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    Dehydrogenation method
    63.
    发明授权
    Dehydrogenation method 失效
    脱氢法

    公开(公告)号：US4128590A

    公开(公告)日：1978-12-05

    申请号：US788101

    申请日：1977-04-15

    Applicant: Ernest L. Pollitzer ,  John C. Hayes

    Inventor： Ernest L. Pollitzer ,  John C. Hayes

    IPC: B01J23/89 ,  C07C5/32 ,  C07C5/333 ,  C07C5/367 ,  C10G13/06

    CPC classification number: C07C5/3337 ,  B01J23/8966 ,  C07C5/325 ,  C07C5/367 ,  C07C2521/04 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/89 ,  Y02P20/52 ,  Y10S585/951

    Abstract: Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a cobalt component, and a germanium component with a porous carrier material. A specific example of the nonacidic catalytic composite disclosed herein is a combination of a platinum group component, a cobalt component, a germanium component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.1 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % germanium and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.

    Abstract translation: 可脱氢烃通过在脱氢条件下与包含催化有效量的铂族组分，钴组分和锗组分的组合的催化复合物与多孔载体材料接触而脱氢。 本文公开的非酸性催化复合物的具体实例是铂组分，钴组分，锗组分和碱金属或碱土金属组分与多孔载体材料的组合，其量足以导致含有约0.01 至约2重量％ ％铂族金属，约0.1至约5wt。 ％钴，约0.01至约5wt。 ％锗和约0.1至约5wt。 ％碱金属或碱土金属。

    Process for reforming and dewaxing by selective hydrocracking of hydrocarbon fractions
    64.
    发明授权
    Process for reforming and dewaxing by selective hydrocracking of hydrocarbon fractions 失效
    通过烃馏分的选择性加氢裂化来重整和脱蜡的方法

    公开(公告)号：US4124487A

    公开(公告)日：1978-11-07

    申请号：US802630

    申请日：1977-06-02

    Applicant: Albert M. Tsybulevsky ,  Kapitolina P. Danilushkina ,  Petr M. Pak

    Inventor： Albert M. Tsybulevsky ,  Kapitolina P. Danilushkina ,  Petr M. Pak

    IPC: C10G35/095 ,  C10G45/64 ,  C10G13/06 ,  C07C9/04 ,  C10G35/06

    CPC classification number: C10G35/095 ,  C10G2400/02 ,  Y10S585/94 ,  Y10S585/942

    Abstract: The process for selective hydrocracking of hydrocarbon fractions consists in that hydrocarbon fractions are contacted with hydrogen at a respective molar ratio of 1:2.5-20, a temperature of 280.degree. - 520.degree. C., and a pressure of 15 - 100 kgf/cm.sup.2 on a zeolite catalyst with a pore size of 4.6 to 6.0 A and containing 0.1 to 5 wt.% of metal of Group VIII of the periodic system, and a tervalent chromium cation with a minimum exchange capacity equal to 30 percent.The herein-proposed process for selective hydrocracking of hydrocarbon fractions is capable of upgrading petroleum products accompanied by producing a synthetic substitute of natural gas.

    Abstract translation: 烃馏分的选择性加氢裂化方法在于烃馏分与氢气的摩尔比为1：2.5-20，温度为280-520℃，压力为15-100kgf / cm2 在孔径为4.6〜6.0A的沸石催化剂上，含有0.1〜5重量％的周期性体系的第Ⅷ族金属和最低交换容量等于30％的三价铬阳离子。

    Hydrogenation process with sulfided catalyst
    65.
    发明授权
    Hydrogenation process with sulfided catalyst 失效
    硫化催化剂的氢化过程

    公开(公告)号：US4104152A

    公开(公告)日：1978-08-01

    申请号：US834621

    申请日：1977-09-19

    Applicant: Lee Hilfman

    Inventor： Lee Hilfman

    IPC: C10G49/04 ,  C10G13/06 ,  B01J23/16 ,  B01J27/04

    CPC classification number: C10G49/04

    Abstract: A hydrogenation process utilizing a hydrogenation catalyst in an oxidized state which catalyst is activated by a method which yields a superior performing hydrogenation catalyst. The hydrogenation catalyst is reduced, sulfided and stripped by a procedure which allows a more economical and time-saving start-up procedure.

    Abstract translation: 利用处于氧化态的氢化催化剂的氢化方法，该催化剂通过产生优异性能的氢化催化剂的方法活化。 氢化催化剂被减少，硫化并通过允许更节省和节省时间的启动程序的方法剥离。

    Combined disulfurization and conversion with alkali metals
    66.
    发明授权
    Combined disulfurization and conversion with alkali metals 失效
    与碱金属组合脱硫和转化

    公开(公告)号：US4076613A

    公开(公告)日：1978-02-28

    申请号：US571903

    申请日：1975-04-28

    Applicant: Roby Bearden, Jr.

    Inventor： Roby Bearden, Jr.

    IPC: C10G65/12 ,  C10G13/06 ,  B01J27/04

    CPC classification number: C10G65/12

    Abstract: Improved processes for the combined desulfurization and hydroconversion of various sulfur-containing pertroleum oils, and particularly various residua feedstocks, are disclosed. These feedstocks are thus contacted with alkali metals, such as sodium, in the molten state, in a conversion zone maintained at specified conditions such that the feedstocks are both desulfurized and subjected to significant hydroconversion, particularly demonstrated by significant reductions in the 1,050.degree. F+ fraction of these feedstocks, as well as significantly decreased Conradson carbon and increased API gravity. In addition, the deep demetallization and moderate denitrogenation of these feedstocks is also achieved. These important results are obtained by maintaining the conversion zone at temperatures of above 750.degree. F, and in the presence of sufficient added hydrogen to produce a hydrogen pressure in the conversion zone of between about 1500 and 3000 psig.

    Abstract translation: 公开了用于各种含硫石油油，特别是各种残留原料的联合脱硫和加氢转化的改进方法。 因此，这些原料在熔融状态下与碱性金属（例如钠）在保持在特定条件下的转化区中接触，使得原料都脱硫并进行显着的加氢转化，特别是通过显着降低1,050°F +馏分 的这些原料，以及Conradson碳显着降低和API重力增加。 此外，还实现了这些原料的深度脱金属和中等脱氮。 这些重要的结果是通过将转化区保持在高于750°F的温度下，并且在有足够的氢气存在下，在转化区中产生约1500-3000psig的氢气压力而获得的。

    Hydroconversion of heavy hydrocarbons
    68.
    发明授权
    Hydroconversion of heavy hydrocarbons 失效
    重油烃的氢化

    公开(公告)号：US4066530A

    公开(公告)日：1978-01-03

    申请号：US745394

    申请日：1976-11-26

    Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

    Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

    IPC: B01J37/00 ,  C10G45/16 ,  C10G13/06 ,  B01J27/04

    CPC classification number: B01J37/00 ,  C10G45/16

    Abstract: A catalytic hydroconversion process is effected by reacting with hydrogen a heavy hydrocarbonaceous oil containing a catalyst comprising an iron component and a catalytically active other metal component prepared by dissolving an oil soluble metal compound in the oil and converting the metal compound in the oil to the corresponding catalytically active metal component. Preferred oil soluble compounds are molybdenum compounds.

    Abstract translation: 烃油的催化加氢转化方法是通过将油溶性金属化合物溶解在油中，将化合物转化成油中的固体非胶态催化剂并使含有催化剂的油与氢反应。 优选的化合物是钼化合物。

    Residua desulfurization and hydroconversion with sodamide and hydrogen
    70.
    发明授权
    Residua desulfurization and hydroconversion with sodamide and hydrogen 失效
    残留脱硫和加氢转化与sodamide和氢

    公开(公告)号：US4007111A

    公开(公告)日：1977-02-08

    申请号：US571946

    申请日：1975-04-28

    Applicant: William Chalmers Baird, Jr.

    Inventor： William Chalmers Baird, Jr.

    IPC: C10G29/20 ,  C10G47/22 ,  C10G13/06 ,  B01J27/24

    CPC classification number: C10G47/22 ,  C10G29/20

    Abstract: Sulfur-containing petroleum oil feedstocks which include heavy hydrocarbons constituents undergo simultaneous desulfurization and hydroconversion by contacting such feedstocks with sodamide in the presence of hydrogen and at elevated temperatures. The mixture of reaction products resulting from the above procedure can be separated to give sodium sulfur salts and a petroleum oil product which has been substantially desulfurized and demetallized and significantly upgraded as demonstrated by a reduced Conradson carbon content and an increased API gravity.

    Abstract translation: 包括重质烃成分的含硫石油原料通过在氢气存在下和高温下使这些原料与氯化钠接触而同时进行脱硫和加氢转化。 由上述程序产生的反应产物的混合物可以分离，得到硫酸钠盐和石油产品，其已基本上脱硫和脱金属化并​​显着升级，这通过降低的康拉逊碳含量和增加的API重力来证明。

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