摘要:
A method for preparation of a printing plate by an electrophotographic process comprising providing a peelable transfer layer (T) containing a resin (A) capable of being removed upon a chemical reaction treatment on an electrophotographic light-sensitive element, forming a toner image on the transfer layer by an electrophotographic process, providing an adhesive layer (M) containing a thermoplastic resin (B) only on the toner image, transferring the toner image together with the transfer layer (T) and the adhesive layer (M) from the electrophotographic light-sensitive element to a receiving material having a surface capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing, and then removing the transfer layer (T) on the receiving material by the chemical reaction treatment.According to the method, printing plates which produces prints of good image qualities can be continuously obtained in a stable manner for a long period of time even when the transfer is conducted under conditions of low temperature, low pressure and high speed.
摘要:
A method for preparation of a printing plate by an electrophotographic process comprising forming a peelable transfer layer mainly containing a resin (A) capable of being removed upon a chemical reaction treatment on the surface of an electrophotographic light-sensitive element, forming a toner image on the transfer layer by an electrophotographic process, heat-transferring the toner image together with the transfer layer onto a receiving material a surface of which is capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing, and removing the transfer layer on the receiving material upon the chemical reaction treatment, wherein prior to or simultaneously with the formation of transfer layer a compound (S) which contains a fluorine atom and/or silicon atom is applied to the surface of electrophotographic light-sensitive element to improve releasability of the surface of electrophotographic light-sensitive element.The method continuously provides printing plates excellent in image qualities in a stable manner and is suitable for a scanning exposure system using a laser beam.An apparatus suitable for performing the present method is also disclosed.
摘要:
Disclosed is a method for preparation of a printing plate by an electrophotographic process comprising forming a toner image on an electrophotographic light-sensitive element by an electrophotographic process. A peelable transfer layer is provided mainly containing a resin (A) capable of being removed upon a chemical reaction treatment on the toner image. The toner image is transferred together with the transfer layer onto a primary receptor. The toner image together with the transfer layer is then transferred from the primary receptor onto a receiving material having a surface which is capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing. The transfer layer on the receiving material is removed by the chemical reaction treatment.
摘要:
An amine compound-containing, but cyanogen-free, desensitizing solution for offset printing, characterized by containing phytic acid (inositol hexaphosphate) and/or a metal and/or ammonium salts of phytic acid, and at least one selected from the group consisting of amine compounds represented by the following general formulae (1) and (2); a carboxylic acid or carboxylate containing (3); an urea (5) and/or an urethane (6) containing (4); an amide compound represented by (8) and/or an imide compound (9), each containing an amino group (7); and a heterocyclic compound at least one nitrogen atom and having an inorganic/organic value of 0.1 to 4.0 inclusive. ##STR1##
摘要:
A process of producing a nonaqueous resin dispersion, particularly useful for a liquid developer in electrostatic photographic, which comprises subjecting to photopolymerization a system containing at least a monomer (A) having one polymerizable double bond, which is soluble in a nonaqueous solvent but becomes insoluble upon polymerization thereof, and at least a dispersion stabilizing resin (P) which is a polymer having a weight average molecular weight of from 1.times.10.sup.4 to 1.times.10.sup.6 and containing a specific repeating unit represented by formula (I) in an amount of at least 50% by weight based on the weight of the polymer and has a specific functional group represented by formula (II) bonded to the side chain of the polymer and/or only one terminal of the main chain of the polymer, the photopolymerization reaction being carried out in the nonaqueous solvent by irradiating the system with ultraviolet rays having a wavelength of not longer than 400 n.m.: ##STR1##
摘要:
There is disclosed a liquid developer composition for electrostatic photography, which comprises, in a nonaqueous solvent having an electric resistance of 10.sup.9 .OMEGA..cm or over and a dielectric constant of 3.5 or over, a toner particle, a charge-controlling agent or resin, and an acid group containing polymer soluble in said nonaqueous solvent and/or a quaternary ammonium salt.
摘要:
An electrophotographic lithographic printing plate precursor having a photoconductive layer containing resin (A) having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 and containing a polymer component of the specified repeating unit and a polymer component having a polar group and dispersed resin grain (L) which is obtained by dispersion polymerization of monomer (C) containing a functional group capable of forming at least one group selected from a thiol group, a sulfo group, an amino group and a ##STR1## group upon decomposition in the presence of a dispersion stabilizing resin soluble in a non-aqueous solvent and which has a silicon and/or fluorine atom-containing substituent.The electrophotographic lithographic printing plate precursor has good electrophotographic characteristics and water retentivity due to the suitable interaction between zinc oxide, a spectral sensitizing dye, the resin (A) and the dispersed resin grain (L).
摘要:
An electrophotographic lithographic printing plate, in which the effect by the hydrophilic property of non-image areas is further improved, and which is stable during storage even under very severe conditions and capable of readily realizing the hydrophilic property in a short time during processing of rendering hydrophilic is provided by a process for the production of an electrophotographic lithographic printing plate, comprising subjecting an electrophotographic photoreceptor to imagewise exposure and forming a toner image, the electrophotographic photoreceptor comprising an electroconductive support having provided thereon at least one photoconductive layer containing photoconductive inorganic compound and a binder resin, the binder resin comprising at least one resin (P) as defined herein, and optionally at least one crosslinking agent, and then subjecting a non-image area of the photoconductive layer to an oil-desensitizing processing with a processing solution containing a hydrophilic compound containing a substituent having a Pearson's nucleophilic constant n of at least 5.5.
摘要:
An electrophotographic lithographic printing plate precursor having a conductive support having provided thereon at least one photoconductive layer containing photoconductive zinc oxide and a binder resin, wherein the photoconductive layer contains at least one of the following non-aqueous solvent-dispersed resin grains having an average grain diameter of same as or smaller than the maximum grain diameter of the photoconductive zinc oxide grains: wherein the non-aqueous solvent-dispersed resin grains comprise copolymer resin grains obtained by (i) subjecting to a polymerization reaction in a non-aqueous solvent, a monofunctional monomer (A) being soluble in the non-aqueous solvent but insoluble after polymerization and containing at least one polar group, as described herein, and a monofunctional polymer [M] comprising a polymer principal chain containing at least recurring units each containing a silicon atom and/or fluorine atom-containing substituent, to only one end of which a polymerizable double bond group represented by the following general formula (I), as described herein, is bonded; or (2) subjecting to a dispersion polymerization reaction in a non-aqueous solvent in the presence of a dispersion stabilizing resin soluble in the non-aqueous solvent, a monofunctional monomer (A) being soluble in the non-aqueous solvent but insoluble after polymerization and containing at least one polar group, as described herein, and a monofunctional monomer [B] being copolymerizable with the monofunctional monomer (A) and having a silicon atom and/or fluorine atom-containing substituent.
摘要:
An electrophotographic light-sensitive material comprising a support having provided thereon at least one photoconductive layer containing an inorganic photoconductive substance and a binder resin, wherein the binder resin comprises at least one resin (A) or (A') and at least one resin (B) as described above. The electrophotographic light-sensitive material according to the present invention is excellent in electrostatic characteristics, moisture resistance and durability.