公开(公告)号：US4536345A

公开(公告)日：1985-08-20

申请号：US535878

申请日：1983-09-26

申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

IPC分类号： C07C255/39 ,  A01N53/00 ,  C07C67/00 ,  C07C213/00 ,  C07C253/00 ,  C07C121/46

CPC分类号： A01N53/00

摘要： Novel imino derivatives of esters of 3-formyl-cyclopropane-1-carboxylic acids in their various isomeric forms and mixtures thereof of the formula ##STR1## wherein Z is an organic residue of a primary amine of the formula Z--NH.sub.2 and the acid moiety may have the cis or trans configuration and the alcohol moiety may have the R,S or RS configuration, novel intermediates therefore and a process for the preparation of the corresponding 3-substituted vinyl esters having insecticidal activity.

摘要翻译： 3-甲酰基 - 环丙烷-1-羧酸酯的各种异构体形式的新颖的亚氨基衍生物及其混合物，其中Z是式Z-NH 2的伯胺和酸的有机残基 部分可以具有顺式或反式构型，并且醇部分可以具有R，S或RS构型，因此是新的中间体，以及制备相应的具有杀虫活性的3-取代乙烯基酯的方法。

公开(公告)号：US4450169A

公开(公告)日：1984-05-22

申请号：US352257

申请日：1982-02-25

申请人： Francois Nezot ,  Pierre Girault ,  Jean Tessier ,  Jacques Martel

发明人： Francois Nezot ,  Pierre Girault ,  Jean Tessier ,  Jacques Martel

IPC分类号： A01N43/836 ,  A01N43/78 ,  A01N43/82 ,  A01N53/00 ,  A01N53/04 ,  A01N53/06 ,  A23K1/16 ,  A61K31/41 ,  A61K31/425 ,  A61K31/426 ,  A61K31/433 ,  A61P31/00 ,  A61P33/10 ,  C07D277/20 ,  C07D277/24 ,  C07D277/30 ,  C07D277/34 ,  C07D277/56 ,  C07D285/08 ,  C07D417/12

CPC分类号： C07D285/08 ,  A01N43/78 ,  A01N43/82 ,  A01N53/00 ,  C07D277/24 ,  C07D277/30 ,  C07D277/34 ,  C07D277/56

摘要： Novel esters of the formula ##STR1## wherein R is selected from the group consisting of ##STR2## W is selected from the group consisting of hydrogen and --CN, Z is selected from the group consisting of --CH.sub.2 -- and --O--, and is attached to a carbon atom included between a nitrogen and the sulfur atom of Y and Y is selected from the group consisting of thiazolyl or thiadiazolyl connected to ##STR3## at one of its available positions.

摘要翻译： 其中R选自由下列组成的组成的组的下式的新颖的酯：其中R选自氢和-CN，Z选自-CH 2 - 和-O-， 并且连接到包含在氮和Y的硫原子之间的碳原子上，Y选自噻唑基或噻二唑基，其在其可用位置之一处连接到“IMAGE”。

公开(公告)号：US4374257A

公开(公告)日：1983-02-15

申请号：US232117

申请日：1981-02-06

申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

IPC分类号： B01J31/02 ,  C07B31/00 ,  C07B57/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/10 ,  C07C29/88 ,  C07C37/86 ,  C07C41/18 ,  C07C43/295 ,  C07C45/57 ,  C07C51/487 ,  C07C62/02 ,  C07C62/04 ,  C07C67/00 ,  C07D307/33 ,  C07D307/88 ,  C07D307/93 ,  C07D315/00 ,  C07D307/94

CPC分类号： C07D307/33 ,  C07C29/10 ,  C07C41/26 ,  C07C43/295 ,  C07C45/57 ,  C07D307/93 ,  C07D315/00 ,  C07B2200/07 ,  C07C2101/14

摘要： Novel ethers of organic compounds containing chiral atoms of the formula ##STR1## wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymetric carbon atom, a phenol moiety substituted comprising at least one asymetric carbon atom and an substituted alcohol or phenol moiety with a chirality due to the dissymetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) .alpha.-cyano-3-phenoxy-benzyl when A is ##STR2## which are useful for the resolution of compounds of the formulae ##STR3## wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms.

摘要翻译： 含有式（I）的手性原子的有机化合物的新型醚，其中A是1至10个基团的烃化链，所述链含有一个或多个杂原子，一个或多个不饱和基团，构成链的基团的组合 代表单环或多环系统，包括螺或内型的系统，链A可以含有一个或多个手性原子，或者内酯部分可以呈现手性，这是由于整个分子的不对称空间结构和Z 选自包含至少一个不对称碳原子的伯，仲或叔醇部分，被至少一个不对称碳原子取代的苯酚部分和具有手性的取代的醇或苯酚部分，这些部分具有由于不对称空间构型的手性 整个分子，条件是Z不是（R）或（S）α-氰基-3-苯氧基 - 苄基，当A是，其可用于分辨c 其中A和Z具有上述定义并且X选自氢和1至4个碳原子的烷基的式的化合物。

公开(公告)号：US4312817A

公开(公告)日：1982-01-26

申请号：US212566

申请日：1980-12-03

申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

IPC分类号： C07C255/39 ,  A01N53/00 ,  C07C67/00 ,  C07C213/00 ,  C07C253/00 ,  C07C121/84

CPC分类号： A01N53/00

摘要： Novel imino derivatives of esters of 3-formyl-cyclopropane-1-carboxylic acids in their various isomeric forms and mixtures thereof of the formula ##STR1## wherein Z is an organic residue of a primary amine of the formula Z-NH.sub.2 and the acid moiety may have the cis or trans configuration and the alcohol moiety may have the R,S or RS configuration, novel intermediates therefore and a process for the preparation of the corresponding 3-substituted vinyl esters having insecticidal activity.

摘要翻译： 3-甲酰基 - 环丙烷-1-羧酸酯的各种异构体形式的新颖的亚氨基衍生物及其混合物，其中Z是式Z-NH 2的伯胺和酸的有机残基 部分可以具有顺式或反式构型，并且醇部分可以具有R，S或RS构型，因此是新的中间体，以及制备相应的具有杀虫活性的3-取代乙烯基酯的方法。

公开(公告)号：US4205008A

公开(公告)日：1980-05-27

申请号：US945328

申请日：1978-09-25

申请人： Jacques Martel ,  Jean Tessier

发明人： Jacques Martel ,  Jean Tessier

IPC分类号： C07C45/67 ,  C07C143/68

CPC分类号： C07C309/00 ,  C07C45/673

摘要： Optically active sulfonates of allethrolone of the formula ##STR1## wherein X is selected from the group consisting of alkyl of 1 to 3 carbon atoms and phenyl optionally substituted in the para position with a member selected from the group consisting of methyl, fluorine, chlorine and bromine with an (R) or (S) configuration which are useful for obtaining optically active allethrolone of antipodal configuration and process for their preparation.

摘要翻译： 其中X选自1至3个碳原子的烷基和在对位任选被取代的苯基的光学活性磺酸盐，其中X选自甲基，氟，氯 和具有（R）或（S）构型的溴，其可用于获得对映体形式的光学活性羟基噻吩酮及其制备方法。

公开(公告)号：US4431576A

公开(公告)日：1984-02-14

申请号：US343348

申请日：1982-01-27

申请人： Jacques Martel ,  Jean Buendia ,  Francois Nezot

发明人： Jacques Martel ,  Jean Buendia ,  Francois Nezot

IPC分类号： C07C69/747 ,  A01N53/06 ,  A01N53/10 ,  A61K8/37 ,  A61Q13/00 ,  C07D307/54 ,  C07D307/58 ,  C07D333/24 ,  C07D333/32 ,  C11B9/00 ,  A61K7/46

CPC分类号： C11B9/0092 ,  C07D307/54 ,  C07D333/24 ,  C11B9/003 ,  C11B9/0076

摘要： A compound in all its possible isomeric forms and mixtures thereof of the formula ##STR1## wherein R is selected from the group consisting of (a) alkyl of 1 to 12 carbon atoms optionally substituted with cycloalkyl or cycloalkenyl of 3 to 6 carbon atoms or a hydrocarbon chain of 2 to 8 carbon atoms optionally interrupted by an oxygen or ketone, (b) alkenyl and alkynyl of 3 to 8 carbon atoms, (c) cycloalkyl of 3 to 12 carbon atoms optionally containing at least one double bond and substituted with at least one alkyl and (d) aralkyl of 7 to 12 carbon atoms optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen and --CF.sub.3 and R.sub.1 and R.sub.2 are individually selected from the group consisting of hydrogen, --CHO, --COAlK.sub.1, --COOAlK.sub.2 and --CN, at least one being hydrogen, AlK.sub.1 and AlK.sub.2 are alkyl of 1 to 8 carbon atoms and R.sub.1 and R.sub.2 taken together with the carbon atom to which they are attached form the group ##STR2## and X is selected from the group consisting of sulfur, oxygen and imino joined to the 1-carbon atom with a double bond with the proviso that the double bond has the E geometry when R.sub.1 or R.sub.2 are --CHO, --COAlK.sub.1, --COOAlK.sub.2 or ##STR3## and their preparation and odorant compositions containing at least one compound of formula I as a perfume agent.

摘要翻译： 化合物，其全部可能的异构形式及其混合物，其中R选自（a）任选被3至6个碳原子的环烷基或环烯基取代的1至12个碳原子的烷基或 2至8个碳原子的烃链任选被氧或酮中断，（b）3至8个碳原子的烯基和炔基，（c）3至12个碳原子的环烷基，任选地含有至少一个双键并被 至少一个烷基和（d）7-12个碳原子的芳烷基，任选被至少一个1-4个碳原子的烷基，1-4个碳原子的烷氧基，卤素和-CF 3和R 1和 R2分别选自氢，-CHO，-COAlK1，-COOAlK2和-CN，至少一个为氢，AlK1和AlK2为1至8个碳原子的烷基，R1和R2与碳原子一起 它们所连接的组由和X选自硫，氧和亚氨基与具有双键的1-碳原子连接，条件是当R1或R2为-CHO，-COAlK1， - COOAlK2或及其制备和加味剂组合物，其含有至少一种式I化合物作为预浸剂。

公开(公告)号：US4283727A

公开(公告)日：1981-08-11

申请号：US4985

申请日：1979-01-19

申请人： Jacques Martel ,  Roger Famin

发明人： Jacques Martel ,  Roger Famin

IPC分类号： H01P1/06 ,  H01Q1/34

CPC分类号： H01P1/061

摘要： A transmission path between a source of microwaves, such as a radar transceiver, and a load rectilinearly movable with reference thereto, such as an aerial mounted on a retractable mast of a submarine periscope, comprises two relatively movable parallel waveguides respectively connected to a pair of coaxial ancillary guide portions with mating extremities which are separated from each other in one relative position and are interfitted in another relative position of the source and the load. The male guide portion is externally grooved to form microwave chokes whose effect is enhanced by a peripheral layer of energy-absorbent coating disposed beyond these chokes as seen from the female guide portion. The main waveguides may be coaxial with the interfitting guide portions or may extend parallel thereto and be connected to them by respective elbows.

摘要翻译： 诸如雷达收发器之类的微波源之间的传输路径以及可参照其直线运动的负载，诸如安装在海底潜望镜的可伸缩桅杆上的天线，包括两个相对移动的平行波导，分别连接到一对 同轴辅助引导部分具有配合的四肢，它们在一个相对位置上彼此分离，并且与源极和负载的另一个相对位置相互配合。 阳引导部分是外槽形成微波扼流圈，其效果通过设置在这些扼流圈之外的能量吸收涂层的外围层增强，从阴引导部分看。 主波导可以与相互配合的引导部分同轴，或者可以与其平行延伸并且通过相应的弯头连接到它们。

公开(公告)号：US4014918A

公开(公告)日：1977-03-29

申请号：US616048

申请日：1975-09-23

申请人： Jacques Martel

发明人： Jacques Martel

IPC分类号： A01N53/00 ,  A47F5/00 ,  A47K1/09 ,  C07C51/00 ,  C07C61/35 ,  C07D307/93

CPC分类号： C07D307/93 ,  A01N53/00 ,  A47F5/00 ,  C07C51/00 ,  C07C61/35

摘要： Process for the preparation of racemic or optically-active cyclopropane carboxylic acid of the formula ##STR1## wherein the CO.sub.2 H substituent on the carbon 1 and the ##STR2## substituent on the carbon 2 are in the cis-position relative to one another, R.sub.1 represents a hydrogen, an alkyl radical, an aralkyl radical, an aryl radical, an alkenyl radical, an alkynyl radical, a cycloalkyl radical, a cycloalkenyl radical, a heterocyclic radical, these radicals being able to be substituted, specifically by lower alkyl or lower alkoxy, or represents a cyano group, an acyl group, a formyl group, an alkoxycarbonyl group or a nitro group, and Z represents the R.sub.2 residue which has the same meaning as R.sub.1 but is identical or different thereto, or the R.sub.3 residue, which represents an allyl radical, a benzyl radical, a cyano group, an acyl group, a formyl group, an alkoxycarbonyl group, or a nitro group, or R.sub.1 and Z together form a saturated or unsaturated carbon homocycle or heterocycle, whose ring can support substituents such as lower alkyls or lower alkoxys, or functions such as ketonic functions, or together form a polycyclic aromatic residue such as a fluorene residue.

摘要翻译： 用于制备式I的外消旋或光学活性环丙烷羧酸的方法，其中碳1上的CO 2和取代基上的CO 2 H取代基相对于彼此处于顺式位置，R1 代表氢，烷基，芳烷基，芳基，烯基，炔基，环烷基，环烯基，杂环基，这些基团能够被低级烷基或低级烷基取代 烷氧基，或表示氰基，酰基，甲酰基，烷氧基羰基或硝基，Z表示与R1相同或相同或不同的R 2残基或R 3残基，其中 表示烯丙基，苄基，氰基，酰基，甲酰基，烷氧基羰基或硝基，或者R 1和Z一起形成饱和或不饱和的碳原子或杂环，其环可以 支持取代基如低级烷基或低级烷氧基，或功能如酮酮官能团，或一起形成多环芳族残基如芴残基。

公开(公告)号：US4406829A

公开(公告)日：1983-09-27

申请号：US318445

申请日：1981-11-05

申请人： Jacques Martel ,  Jean Buendia ,  Francois Nezot

发明人： Jacques Martel ,  Jean Buendia ,  Francois Nezot

IPC分类号： C07C69/747 ,  A61K8/37 ,  A61Q13/00 ,  C11B9/00 ,  C07C69/743

CPC分类号： C11B9/0026

摘要： Novel esters of all possible isomers and mixtures thereof of compounds of the formula ##STR1## wherein n is a number of 2,3 or 4 and R is selected from the group consisting of (a) alkyl of 1 to 12 carbon atoms optionally substituted with a member of the group consisting of cycloalkyl of 3 to 6 carbon atoms and a hydrocarbon chain of 2 to 8 carbon atoms optionally interrupted by an oxygen atom or a ketone group, (b) alkenyl and alkynyl of 3 to 8 carbon atoms, (c) cycloalkyl of 3 to 12 carbon atoms optionally containing at least one double bond and optionally substituted with at least one alkyl of 1 to 5 carbon atoms and (d) aralkyl of 7 to 12 carbon atoms optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen and --CF.sub.3 having perfume and insecticidal properties.

摘要翻译： 所有可能的异构体的新型酯及其下式化合物的混合物，其中n是2,3或4的数，R选自（a）任选取代的（a）1至12个碳原子的烷基 与碳原子数为3〜6的环烷基和碳原子数为2〜8的烃链任选被氧原子或酮基中断的基团，（b）碳原子数为3〜8的烯基和炔基，（ c）3至12个碳原子的环烷基，任选地含有至少一个双键并且任选被至少一个1至5个碳原子的烷基取代，和（d）7-12个碳原子的芳烷基，任选被至少一个 由1至4个碳原子的烷基，1至4个碳原子的烷氧基，卤素和具有香料和杀虫性能的-CF 3组成的组。

公开(公告)号：US3997586A

公开(公告)日：1976-12-14

申请号：US395146

申请日：1973-09-07

申请人： Jacques Martel ,  Chanh Huynh ,  Jean Buendia

发明人： Jacques Martel ,  Chanh Huynh ,  Jean Buendia

IPC分类号： C07C317/14 ,  C07D307/54 ,  C07D309/04 ,  C07C69/14 ,  C07C61/12 ,  C07D307/26

CPC分类号： C07C317/14 ,  C07D307/54 ,  C07D309/04

摘要： Novel cyclopropanecarboxylic acids and esters of the formula ##STR1## wherein Z.sub.1 and Z.sub.2 are selected from the group consisting of hydrogen, alkyl, aralkyl, aryl, alkenyl non-conjugated with the cyclopropane ring, alkenyl non-conjugated with the cyclopropane ring, cycloalkyl, cycloalkenyl and heterocyclic; R is selected from the group consisting of OH and OR' in which R' is selected from the group consisting of lower alkyl which may be substituted, benzyl which may be substituted on the phenyl or methylene portion, N-methylene-dicarboximide, (5-benzyl-furyl-3) methyl, and a cyclopentene of the formula ##STR2## WHEREIN R" is selected from the group consisting of alkyl, alkynyl, alkenyl, aryl, aralkyl, cycloalkyl, cycloalkenyl and heterocyclic; A is a bivalent alkyl radical selected from the group consisting of ##STR3## WHEREIN R.sub.1 is selected from the group consisting of hydrogen and lower alkyl, R.sub.2 and R.sub.3 are selected from the group consisting of alkyl, alkynyl, alkenyl, aryl, aralkyl, cycloalkyl, cycloalkenyl and heterocyclic and taken together with the carbon atom to which they are attached form a ring selected from the group consisting of carbon homo rings and unsaturated carbon homo rings of 3 to 7 carbon atoms and heterocyclic rings which may be substituted with lower alkyl or lower alkoxy and R.sub.2 and R.sub.3 may together form a polycyclic aromatic radical, R.sub.4 is lower alkyl, R.sub.5 is selected from the group consisting of hydrogen and lower alkyl and R.sub.4 and R.sub.5 together with the carbon atoms to which they are attached may form a saturated or unsaturated carbon homo ring or a heterocyclic ring, Y is selected from the group consisting of methylene and a saturated or unsaturated carbon chain and Y' is selected from the group consisting of methine and a saturated or unsaturated carbon chain with the proviso that when Z.sub.1 and Z.sub.2 are methyl and R.sub.1 is hydrogen, R.sub.2 is other than methyl and their preparation.