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    Peroxide compositions with reactive diluents
    1.
    发明授权
    Peroxide compositions with reactive diluents 失效
    具有活性稀释剂的过氧化物组合物

    公开(公告)号：US07160951B2

    公开(公告)日：2007-01-09

    申请号：US10451049

    申请日：2001-12-19

    Applicant: Jan H Udding ,  Agnes E Wolters ,  Heinz Wilhelm ,  Armin Pfeil ,  Thomas Bürgel ,  Lutz Sager

    Inventor： Jan H Udding ,  Agnes E Wolters ,  Heinz Wilhelm ,  Armin Pfeil ,  Thomas Bürgel ,  Lutz Sager

    IPC: C08F261/06

    CPC classification number: C07C407/006 ,  C07C407/00 ,  C08F4/32 ,  C07C409/22 ,  C07C409/38 ,  C07C409/34 ,  C07C409/10

    Abstract: The invention relates to peroxide compositions comprising a reactive diluent for the peroxide, wherein the diluent is either a component containing one or more vinyl ether group(s) and having a monomeric structure according to formula 1, (A—CH═CH—O)n—R, or is a suitable resinous compound comprising, in a covalently built-in manner, a component containing one or more vinyl ether group(s). In the formula A represents hydrogen or an alkyl group with 1–3 C atoms, and individual A groups may be different R either represents an aliphatic group, optionally branched, with 1–20 C atoms, etc.  or represents a polyethylene or polypropylene glycol with 2 to 120 glycol units, etc. and n is 1, 2, 3 or 4. The resinous compounds comprising, in a covalently built-in manner, a component containing one or more vinyl ether group(s)are obtained by reaction of: a) a first compound (the HVE-compound) containing at least one hydroxyl group and at least one vinyl ether group, and b) a second compound (the D/HIC-compound), being an isocyanate, reacting with formation of one or more urethane group(s), and c) a third compound (the G/P/HP-compound) chosen from the groups of (1) C2-6 glycols, (2) C5-20 polyols having 2–5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1–5 free hydroxyl groups and from 2–50 monomeric ester units (the G/P/HP-compound), or mixtures thereof. The invention also relates to the preparation of such compositions and to the use of such reactive diluents for peroxides in radically curing of unsaturated polyester resins for structural applications.

    Abstract translation: 本发明涉及包含用于过氧化物的反应性稀释剂的过氧化物组合物，其中稀释剂是含有一个或多个乙烯基醚基团并且具有根据式1的单体结构的组分（A-CH-CH-O） 或者是合适的树脂化合物，其以共价内置的方式包含含有一个或多个乙烯基醚基团的组分。 式A表示氢或具有1-3个C原子的烷基，各个A基团可以不同，R表示任选支链的1-20个C原子的脂族基团等，或代表聚乙烯或聚丙二醇 2〜120个二醇单元等，n为1,2,3或4.含有一个或多个乙烯基醚基的成分以共价内置的方式包含的树脂化合物是通过 ：a）含有至少一个羟基和至少一个乙烯基醚基团的第一化合物（HVE-化合物），和b）作为异氰酸酯的第二化合物（D / HIC-化合物）与形成一个 或更多个氨基甲酸酯基团，和c）选自（1）C 2-6 - 二醇的第三化合物（G / P / HP-化合物），（2）C < 具有2-5个羟基的（3）羟基封端的聚酯化合物，不具有1-5个游离羟基的醇酸树脂和2-50个单体酯单元（t 他G / P / HP-化合物）或其混合物。 本发明还涉及这种组合物的制备以及这种反应性稀释剂在不饱和聚酯树脂的自由基固化中用于结构应用的过氧化物的用途。

    Peroxides, their preparation process and use
    3.
    发明授权
    Peroxides, their preparation process and use 失效
    过氧化物，其制备过程和用途

    公开(公告)号：US06384287B1

    公开(公告)日：2002-05-07

    申请号：US09762671

    申请日：2001-02-12

    Applicant: Anna Gerdine Van De Bovenkamp-Bouwman ,  Bernhard De Vries ,  John Meijer ,  Ejaz Ahmed Syed ,  Andreas Herman Hogt

    Inventor： Anna Gerdine Van De Bovenkamp-Bouwman ,  Bernhard De Vries ,  John Meijer ,  Ejaz Ahmed Syed ,  Andreas Herman Hogt

    IPC: C07C40900

    CPC classification number: C08F4/36 ,  C07C409/22 ,  C07C2601/14 ,  C08F283/01 ,  C08F4/28

    Abstract: The present invention relates to a new class of peroxides and to a process for the preparation of these peroxides having the general formula (I), wherein n=1 or 2, R1, R2, R4, R5, and R6 are independently selected from the group comprising hydrogen, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 aralkyl, and C7-C20 alkaryl, or R1 and R2 form a C3-C12 cycloalkyl group, which groups may include linear or branched alkyl moieties; and each of R1, R2, R4, R5, and R6 may optionally be substituted with one or more groups selected from hydroxy, alkoxy, linear or branched alkyl, aryloxy, halogen, ester, carboxy, nitrile, and amido, and R1 and R2 may form a ring, and R3 is independently selected from the group comprising C1-C20, alkyl; C3-C20 cycloalkyl, C6-C20 aryl, C7-C20, aralkyl, and C7-C20 alkaryl, which groups may include linear or branched alkyl moieties; and R3 may optionally be substituted with one or more groups selected from hydroxy, alkoxy, linear or branched alkyl, aryloxy, halogen, ester, carboxy, nitrile, and amido, and any pair of the optionally substituted R3, R4, R5, and R6 may form a ring, comprising the reaction of the corresponding ketone.

    Abstract translation: 本发明涉及一类新型过氧化物，以及制备具有通式（I）的这些过氧化物的方法，其中n = 1或2，R 1，R 2，R 4，R 5和R 6独立地选自 包括氢，C 1 -C 20烷基，C 3 -C 20环烷基，C 6 -C 20芳基，C 7 -C 20芳烷基和C 7 -C 20烷芳基，或R 1和R 2形成C 3 -C 12环烷基，所述基团可包括直链或支链烷基 部分; R 1，R 2，R 4，R 5和R 6可以任选被一个或多个选自羟基，烷氧基，直链或支链烷基，芳氧基，卤素，酯，羧基，腈和酰氨基的基团取代，并且R 1和R 2 可以形成环，R 3独立地选自C 1 -C 20烷基， C 3 -C 20环烷基，C 6 -C 20芳基，C 7 -C 20，芳烷基和C 7 -C 20烷芳基，这些基团可以包括直链或支链烷基部分; 并且R 3可以任选被一个或多个选自羟基，烷氧基，直链或支链烷基，芳氧基，卤素，酯，羧基，腈和酰氨基的基团取代，以及任意一对任选取代的R 3，R 4，R 5和R 6 可形成环，包括相应酮的反应。

    Agglomeration of solid peroxides
    5.
    发明授权
    Agglomeration of solid peroxides 失效
    固体过氧化物的聚集

    公开(公告)号：US5314639A

    公开(公告)日：1994-05-24

    申请号：US647336

    申请日：1991-01-28

    Applicant: Reinder Torenbeek

    Inventor： Reinder Torenbeek

    IPC: C07C407/00 ,  C07C409/00 ,  C07C409/22 ,  C07C409/32 ,  C07C409/34 ,  C01B15/00

    CPC classification number: C07C409/34 ,  C07C407/00 ,  C07C407/003 ,  C07C409/22 ,  C07C409/32 ,  C07C2101/14

    Abstract: The present application discloses a process for the production of agglomerates of peroxides that are solid at room temperature and which decompose rapidly when heated to their melting point. The process comprises agitating an aqueous suspension comprising a solid first peroxide which rapidly decomposes when heated to its melting point and a solid second peroxide which does not rapidly decompose when heated to its melting point and has a melting point which is substantially lower than the temperature at which said first peroxide rapidly decomposes, at a temperature sufficient to at least partially melt said second peroxide and below the decomposition temperature of said first peroxide to produce agglomerates comprised of said first and second peroxides; cooling with continued agitation the aqueous suspension having agglomerates to a temperature at which said second peroxide turns solid; and isolating the agglomerates. Also disclosed is a process such as that described above wherein a solvent immiscible with water is employed to aid the agglomeration process. The agglomerated peroxides are particularly useful in the polymerization of vinyl chloride monomers and the curing of unsaturated polyester resins.

    Abstract translation: 本申请公开了一种生产过氧化物附聚物的方法，其在室温下为固体，并且当加热至其熔点时迅速分解。 该方法包括搅拌包含固体第一过氧化物的水性悬浮液，其在加热至其熔点时快速分解，而固体第二过氧化物在加热至其熔点时不会快速分解，并且具有基本上低于 所述第一过氧化物在足以至少部分地熔化所述第二过氧化物并低于所述第一过氧化物的分解温度的温度下快速分解，以产生由所述第一和第二过氧化物组成的附聚物; 在持续搅拌下将具有附聚物的水性悬浮液冷却至所述第二过氧化物变固的温度; 并分离附聚物。 还公开了如上所述的方法，其中使用与水不混溶的溶剂来帮助凝聚过程。 附聚过氧化物特别可用于氯乙烯单体的聚合和不饱和聚酯树脂的固化。

    Gem-diperoxyesters
    6.
    发明授权
    Gem-diperoxyesters 失效
    宝石双过氧化物

    公开(公告)号：US4443376A

    公开(公告)日：1984-04-17

    申请号：US424820

    申请日：1982-09-27

    Applicant: Ronald L. Pastorino ,  Lawrence A. Bock ,  Reidar Halle

    Inventor： Ronald L. Pastorino ,  Lawrence A. Bock ,  Reidar Halle

    IPC: C07C409/22 ,  C08F299/04 ,  C07C179/14

    CPC classification number: C07C409/22 ,  C07C409/38 ,  C08F299/045

    Abstract: Gem-diperoxyesters of the formula: ##STR1## where R is selected from methyl and ethyl; R.sub.1 is ethyl when R is ethyl; R.sub.1 is hydroxyalkyl of 1 to 7 carbon atoms when R is methyl; and each R.sub.2 is ##STR2## where each of R.sub.3, R.sub.4, and R.sub.5 is selected from hydrogen and alkyl, provided not more than one of R.sub.3, R.sub.4, and R.sub.5 is hydrogen, R.sub.3, R.sub.4, and R.sub.5 collectively containing from 2 to 12 carbon atoms.The compounds are particularly efficient at varying temperatures from ambient to 60.degree. C. for the initiation of the polymerization of vinyl chloride. They also have high efficiency in the curing of polyester resins and in the polymerization of other monomers and comonomers having ethylenic unsaturation.

    Abstract translation: 下式的Gem-diperoxyester：其中R选自甲基和乙基; 当R为乙基时，R 1为乙基; 当R为甲基时，R 1为1至7个碳原子的羟烷基; 并且每个R 2是，其中R 3，R 4和R 5各自选自氢和烷基，条件是不多于一个R 3，R 4和R 5是氢，R 3，R 4和R 5共同含有2至12个 碳原子。 该化合物在环境温度至60℃的不同温度下特别有效，用于引发氯乙烯的聚合。 它们在聚酯树脂的固化和其它单体和具有烯属不饱和键的共聚单体的聚合中也具有高效率。

    Organic peroxides their preparation and their applications
    8.
    发明授权
    Organic peroxides their preparation and their applications 失效
    有机过氧化物的制备及其应用

    公开(公告)号：US3980712A

    公开(公告)日：1976-09-14

    申请号：US374009

    申请日：1973-06-26

    Applicant: Egeo Sacrini ,  Claudio Cavallotti

    Inventor： Egeo Sacrini ,  Claudio Cavallotti

    IPC: C07C409/20 ,  C07C409/22 ,  C07C179/00

    CPC classification number: C07C409/20 ,  C07C409/22

    Abstract: Tetraperoxides of the formula ##EQU1## where X is a bivalent radical such as alkylene; R.sub.1 is hydrogen or an organic radical; R.sub.2 is alkylene alkoxy carbonyl; and R.sub.3 is an organic radical. Method of preparing tetraperoxides by addition reaction between a bis-hydroperoxide and a carbonyl compound to form a dihydroxy diperoxide, followed by condensation of the dihydroxy diperoxide with a tertiary monohydroxide. The tetraperoxides are useful for vulcanizing saturated elastomers, crosslinking plastomers, and initiating radical polymerization.

    Abstract translation: 式R1R1 || R3-OO-C-OO-X-OO-C-R3 || R2R2的四环氧化物其中X是二价基团如亚烷基; R1是氢或有机基团; R2是亚烷基烷氧基羰基; 并且R 3是有机基团。 通过双氢过氧化物和羰基化合物之间的加成反应制备四
    氧化物以形成二羟基二过氧化物，然后二羟基二过氧化物与叔氢氧化物的缩合制备方法。 四元素可用于硫化饱和弹性体，交联塑性体和引发自由基聚合。

    Organic peroxides, their preparation, and their applications
    9.
    发明授权
    Organic peroxides, their preparation, and their applications 失效
    有机过氧化物，它们的制备及其应用

    公开(公告)号：US3928464A

    公开(公告)日：1975-12-23

    申请号：US57060175

    申请日：1975-04-23

    Applicant: GOODRICH CO B F

    Inventor： SACRINI EGEO ,  CAVALLOTTI CLAUDIO

    IPC: C07C409/20 ,  C07C409/22 ,  C07C179/06

    CPC classification number: C07C409/22 ,  C07C2601/14

    Abstract: Tetraperoxides of the formula

    where X is a bivalent radical such as alkylene; R1 is hydrogen or an organic radical; R2 is alkylene alkoxy carbonyl; and R3 is an organic radical. Method of preparing tetraperoxides by addition reaction between a bis-hydroperoxide and a carbonyl compound to form a dihydroxy diperoxide, followed by condensation of the dihydroxy diperoxide with a tertiary monohydroxide. The tetraperoxides are useful for vulcanizing saturated elastomers, crosslinking plastomers, and initiating radical polymerization.

    Abstract translation: 式R1R1 || R3-OO-C-OO-X-OO-C-R3 || R2R2的四环氧化物其中X是二价基团如亚烷基; R1是氢或有机基团; R2是亚烷基烷氧基羰基; 并且R 3是有机基团。 通过双氢过氧化物和羰基化合物之间的加成反应制备四
    氧化物以形成二羟基二过氧化物，然后二羟基二过氧化物与叔氢氧化物的缩合制备方法。 四元素可用于硫化饱和弹性体，交联塑性体和引发自由基聚合。

    Alkylideneperoxides,method for preparing same and vulcanizable compositions obtained therefrom
    10.
    发明授权
    Alkylideneperoxides,method for preparing same and vulcanizable compositions obtained therefrom 失效
    烷基酚氧化物，其制备方法和获得的可化合物

    公开(公告)号：US3489730A

    公开(公告)日：1970-01-13

    申请号：US51094165

    申请日：1965-12-01

    Applicant: MONTEDISON SPA

    Inventor： BUTTAR CARLO ,  MARTINI EMILIO

    IPC: C07C409/22 ,  C08K5/14 ,  C08F45/72 ,  C07C73/00

    CPC classification number: C07C409/22 ,  C07C407/00 ,  C07C2601/14 ,  C08K5/14 ,  C08L23/16

    Abstract: A vulcanizable composition contains an olefin copolymer or terpolymer, a reinforcing filler and an alkylidene peroxide of the formulae wherein R and R1 are each H, alkyl, aryl or aralkyl groups, R11 and R111 are each tertiary alkyl or tertiary aralkyl groups, R1111 is a hydrogen atom or an alkyl radical, R5 is an alkylene, arylene or aralkylene radical and R6 is the same as R11 or R111, R11 and R111 are different and n is 0 or 1. The peroxide should be present in an amount from 0.1 to 10 parts by weight, per 100 parts of copolymer or terpolymer. Also, vulcanized articles obtained from the said compositions by heating the composition to a temperature higher than the decomposition temperature of the alkylidene peroxide. Examples are given in which ethylene-propylene copolymers are vulcanized.ALSO:Alkylidene peroxides of the general formulae wherein R and R1 are each H, alkyl, aryl or aralkyl groups, R11 and R111 are each tertiary alkyl or tertiary aralkyl groups, R1111 is a hydrogen atom or an alkyl radical, R5 is an alkylene, arylene or aralkylene radical and R6 is the same as R11 or R111, R11 and R111 are different and n is 0 or 1 are prepared in the case of the first three types by transperoxidation of an alkylidene peroxide of the formulae with a hydroperoxide of the formula R111OOH which is less volatile than the hydroperoxide R11OOH from which the radical -OOR11 is derived, in the absence of catalysts generally at from 35 DEG to 110 DEG C. by continuously removing by distillation the hydroperoxide R11OOH released generally until 1 mol. of hydroperoxide R11OOH per 1 mol. of starting alkylidene peroxide has been eliminated or until the R11OOH hydroperoxide has been completely eliminated; and in the case of the fourth type by transperoxidation generally of 2 mols of an alkylidene peroxide of the formula with 1 mol. of a dihydroperoxide of the formula This invention also comprises the compounds of the formulae per se: Examples are given for the production of the compounds. They are useful as vulcanizing agents.

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