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公开(公告)号：US20240218273A1
公开(公告)日：2024-07-04
申请号：US18091367
申请日：2022-12-30
发明人： Scott Lehrer , Zhengwei Liu , Philippe Prince , Jagrut Jani
CPC分类号： C10G75/04 , C02F1/281 , C02F5/08 , C09K8/532 , C09K8/54 , C10G29/10 , C02F2103/10 , C09K2208/20 , C10G2300/202 , C10G2300/207
摘要： Certain zinc-based scavengers can scavenge sulfur compounds from fluids containing one or more hydrocarbons, water and the sulfur compound, but may leave deposits of insoluble zinc sulfide (ZnS) which can be problematic. When the zinc-based scavengers are used together with at least one zinc sulfide deposition preventer, deposition of zinc sulfide can be reduced or eliminated. The sulfur compound may be hydrogen sulfide (H2S). Suitable zinc-based sulfur compound scavengers include, but are not necessarily limited to, a zinc carboxylate, a tetramine zinc carbonate, zinc carbonate, zinc ammonium carbonate, zinc chelates, and/or zinc lignosulfonate. Suitable zinc sulfide deposition preventers include, but are not necessarily limited to, sodium salts of a phosphorous-based polymer, polymeric ammonium salts, acrylic sulfonate non-ionic terpolymers, and/or modified acrylic acid polymers.
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2.发明申请公开(公告)号：US20190194555A1
公开(公告)日：2019-06-27
申请号：US16267942
申请日：2019-02-05
CPC分类号： C10G53/12 , B01D11/043 , B01D11/0484 , B01D11/0488 , B01D11/0492 , B01J37/20 , C10G19/02 , C10G21/30 , C10G29/10 , C10G53/14 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2300/703 , C10L3/103
摘要： The invention involves an integrated process in which a hydrocarbon feedstock is treated with a caustic (alkaline) extraction to remove sulfides, disulfides, and mercaptans. These extracted materials are further treated, and are then used to activate hydrotreating catalysts.
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公开(公告)号：US09523043B2
公开(公告)日：2016-12-20
申请号：US14481265
申请日：2014-09-09
CPC分类号： C10G29/02 , C10G7/00 , C10G29/10 , C10G29/28 , C10G2300/205 , C10G2300/206
摘要： Mercury in distilled products from a distillation column is removed and extracted as soluble mercury compounds with the injection of a complexing agent into the overhead sections of the column. Examples of complexing agents include polysulfides such as sodium polysulfide or ammonium polysulfide. In one embodiment, the complexing agent is injected into the inlet pipe just before the overhead condenser, converting the volatile elemental mercury into a species that is soluble in the sour water stream that collected in the overhead sections.
摘要翻译： 从蒸馏塔中蒸馏出的产物中的汞被除去，并将其作为可溶性汞化合物提取，同时将络合剂注入柱的塔顶部分。 络合剂的实例包括多硫化物，例如多硫化钠或多硫化铵。 在一个实施方案中，将络合剂注入到塔顶冷凝器之前的入口管中，将挥发性元素汞转化为可溶于收集在塔顶部分中的酸性水流中的物质。
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4.发明申请PROCESS FOR UPGRADING BIOMASS DERIVED PRODUCTS USING LIQUID-LIQUID EXTRACTION 审中-公开使用液体萃取提升生物质衍生产品的方法公开(公告)号：US20160317947A1
公开(公告)日：2016-11-03
申请号：US15207134
申请日：2016-07-11
发明人： Vicente Sanchez , Richard Engelman , Chris Lewis , Brent Moore , Ed Smith
CPC分类号： B01D11/0446 , B01D11/0415 , B01D11/0492 , B01D17/0208 , B01D17/042 , B01D17/044 , B01D17/047 , B01D61/147 , C10B53/02 , C10G1/002 , C10G1/08 , C10G3/40 , C10G3/42 , C10G21/06 , C10G21/16 , C10G21/28 , C10G29/06 , C10G29/10 , C10G29/20 , C10G29/22 , C10G33/04 , C10G2300/1011 , C10G2300/308 , Y02P30/20
摘要： Disclosed is a process for the alteration of the ratio of the specific gravities of the oil and water phases resulting from the conversion of biomass to liquid products, the reduction of the conductivity and of metals of the product mixture, which each can aid in the removal of solids contained in the oil phase; and a liquid-liquid extraction method for partitioning desirable carbon containing compounds into the oil phase and undesirable carbon containing compounds into the water phase.
摘要翻译： 公开了一种用于改变由生物质转化为液体产物而导致的油相和水相的比重与产物混合物的导电性和金属的降低的比例的方法，其中每一种可以有助于除去 包含在油相中的固体; 以及用于将期望的含碳化合物分解成油相和不期望的含碳化合物进入水相的液体 - 液体萃取方法。
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5.发明授权公开(公告)号：US07632396B2
公开(公告)日：2009-12-15
申请号：US11123517
申请日：2005-05-06
IPC分类号： C10G19/02
CPC分类号： C10G19/02 , C10G29/10 , C10G2300/1044 , C10G2300/202 , C10G2300/805 , C10G2400/02
摘要： A method for reducing the level of elemental sulfur from sulfur-containing hydrocarbon streams as well as reducing the level of total sulfur in such streams. Preferred hydrocarbon streams include fuel streams such as naphtha and distillate streams that are transported through a pipeline. The sulfur-containing hydrocarbon stream is blended with an aqueous solution of water, a caustic, and at least one metal sulfide thereby resulting in an organic phase and an aqueous phase. The blended stream is then passed through a bed of solids having a suitable surface area so that a substantial amount of the sulfur moieties are removed by the aqueous phase.
摘要翻译： 一种降低含硫烃流中元素硫含量的方法以及降低这些物流中总硫的含量。 优选的烃流包括通过管道输送的燃料流，例如石脑油和馏出物流。 含硫烃流与水，苛性碱和至少一种金属硫化物的水溶液共混，从而产生有机相和水相。 然后将混合的物流通过具有合适表面积的固体床，使得大量的硫部分被水相除去。
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公开(公告)号：US20020179452A1
公开(公告)日：2002-12-05
申请号：US10148184
申请日：2002-06-06
发明人： Tsunenori Sakai , Hajime Ito , Jun Mase
IPC分类号： C25B003/00 , C25B001/16
摘要： The continuous process for removing mercury comprises a step of continuously feeding a mercury-containing liquid hydrocarbon to an ionization zone where the elementary mercury is ionized; and a step of continuously feeding the liquid hydrocarbon containing the ionized mercury to a sulfur compound-treatment zone where the ionized mercury is converted to a solid mercury compound. The semi-continuous process for removing mercury comprises a step of continuously feeding a mercury-containing liquid hydrocarbon to an ionization column where the elementary mercury is ionized; and a step of feeding the liquid hydrocarbon containing the ionized mercury to a sulfur compound-treatment tank where the ionized mercury is converted to a solid mercury compound in batch manner. With the above processes, the mercury is removed from the liquid hydrocarbon with ease in a continuous or semi-continuous manner at around ordinary temperature under around ordinary pressure.
摘要翻译： 用于去除汞的连续方法包括将含汞液体烃连续供给到基本汞被离子化的电离区的步骤; 以及将含有电离汞的液态烃连续供给到硫化合物处理区域的步骤，其中电离汞转化为固体汞化合物。 用于去除汞的半连续方法包括将含汞液体烃连续供给到基本汞离子化的离子化柱的步骤; 以及将含有电离汞的液体烃进料到硫化合物处理槽中的步骤，其中电离汞以分批方式转化为固体汞化合物。 通过上述方法，在大约常压下在大约常压下，以连续或半连续的方式容易地从液态烃中除去汞。
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公开(公告)号：US5160045A
公开(公告)日：1992-11-03
申请号：US716485
申请日：1991-06-17
IPC分类号： C10G29/10
CPC分类号： C10G29/10
摘要： A process for removing elemental sulfur from fluids such as refined petroleum products transported through pipelines for the transportation of sour hydrocarbon streams. The fluids are contacted with an aqueous solution containing caustic, sulfide and optionally elemental sulfur to produce an aqueous layer containing metal polysulfides and a clear fluid layer having a reduced elemental sulfur level. Organo mercaptans may also be mixed with the fluid to accelerate the removal of elemental sulfur.
摘要翻译： 从流体中除去元素硫的方法，例如通过管道运输的精炼石油产品用于运输酸性碳氢化合物流。 流体与含有苛性碱，硫化物和任选的元素硫的水溶液接触以产生含有金属多硫化物的水层和具有降低的元素硫含量的透明流体层。 有机硫醇也可与流体混合以加速元素硫的去除。
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公开(公告)号：US4366044A
公开(公告)日：1982-12-28
申请号：US220021
申请日：1981-01-05
申请人： Rollan Swanson
发明人： Rollan Swanson
CPC分类号： C10G29/10 , C07C1/00 , C10G1/00 , C10G45/00 , Y02P20/582 , Y10S208/951
摘要： A process for converting coals to hydrocarbon values, by intimately contacting coals such as lignite coal with a reagent, e.g., an alkali metal sulfide or polysulfide or an alkali metal hydrosulfide, in the presence of steam, or a combination of steam and hydrogen sulfide, at temperatures between 65.degree. C. to 450.degree. C.; liquid and gaseous hydrocarbons of preselected compositions may be produced; these are useful as fuel, or as chemical starting materials, e.g., for upgrading fuel or making industrial chemicals.
摘要翻译： 通过将煤炭如褐煤与试剂（例如碱金属硫化物或多硫化物或碱金属氢硫化物）在蒸汽或蒸汽和硫化氢的组合的存在下紧密接触来将煤转化为烃值的方法， 在65℃至450℃的温度下。 可以制备预选组合物的液态和气态碳氢化合物; 这些可用作燃料，或用作化学原料，例如用于升级燃料或制造工业化学品。
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9.发明授权
公开(公告)号：US4248695A
公开(公告)日：1981-02-03
申请号：US80213
申请日：1979-10-01
申请人： Rollan Swanson
发明人： Rollan Swanson
CPC分类号： C10G29/10
摘要： Petroleum crude and certain liquid distillate fractions derived therefrom, and other sulfur containing fuels or residues are reduced in sulfur content by intimately contacting the fuel or residues with alkanol solutions of alkali metal hydrosulfides, at temperatures and pressures from ambient up to the critical temperature of the alkanol for from 1 to 20 minutes. Thereafter, the fuel is caused to separate from the alkanol solution by the addition of water. A liquid-liquid separation separates desulfurized fuel from the alkanol solution. Hydrogen sulfide formed in the process is used to re-generate alkali metal hydrosulfide for use in desulfurizing additional petroleum fuel.
摘要翻译： 通过将燃料或残余物与碱金属氢硫化物的链烷醇溶液紧密接触，在环境温度和压力范围内直到临界温度下，从其衍生的石油原油和其他含硫燃料或残余物的硫含量降低 链烷醇1〜20分钟。 此后，通过添加水使燃料与烷醇溶液分离。 液 - 液分离将脱硫燃料与烷醇溶液分离。 该方法中形成的硫化氢用于重新生成用于脱硫另外的石油燃料的碱金属氢硫化物。
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公开(公告)号：US4230184A
公开(公告)日：1980-10-28
申请号：US965659
申请日：1978-12-01
申请人： George C. Blytas
发明人： George C. Blytas
IPC分类号： B01D11/04 , C01B17/06 , C09K8/532 , C10G21/08 , C10G29/10 , C10G19/00 , C10G29/08 , E21B21/00
CPC分类号： C10G21/08 , B01D11/0426 , B01D11/0488 , C01B17/06 , C09K8/532 , C10G29/10
摘要： Circulating oil used for removal of sulfur in sour gas wells is contacted with an aqueous solution of a lower polysulfide of an alkali metal or ammonia to form a higher polysulfide of the alkali metal or ammonia, and the oil is separated from the higher polysulfide. The higher polysulfide is converted to lower polysulfide by precipitating part of the sulfur contained therein, and the lower polysulfide is recycled for oil desulfurization.
摘要翻译： 用于除去酸性气井中的硫的循环油与碱金属或氨的下部多硫化物的水溶液接触以形成较高的碱金属或氨的多硫化物，并且油与高级多硫化物分离。 通过沉淀其中所含的部分硫，将较高的多硫化物转化为较低的多硫化物，并将下部多硫化物再循环用于油脱硫。
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