Intermediates for the preparation of triazolinones
    62.
    发明授权
    Intermediates for the preparation of triazolinones 失效
    用于制备三唑啉酮的中间体

    公开(公告)号:US5639891A

    公开(公告)日:1997-06-17

    申请号:US528375

    申请日:1995-09-14

    IPC分类号: C07D249/12

    CPC分类号: C07D249/12

    摘要: The invention relates to a new process and new intermediates for the preparation of triazolinones of the general formula (I) ##STR1## in which R.sup.1 represents in each case optionally substituted alkyl or cycloalkyl andR.sup.2 represents amino or in each case optionally substituted alkyl, alkenyl, alkinyl, alkoxy, alkylamino, dialkylamino, cycloalkyl, cycloalkylalkyl or phenyl, and to new intermediates for the preparation of triazolinones, many of which are known and which can be used as intermediates for the preparation of herbicides and insecticides.

    摘要翻译: 本发明涉及用于制备通式(I)的三唑啉酮的新方法和新中间体,其中R 1表示在每种情况下为任选取代的烷基或环烷基,R 2表示氨基或在各种情况下任选取代 烷基,烯基,炔基,烷氧基,烷基氨基,二烷基氨基,环烷基,环烷基烷基或苯基,以及用于制备三唑啉酮的新中间体,其中许多是已知的,可用作制备除草剂和杀虫剂的中间体。

    Process and intermediates for the preparation of triazolinones
    64.
    发明授权
    Process and intermediates for the preparation of triazolinones 失效
    用于制备三唑啉酮的方法和中间体

    公开(公告)号:US5508420A

    公开(公告)日:1996-04-16

    申请号:US347985

    申请日:1994-12-05

    IPC分类号: C07D249/12 C07D249/14

    CPC分类号: C07D249/12

    摘要: The invention relates to a new process and to new intermediates for the preparation of triazolinones, most of which are known, of the general formula (I) ##STR1## in which R.sup.1 and R.sup.2 have the meanings given in the application, and which can be used as intermediates for the preparation of herbicides and insecticides.

    摘要翻译: 本发明涉及新方法和用于制备三唑啉酮的新中间体,其中大部分是通式(I)的化合物,其中R 1和R 2具有本申请中给出的含义,以及 其可以用作制备除草剂和杀虫剂的中间体。

    Substituted triazolinone herbicides and plant growth regulators
    65.
    发明授权
    Substituted triazolinone herbicides and plant growth regulators 失效
    取代的三唑啉酮除草剂和植物生长调节剂

    公开(公告)号:US5262389A

    公开(公告)日:1993-11-16

    申请号:US868065

    申请日:1992-04-13

    摘要: Novel herbicides and plant growth regulants of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkyl, halogenoalkinyl, alkoxyalkyl, alkoxy, cycloalkylalkyl or cycloalkyl, or represents in each case optionally substituted aralkyl or aryl,R.sup.2 represents a radical ##STR2## or represents a radical --S(O).sub.n --R.sup.7, R.sup.3 and R.sup.4 independently of one another each represent hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, cyanoalkyl, hydroxyalkyl, alkoxyalkyl, alkylaminoalkyl, alkoxycarbonylalkyl or alkoxycarbonylalkenyl, or represent in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl or cycloalkenylalkyl, or represent optionally substituted heterocyclylalkyl, or represent in each case optionally substituted aralkyl, aroyl or aryl, or represent alkoxy, alkenyloxy, alkinyloxy, aralkyloxy or aryloxy, or, together with the nitrogen atom to which they are bonded, represent an optionally substituted heterocyclic radical,X represents oxygen or sulphur andY represents oxygen or sulphur,whereinR.sup.5 and R.sup.6 independently of one another each represent alkyl, alkenyl, alkinyl, hatogenoalkyl, halogenoalkenyl, halogenoalkinyl, alkoxyalkyl, alkoxy, cycloalkyl or cycloalkylalkyl, or represent in each case optionally substituted aryl, aralkyl or heteroaryl, or, together with the nitrogen atom to which they are bonded, represent an optionally substituted heterocyclic radical,R.sup.7 represents alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkylalkyl, or represents in each case optionally substituted aralkyl or aryl and n represents the number 0, 1 or 2, but wherein R.sup.2 only represents a radical --S(O).sub.n --R.sup.7 if R.sup.3 and R.sup.4 do not simultaneously represent methyl.Intermediates therefor where NR.sup.3 R.sup.4 is replaced by Cl are also new.

    摘要翻译: 式(I)的新型除草剂和植物生长调节剂,其中R 1表示氢,烷基,烯基,炔基,卤代烷基,卤代烷基,卤代烷基,烷氧基烷基,烷氧基,环烷基烷基或环烷基,或在每种情况下表示任选取代的芳烷基或 芳基,R 2表示基团,或表示基团-S(O)n -R 7,R 3和R 4彼此独立地表示氢,烷基,烯基,炔基,卤代烷基,卤代烯基,卤代烷基,氰基烷基,羟基烷基,烷氧基烷基 或烷基氨基烷基,烷氧基羰基烷基或烷氧基羰基烯基,或在每种情况下表示任选取代的环烷基,环烷基烷基,环烯基或环烯基烷基,或代表任选取代的杂环基烷基,或在每种情况下表示任选取代的芳烷基,芳酰基或芳基,或代表烷氧基,烯氧基,烷氧基,芳烷氧基 或芳氧基,或者与它们所键合的氮原子一起表示任选的亚烷基 取代的杂环基,X表示氧或硫,Y表示氧或硫,其中R5和R6彼此独立地表示烷基,烯基,炔基,半阴离子烷基,卤代烯基,卤代烷基,烷氧基烷基,烷氧基,环烷基或环烷基烷基,或各自表示 任选取代的芳基,芳烷基或杂芳基,或与它们所键合的氮原子一起表示任选取代的杂环基,R 7表示烷基,烯基,炔基,环烷基或环烷基烷基,或在每种情况下表示任选取代的芳烷基或 芳基,n表示数字0,1或2,但如果R3和R4不同时表示甲基,则其中R2仅表示基团-S(O)n-R7。 NR3R4被Cl取代的中间体也是新的。

    Herbicidal 3-amino-5-aminocarbonyl-1,2,4-triazoles
    66.
    发明授权
    Herbicidal 3-amino-5-aminocarbonyl-1,2,4-triazoles 失效
    除草剂3-氨基-5-氨基羰基-1,2,4-三唑

    公开(公告)号:US5234897A

    公开(公告)日:1993-08-10

    申请号:US762044

    申请日:1991-09-18

    IPC分类号: A01N43/653 C07D249/14

    CPC分类号: A01N43/653 C07D249/14

    摘要: Herbicidal 3-amino-5-aminocarbonyl-1,2,4-triazoles of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is an alkyl or other organic radical, andR.sup.3 and R.sup.4 each independently is hydrogen or an organic radical,with the exception of the compounds in whicha) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.CH.sub.3, R.sup.3 .dbd.H, R.sup.4 .dbd.cyclohexyl;b) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.C.sub.2 H.sub.5, R.sup.3 .dbd.H, R.sup.4 .dbd.CH.sub.2 -C(CH.sub.3).sub.3 ;c) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.C.sub.2 H.sub.5, R.sup.3 .dbd.H, R.sup.4 .dbd.1-phenyl-ethyl;d) R.sup.1 .dbd.C.sub.2 H.sub.5, R.sup.2 .dbd.CH.sub.3, R.sup.3 .dbd.H, R.sup.4 .dbd.C(CH.sub.3).sub.3 ;e) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.CH.sub.3, R.sup.3 .dbd.CH.sub.3, R.sup.4 .dbd.C(CH.sub.3).sub.3 ;f) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.CH.sub.3, R.sup.3 .dbd.H, R.sup.4 .dbd.--CH(CH.sub.3)--CH.dbd.N--OCH.sub.3 andg) R.sup.1 .dbd.CH.sub.3, R.sup.2 .dbd.CH.sub.3, R.sup.3 =H, ##STR2##

    摘要翻译: 式“IMAGE”的除草3-氨基-5-氨基羰基-1,2,4-三唑其中R 1和R 2各自独立地为烷基或其它有机基团,且R 3和R 4各自独立地为氢或有机基团, 除了其中a)R 1 = CH 3,R 2 = CH 3,R 3 = H,R 4 =环己基的化合物之外。 b)R1 = CH3,R2 = C2H5,R3 = H,R4 = CH2-C(CH3)3; c)R1 = CH3,R2 = C2H5,R3 = H,R4 = 1-苯基 - 乙基; d)R1 = C2H5,R2 = CH3,R3 = H,R4 = C(CH3)3; e)R1 = CH3,R2 = CH3,R3 = CH3,R4 = C(CH3)3; f)R1 = CH3,R2 = CH3,R3 = H,R4 = -CH(CH3)-CH = N-OCH3,g)R1 = CH3,R2 = CH3,R3 = H,

    Process for the preparation of acyl cyanides
    68.
    发明授权
    Process for the preparation of acyl cyanides 失效
    酰基氰的制备方法

    公开(公告)号:US4555370A

    公开(公告)日:1985-11-26

    申请号:US658444

    申请日:1984-10-05

    CPC分类号: C07C253/14 C07C51/58

    摘要: A novel process for the preparation of acyl cyanides of the general formulaR--CO--CN (I)whereinR represents an optionally substituted alkyl radical with 1 to 8 carbon atoms, an optionally substituted cycloalkyl radical with 3 to 12 carbon atoms, an optionally substituted aryl radical or an optionally substituted 5-membered or 6-membered heterocyclic radical, which can additionally be fused to a benzene ring,in which a carboxylic acid fluoride or the general formulaR--CO--F (II)in whichR has the abovementioned meaningis reacted with an alkali metal cyanide, optionally in the presence of a diluent, at a temperature between 10.degree. and 200.degree. C.The acylcyanides (I) can be used as intermediates in the synthesis of known herbicides.

    摘要翻译: 制备通式为R-CO-CN(I)的酰基氰的新方法,其中R表示任选取代的具有1至8个碳原子的烷基,任选取代的具有3至12个碳原子的环烷基,任选地 取代的芳基或任选取代的5元或6元杂环基团,其另外可以与苯环稠合,其中羧酸氟化物或其中R具有下式的通式R-CO-F(II) 上述含义可任选在稀释剂存在下,在10〜200℃的温度下与碱金属氰化物反应。酰基氰化物(I)可用作合成已知除草剂的中间体。

    Process for the production of polyurethanes using cyclic
N-hydroxyalkyl-substituted compounds containing amidine groups as
catalysts
    70.
    发明授权
    Process for the production of polyurethanes using cyclic N-hydroxyalkyl-substituted compounds containing amidine groups as catalysts 失效
    使用含有脒基作为催化剂的环状N-羟基烷基取代的化合物生产聚氨酯的方法

    公开(公告)号:US4368278A

    公开(公告)日:1983-01-11

    申请号:US251011

    申请日:1981-04-03

    CPC分类号: C08G18/2009

    摘要: A polyurethane is made by reacting a polyisocyanate with a compound having at least two isocyanate-reactive hydrogen atoms and having a molecular weight of from 400 to 10,000 in the presence of a catalyst. The catalyst employed is a cyclic N-hydroxyalkyl-substituted compound containing an amidine group. Polyurethanes made in accordance with this process are useful as shoe soles, upholstery material, sound insulating materials, coating compositions, packaging materials and mattresses.

    摘要翻译: 通过使多异氰酸酯与具有至少两个异氰酸酯反应性氢原子且在催化剂存在下的分子量为400至10,000的化合物反应制备聚氨酯。 所使用的催化剂是含有脒基的环状N-羟烷基取代的化合物。 根据该方法制备的聚氨酯可用作鞋底,装饰材料,隔音材料,涂料组合物,包装材料和床垫。