Fe), B, Zr, and Cu. The permanent magnet contains a plurality of main phase grains including Nd, T, and B, and grain boundary multiple junctions, the one grain boundary multiple junction is a grain boundary surrounded by three or more of the main phase grains, one of the grain boundary multiple junctions contains a ZrB2 crystal and an R—Cu-rich phase including R and Cu, Fe is contained in the ZrB2 crystal, a total concentration of Nd and Pr in the one grain boundary multiple junction containing both the ZrB2 crystal and the R—Cu-rich phase is higher than a total concentration of Nd and Pr in the main phase grain, a concentration of Cu in the one grain boundary multiple junction containing both the ZrB2 crystal and the R—Cu-rich phase is higher than a concentration of Cu in the main phase grain, and a unit of the concentration of each of Nd, Pr, and Cu is atomic %.

    R-T-B-based rare earth magnet particles, and bonded magnets containing R-T-B-based rare earth magnet particles

    公开(公告)号:US11120932B2

    公开(公告)日:2021-09-14

    申请号:US14205894

    申请日:2014-03-12

    申请人: TODA KOGYO CORP.

    摘要: An object of the present invention is to enhance a coercive force of magnetic particles by promoting formation of a continuous R-rich grain boundary phase in a crystal grain boundary of a magnetic phase of the particles, and to thereby obtain R-T-B-based rare earth magnet particles further having a high residual magnetic flux density. The present invention relates to production of R-T-B-based rare earth magnet particles capable of exhibiting a high coercive force even when a content of Al therein is reduced, and a high residual magnetic flux density, in which formation of an R-rich grain boundary phase therein can be promoted by heat-treating Al-containing R-T-B-based rare earth magnet particles obtained by HDDR treatment in vacuum or in an Ar atmosphere at a temperature of not lower than 670° C. and not higher than 820° C. for a period of not less than 30 min and not more than 300 min.