公开(公告)号：US20150011804A1

公开(公告)日：2015-01-08

申请号：US14382082

申请日：2013-02-25

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haiyou Wang ,  Selma Bektesevic ,  Hsueh S. Tung ,  Haluk Kopkalli ,  Yuon Chiu

IPC: C07C17/35 ,  C07C17/38

CPC classification number: C07C17/35 ,  C07C17/206 ,  C07C17/38 ,  Y02P20/582 ,  C07C21/18

Abstract: The present invention relates, in part, an improved process for the production of certain hydrofluoroolefins, particularly 2,3,3,3-tetrafluoropropene (1234yf). In certain non-limiting embodiments, the invention relates to methods for improving process efficiency during the fluorination of 1,1,2,3-tetrachloropropene, 2,3,3,3-tetrachloropropene, and/or 1,1,1,2,3-pentachloropropane to 2-chloro-3,3,3-trifluoropropene by separating and recycling unreacted HF, unreacted starting materials, and/or certain pro cess intermediates from the 2-chloro-3,3,3-trifluoropropene product stream.

Abstract translation: 本发明部分地涉及用于生产某些氢氟烯烃，特别是2,3,3,3-四氟丙烯（1234yf）的改进方法。 在某些非限制性实施方案中，本发明涉及在1,1,2,3-四氯丙烯，2,3,3,3-四氯丙烯和/或1,1,1,2,3-四氯丙烯的氟化期间提高工艺效率的方法 通过从2-氯-3,3,3-三氟丙烯产物流中分离和循环未反应的HF，未反应的起始物质和/或某些过程中间体，将3-五氯丙烷加入到2-氯-3,3,3-三氟丙烯中。

公开(公告)号：US08859829B2

公开(公告)日：2014-10-14

申请号：US14203714

申请日：2014-03-11

Applicant: Honeywell International Inc.

Inventor： Haluk Kopkalli ,  Haiyou Wang ,  Hsueh Sung Tung ,  Daniel C. Merkel

IPC: C07C17/20 ,  C07C17/00 ,  C09K15/32 ,  C09K15/16 ,  C09K15/06 ,  C07C17/42

CPC classification number: C09K15/30 ,  C07C17/087 ,  C07C17/202 ,  C07C17/206 ,  C07C17/25 ,  C07C17/42 ,  C07C21/04 ,  C07C19/10

Abstract: The present invention relates in part to a method of stabilizing chloropropenes, such as 1,1,2,3-tetrachloropropene, otherwise known to decompose and degrade, and to the resulting stabilized chloropropene, using a morpholine compound and/or a trialkyl phosphate compound as defined herein. Such stabilized chloropropenes are useful in the manufacture of hydrofluoroolefins such as 2,3,3,3-tetrafluoroprop-1-ene (1234yf).

Abstract translation: 本发明部分地涉及使用吗啉化合物和/或三烷基磷酸酯化合物稳定氯丙烯如1,1,2,3-四氯丙烯或另外已知分解和降解的方法和所得稳定的氯丙烯的方法 如本文所定义。 这种稳定的氯丙烯可用于制备氢氟烯烃，例如2,3,3,3-四氟丙-1-烯（1234yf）。