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61.发明授权公开(公告)号：US11578899B2
公开(公告)日：2023-02-14
申请号：US17840674
申请日：2022-06-15
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor： Sheng Peng , Mario Joseph Nappa
IPC: C07C21/18 , F25B13/00 , C07C17/357
Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.
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公开(公告)号：US11547990B2
公开(公告)日：2023-01-10
申请号：US17455974
申请日：2021-11-22
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor： Mario Joseph Nappa
Abstract: A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein Rf is a perfluorinated alkyl group.
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公开(公告)号：US11434185B2
公开(公告)日：2022-09-06
申请号：US17218446
申请日：2021-03-31
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor： Mario Joseph Nappa , Xuehui Sun , David Richard Corbin
IPC: C07C17/389 , C07C17/25 , C07C17/087
Abstract: This disclosure relates to processes which involve: contacting a mixture comprising at least one fluoroolefin and at least one impurity with at least one zeolite to reduce the concentration of the at least one impurity in the mixture; and the at least one zeolite is selected from the group consisting of zeolites having pore opening of at least 4 Angstroms and no more than about 5 Angstroms, zeolites having pore opening of at least about 5 Angstroms and Sanderson electronegativity of no more than about 2.6, and mixtures thereof; provided that the at least one zeolite is not zeolite 4A. This disclosure also relates to processes for making at least one hydrotetrafluoropropene product selected from the group consisting of CF3CF═CH2, CF3CH═CHF, and mixtures thereof; and relates to processes for making at least one hydrochlorotrifluoropropene product selected from the group consisting of CF3CCl═CH2, CF3CH═CHCl, and mixtures thereof.
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64.发明申请公开(公告)号：US20220268493A1
公开(公告)日：2022-08-25
申请号：US17733563
申请日：2022-04-29
Applicant: The Chemours Company FC, LLC
Inventor： Sheng Peng , Mario Joseph Nappa
IPC: F25B13/00 , C07C17/357 , C07C21/18
Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.
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公开(公告)号：US11312890B2
公开(公告)日：2022-04-26
申请号：US17233982
申请日：2021-04-19
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor： Barry Asher Mahler , Mario Joseph Nappa
IPC: C09K5/04 , C07C17/04 , C07C17/087 , C07C17/20 , C07C17/25 , C07C19/08 , C07C19/10 , C07C19/12 , C07C21/04 , C07C21/18 , C08J9/14 , C09K3/30 , A62D1/00 , B01F17/00 , C09K3/00 , C11D7/30 , H01B3/56 , C07C17/23 , C09K21/08
Abstract: Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF═CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.
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Patent Agency Ranking
公开(公告)号：USRE48889E1
公开(公告)日：2022-01-11
申请号：US16193924
申请日：2018-11-16
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor： Sheng Peng , Mario Joseph Nappa
IPC: C07C17/25
Abstract: A method of producing a fluoropropane fluoropropene of formula CF3CH═CHF, comprising contacting a mixture of 1,1,1,3,3-pentafluoropropane and Z-1,3,3,3-tetrafluoropropene in the gas phase with a catalyst comprising at least one catalyst selected from the group consisting of fluorinated Cr2O3 or Cr/Ni on fluoride alumina, in the presence of an oxygen containing gas, to form a mixture comprising Z-1,3,3,3-tetrafluoropropane Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3,-tetrafluoropropene, hydrogen fluoride, and optionally unreacted 1,1,1,3,3-pentafluoropropane, separating the E-1,3,3,3-tetrafluoropropene from the Z-isomer and any unreacted 1,1,1,3,3-pentafluoropropane, if present, and recovering said E-1,3,3,3-tetrafluoropropene.
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公开(公告)号：US11130894B2
公开(公告)日：2021-09-28
申请号：US16715725
申请日：2019-12-16
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor： Andrew Edward Feiring , Viacheslav A. Petrov , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Thomas Joseph Leck , Jon Lee Howell
Abstract: The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling to apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
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公开(公告)号：US11124685B2
公开(公告)日：2021-09-21
申请号：US16733356
申请日：2020-01-03
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor： Mario Joseph Nappa , Barbara Haviland Minor , Allen Capron Sievert
Abstract: The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.
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公开(公告)号：US11053421B2
公开(公告)日：2021-07-06
申请号：US16458350
申请日：2019-07-01
Applicant: THE CHEMOURS COMPANY FC, LLC
IPC: C09K5/04 , C07C17/00 , C07C17/087 , C07C17/20 , C07C17/23 , C07C17/354 , C07C19/08 , C07C19/10
Abstract: A process is disclosed for making CF3CF═CHF. The process involves reacting CF3CClFCCl2F with H2 in a reaction zone in the presence of a catalyst to produce a product mixture comprising CF3CF═CHF. The catalyst has a catalytically effective amount of palladium supported on a support selected from the group consisting of alumina, fluorided alumina, aluminum fluoride and mixtures thereof and the mole ratio of H2 to CF3CClFCCl2F fed to the reaction zone is between about 1:1 and about 5:1. Also disclosed are azeotropic compositions of CF3CClFCCl2F and HF and azeotropic composition of CF3CHFCH2F and HF.
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公开(公告)号：US11046877B1
公开(公告)日：2021-06-29
申请号：US17205875
申请日：2021-03-18
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor： Mario Joseph Nappa , Barbara Haviland Minor , Allen Capron Sievert
Abstract: The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.
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