摘要:
An asymmetric chain carbonate can be produced in a single-step reaction comprising a step of reacting methyl nitrite, carbon monoxide, and 0.05-1.5 moles of an aliphatic alcohol having 2-6 carbon atoms or an alicyclic alcohol having 5-6 carbon atoms per one mole of methyl nitrile in a gaseous phase in the presence of a solid catalyst comprising a platinum group metal or a compound thereof placed on a support.
摘要:
A nonaqueous electrolytic solution for lithium battery comprises an electrolyte salt dissolved in a nonaqueous solvent and contains a carboxylate compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution. (In the formula R1 and R2 each independently represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; R3 represents a hydrogen atom, a methyl group, or a group —CH2CO2CR1R2C≡CH (R1 and R2 have the same meaning as above) .) A lithium battery uses the nonaqueous electrolytic solution having excellent cycle property and storage property.
摘要翻译:用于锂电池的非水电解液包含溶解在非水溶剂中的电解质盐,并且含有由以下通式(I)表示的羧酸盐化合物,其量为非水电解液的0.01至10质量%。 (式中,R 1和R 2各自独立地表示氢原子或碳原子数1〜6的烷基,R 3表示氢原子,甲基或基团-CH 2 CO 2 CR 1 R 2C≡CH(R 1和R 2相同 如上所述)。锂电池使用具有优异的循环性能和储存性能的非水电解液。
摘要:
In a rechargeable non-aqueous electrolyte secondary battery using positive electrodes, negative electrodes and a non-aqueous electrolytic solution, additives to the electrolytic solution are used in combination, preferably in combination of at least two compounds selected from o-terphenyl, triphenylene, cyclohexylbenzene and biphenyl, and thus there are provided batteries excellent in safety and storage characteristics.
摘要:
A nonaqueous electrolyte secondary battery including a negative electrode containing a graphite material as the negative active material, a positive electrode containing lithium cobalt oxide as a main component of the positive active material and a nonaqueous electrolyte solution, the battery being characterized in that the lithium cobalt oxide contains a group IVA element selected from the group consisting of Ti, Zr and Hf and a group IIA element of the periodic table, the nonaqueous electrolyte solution contains 0.2-1.5% by weight of a sulfonyl-containing compound and preferably further contains 0.5-4% by weight of vinylene carbonate.
摘要:
The present invention provides a nonaqueous electrolytic solution exhibiting excellent battery characteristics such as electrical capacity, cycle property and storage property and capable of maintaining the battery characteristics for a long tire, and a lithium secondary battery using the nonaqueous electrolytic solution.A nonaqueous electrolytic solution for a lithium secondary battery, in which an electrolyte salt is dissolved in a nonaqueous solvent, containing 0.1 to 10% by weight of an ethylene carbonate derivative represented by the general formula (I) shown below, and 0.01 to 10% by weight of (A) a triple bond-containing compound and/or (B) a pentafluorophenyloxy compound represented by the general formula (X) shown below: wherein R1 to R3 each independently represents a hydrogen atom, a halogen atom, an alkenyl group, an alkynyl group or an aryl group, provided that ethylene carbonate is excluded from the definition of the ethylene carbonate derivative, wherein R15 represents an alkylcarbonyl group, an alkoxycarbonyl group, an aryloxycarbonyl group or an alkanesulfonyl group.
摘要:
In a heat treatment method for supplying transforming gas and enriched gas inside a furnace and heat treating a workpiece inside the furnace, feedback control of carbon potential is performed by operating a supply flow rate of the enriched gas based on carbon potential inside the furnace, the feedback control is stopped before an opening of the furnace is opened and supply flow rates of the transforming gas and the enriched gas are increased from supply flow rates thereof immediately before the feedback control is stopped; and the supply flow rate of the transforming gas is returned to the supply flow rate thereof immediately before the feedback control is stopped and the feedback control is resumed after the opening of the furnace is closed.
摘要:
The present invention provides (1) a sulfone compounds having a propargyl group, (2) a nonaqueous electrolytic solution for lithium secondary batteries, which comprises an electrolyte salt dissolved in a nonaqueous solvent and contains a sulfone compound having a specific structure that has an SO2 group with a propargyl group or a vinyl group bonding thereto, in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution, and which can prevent gas generation and is excellent in battery characteristics such as cycle property and the like, and (3) a lithium secondary battery comprising a positive electrode, a negative electrode and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution contains a sulfone compound having a specific structure, in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution.
摘要:
The present invention provides a lithium secondary battery having excellent battery cycle property, electrical capacity, storage characteristic and other battery characteristics for a long period of time, and a nonaqueous electrolytic solution which is usable for the lithium secondary battery.A nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprising (i) a dicarbonyl compound represented by the general formula (I), or (ii) a dicarbonyl compound represented by the general formula (II) and vinylene carbonate and the like in the nonaqueous electrolytic solution. (wherein R1 represents a hydrogen atom, an alkyl group, an alkenyl group, a phenyl group or the like; and X represents a hydrogen atom, an R2 group or an OR2 group. R2 represents an alkyl group, an alkenyl group, a phenyl group or the like.) (wherein R1 and X are the same as above; Y and Z represents a hydrogen atom, an R2 group, an OR2 group, a COR2 group or a CH2COR2 group; and n is 1 to 6.).
摘要:
In order to manufacture a lithium secondary battery having excellent performances in safety under overcharge condition, cycle property, electric capacity, and storage endurance, 0.1 wt. % to 10 wt. % of a tert-alkylbenzene compound is favorably incorporated into a non-aqueous electrolytic solution comprising a non-aqueous solvent and an electrolyte, preferably in combination with 0.1 wt. % to 1.5 wt. % of a biphenyl compound.
摘要:
A separator is disclosed which enables to inject a non-aqueous electrolytic solution easily during production of batteries such as lithium ion secondary batteries and also enables to produce a battery which is excellent in various battery performances.The battery separator comprises a long porous film in which plural non-porous linear regions are arranged in a width direction of the film, at least one surface of the linear regions being a concave or convex surface is advantageously used as a battery separator for lithium secondary batteries or the like.