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公开(公告)号：US5006633A
公开(公告)日：1991-04-09
申请号：US395803
申请日：1989-08-18
摘要： An electroactive polymer is obtained by doping a copolymer represented by the following general formula (I): ##STR1## wherein R.sup.1 is hydrogen or a hydrocarbon residue having 1 to 20 carbon atoms; R.sup.2 is hydrogen, a hydrocarbon residue having 1 to 20 carbon atoms, furyl, pyridyl, nitrophenyl, chlorophenyl, or methoxyphenyl; l is an integer not smaller than 2; m is an integer not smaller than 1; and n is an integer not smaller than 2.
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公开(公告)号：US4978473A
公开(公告)日：1990-12-18
申请号：US354374
申请日：1989-05-19
IPC分类号： C08F299/00 , C08F2/44 , C08F290/00 , C08F290/06 , C08F299/02 , G02F1/15 , H01B1/06 , H01B1/12 , H01M6/18
CPC分类号： G02F1/1525 , H01M6/181
摘要： The present invention relates to a polymeric solid electrolyte which comprises a network molecule formed by polymerizing a polyethylene glycol with acrylic or methacrylic groups at both ends, and containing therein (a) a specific acrylate-type copolymer, (b) a low molecular polyethylene glycol with both ends methyl-esterified, and (c) an alkali metal salt or ammonium salt. The polymeric solid electrolyte of the present invention has an ionic conductivity of 10.sup.-5 S/cm or higher at room temperature, is strong in film strength even with a thickness of 100 .mu.m or less, and is superb in adherence to electrodes.
摘要翻译： 聚合物固体电解质本发明涉及聚合物固体电解质，其包含通过在两端聚合聚乙二醇与丙烯酸或甲基丙烯酸基团而形成的网络分子，并且其中含有（a）特定的丙烯酸酯类共聚物，（b）低分子量聚乙二醇 其两端被甲基酯化，和（c）碱金属盐或铵盐。 本发明的聚合物固体电解质在室温下的离子电导率为10-5S / cm以上，即使是100μm以下的厚度，膜强度也很强，并且对电极的粘附性极好。
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公开(公告)号：US4970012A
公开(公告)日：1990-11-13
申请号：US444947
申请日：1989-12-04
IPC分类号： C08F299/00 , C08F290/00 , C08F299/02 , C08L57/00 , C08L71/02 , H01B1/12 , H01G9/02 , H01G9/025 , H01M6/18
摘要： Polymeric solid electrolytes are formed by the present invention, namely, by incorporating a low molecular weight polyethylene glycol, a high molecular weight polyethylene oxide and an alkali metal or ammonium salt in a specific cinnamate ester compound, followed by a polymerization and crosslinking. The polymeric solid electrolytes have high ionic conductivity, high strength as a film, and good adhesion with electrodes. Therefore, they can be applied widely as ionics materials, e.g., for the total solidification of lithium batteries and plastic batteries and high capacity condensers and as electrolytes for electrochromic displays.
摘要翻译： 通过本发明形成聚合物固体电解质，即通过在特定肉桂酸酯化合物中引入低分子量聚乙二醇，高分子量聚环氧乙烷和碱金属盐或铵盐，然后进行聚合和交联。 聚合物固体电解质具有高离子导电性，作为膜的高强度，以及与电极的良好粘合性。 因此，它们可以广泛地用作离子材料，例如用于锂电池和塑料电池和高容量电容器的总体固化，以及用于电致变色显示器的电解质。
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公开(公告)号：US4507448A
公开(公告)日：1985-03-26
申请号：US374627
申请日：1982-05-04
CPC分类号： C08F10/00 , Y10S526/901 , Y10S526/906
摘要： A process for the homopolymerization or copolymerization of olefins is disclosed, which is carried out in the presence of a catalyst system comprising the combination of at least one organometallic compound with a component resulting from the reaction of (a) a magnesium halide, (b) a compound represented by the formula, Al(OR).sub.n X.sub.3-n, where R is a hydrocarbon residual group having 1 to 20 carbon atoms, X is a hydrogen atom, and n is 0.ltoreq.n.ltoreq.3, (c) a compound represented by the formula, Si(OR').sub.m X.sub.4-m, where R' is a hydrocarbon residual group having 1 to 20 carbon atoms, X is a halogen atom, and m is 0.ltoreq.m.ltoreq.4, and (d) a titanium compound and/or a vanadium compound. The resulting polymers have a large bulk density and a narrow range of molecular weight distribution.
摘要翻译： 公开了一种用于烯烃均聚或共聚的方法，该催化剂体系包括至少一种有机金属化合物与由（a）卤化镁反应得到的组分的组合的催化剂体系，（b） 由式Al（OR）nX3-n表示的化合物，其中R是具有1至20个碳原子的烃残基，X是氢原子，n是0
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公开(公告)号：US4451688A
公开(公告)日：1984-05-29
申请号：US413829
申请日：1982-09-01
CPC分类号： C08F10/00
摘要： Olefins are polymerized in the presence of a catalyst which comprises the combination of:[I] a solid substance obtained by the reaction of at least the following two components:(i) a magnesium compound represented by the general formula R.sup.1.sub.m (OR.sup.2).sub.n MgX.sub.2-m-n wherein R.sup.1 and R.sup.2 are each a hydrocarbon radical having 1 to 24 carbon atoms, X is a halogen atom, m is 0.ltoreq.m.ltoreq.2 and n is 0.ltoreq.n.ltoreq.2, provided 0.ltoreq.m+n.ltoreq.2, and(ii) a titanium compound and/or a vanadium compound;[II] a silicon compound represented by general formula R.sup.1 mSi(OR.sup.2).sub.n X.sub.4-m-n wherein R.sup.1 and R.sup.2 are each hydrocarbon radical having 1 to 24 carbon atoms, X is a halogen atom, m is 0.ltoreq.m
摘要翻译： 烯烃在催化剂的存在下聚合，该催化剂包含以下组合的组合：[I]通过至少以下两种组分的反应获得的固体物质：（i）由通式R 1 m（OR 2）表示的镁化合物nMgX2- mn其中R 1和R 2各自是具有1至24个碳原子的烃基，X是卤素原子，m是0≤n≤2且n是0
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公开(公告)号：US4371679A
公开(公告)日：1983-02-01
申请号：US229167
申请日：1981-01-28
申请人： Nobuyuki Kuroda , Akira Sano , Toru Nakamura , Kazuo Matsuura , Mituji Miyoshi
发明人： Nobuyuki Kuroda , Akira Sano , Toru Nakamura , Kazuo Matsuura , Mituji Miyoshi
CPC分类号： C08F10/00 , Y10S526/909
摘要： This invention provides a process for preparing polyolefins by polymerizing or copolymerizing olefins using as the catalyst a titanium compound-containing solid component and an organometal compound, said solid component comprising a substance obtained by copulverizing (1) magnesium halide and/or manganese halide, (2) an organic halide compound, (3) a chain or cyclic silicone compound with a recurring structural unit represented by the general formula ##STR1## wherein R' and R" respectively represent a hydrogen, alkyl, aryl, alkoxy or hydroxyl group and (4) tetravalent and/or trivalent titanium compound(s).
摘要翻译： 本发明提供一种通过使用含钛化合物的固体组分和有机金属化合物作为催化剂聚合或共聚烯烃来制备聚烯烃的方法，所述固体组分包括通过共混（1）卤化镁和/或卤化锰得到的物质（ 2）有机卤化物，（3）具有由通式“IMAGE”表示的重复结构单元的链或环状硅氧烷化合物，其中R'和R“分别表示氢，烷基，芳基，烷氧基或羟基， （4）四价和/或三价钛化合物。
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公开(公告)号：US4078006A
公开(公告)日：1978-03-07
申请号：US682064
申请日：1976-04-30
CPC分类号： C07C37/60
摘要： A process for preparing dihydric phenol derivatives by oxidizing monohydric phenol derivatives with hydrogen peroxide in the presence of a ketone. This reaction can be promoted in the presence of sulfuric acid or a salt thereof or a sulfonic acid or a salt thereof.
摘要翻译： 通过在酮存在下用过氧化氢氧化一元酚衍生物来制备二元酚衍生物的方法。 该反应可以在硫酸或其盐或磺酸或其盐的存在下促进。
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公开(公告)号：US4072722A
公开(公告)日：1978-02-07
申请号：US745556
申请日：1976-11-29
IPC分类号： C07C37/60 , C07C409/22 , C07C39/08
CPC分类号： C07C37/60 , C07C407/00 , C07C409/22 , C07C2101/08
摘要： A process for preparing dihydric phenol derivatives by oxidizing monohydric phenol derivatives with a ketone peroxide in the presence or absence of sulfuric acid or a salt thereof or a sulfonic acid or a salt thereof.
摘要翻译： 在存在或不存在硫酸或其盐或磺酸或其盐的情况下用酮过氧化物氧化一元酚衍生物来制备二元酚衍生物的方法。
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公开(公告)号：US4065611A
公开(公告)日：1977-12-27
申请号：US722859
申请日：1976-09-10
申请人： Mituji Miyoshi , Kazuo Matsuura , Nobuyuki Kuroda , Shiro Ogawa
发明人： Mituji Miyoshi , Kazuo Matsuura , Nobuyuki Kuroda , Shiro Ogawa
CPC分类号： C08F10/00
摘要： Processes for the production of polyolefins are disclosed in which olefins are polymerized in the presence of Ziegler catalyst components carried on magnesium oxide. The polymerization is effected in the presence of a solid catalyst comprising a transition metal halide carried on magnesium oxide, such oxide having been pretreated with an organic halide, and another catalyst component selected from the group consisting of organoaluminum compounds and alkylzinc. The combination of these catalysts contributes to increased polymer yields based on both carrier and transition metal.
摘要翻译： 公开了用于生产聚烯烃的方法，其中在氧化镁载带的齐格勒催化剂组分存在下使烯烃聚合。 聚合反应在包含负载在氧化镁上的过渡金属卤化物的固体催化剂存在下进行，这种氧化物已用有机卤化物预处理，另一种催化剂组分选自有机铝化合物和烷基锌。 这些催化剂的组合有助于基于载体和过渡金属的增加的聚合物产率。
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公开(公告)号：US4064334A
公开(公告)日：1977-12-20
申请号：US705606
申请日：1976-07-15
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： According to the present invention, there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins in the presence of a catalyst consisting of a solid component and an organometallic compound component, characterized in that said solid component is obtained by copulverizing1. a magnesium halide,2. a compound represented by the general formula Al(OR)mX.sub.3-m wherein R is alkyl and/or aralkyl having 1 to 20 carbon atoms and may be the same or different, X is halogen and O
摘要翻译： 根据本发明，提供了一种在由固体组分和有机金属化合物组分组成的催化剂存在下聚合或共聚烯烃制备聚烯烃的方法，其特征在于所述固体组分通过共混获得。1.镁 卤化物，2.一般化合物表示的化合物Al（OR）mX3-m其中R是具有1至20个碳原子的烷基和/或芳烷基并且可以相同或不同，X是卤素，且O < 3，三价钛化合物，和4.一种三价钛化合物，其中该有机元素化合物组分是一种混合物。5.一种三乙基铝和六种一般化合物表示的化合物AlR'nX3-n，其中R'是 具有1-10个碳原子的烷基可以相同或不同，X是卤素且O
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