Process for purifying and activating aqueous inorganic salt solutions
employed in the wet spinning of filamentary vinyl polymers
    62.
    发明授权
    Process for purifying and activating aqueous inorganic salt solutions employed in the wet spinning of filamentary vinyl polymers 失效
    净化和活化用于丝状乙烯基聚合物湿纺丝的无机盐水溶液的方法

    公开(公告)号:US4201740A

    公开(公告)日:1980-05-06

    申请号:US913638

    申请日:1978-06-08

    Inventor: Rupert B. Hurley

    CPC classification number: D01F13/00 D01F6/18 Y02P70/625

    Abstract: Filamentary vinyl polymer compositions are commonly prepared according to the following procedure:(a) polymerizing a vinyl monomer in a concentrated aqueous inorganic salt solution to produce a vinyl polymer solution;(b) spinning the resulting vinyl polymer solution into a coagulating bath containing an aqueous solution of the same inorganic salt as that employed in the polymerization step, the concentration of inorganic salt in the coagulating bath being maintained at a level which affords precipitation of the vinyl polymer to form a coherent filamentary gel;(c) washing the gel so produced;(d) recovering the concentrated aqueous inorganic salt solution from the washing and coagulation steps; and(e) recycling the recovered concentrated aqueous inorganic salt solution into the polymerizing step. In such a process, undesirable copper ion impurities accumulate in the recovered concentrated aqueous inorganic salt solution. According to the present invention, the recovered aqueous inorganic salt solution is purified and activated prior to the recycling and use thereof by:(1) introducing a source of sulfide ion into the recovered aqueous inorganic salt solution in an amount sufficient to provide a concentration of about 2 to about 200 ppm of sulfide ion, based upon the concentrated aqueous inorganic salt solution; and(2) removing the precipitate resulting from said sulfide ion introduction.

    Abstract translation: 长丝乙烯基聚合物组合物通常根据以下程序制备:(a)在浓缩的无机盐水溶液中聚合乙烯基单体以制备乙烯基聚合物溶液; (b)将得到的乙烯基聚合物溶液旋转到含有与聚合步骤中使用的相同无机盐的水溶液的凝结浴中,凝固浴中无机盐的浓度保持在乙烯基 聚合物形成相干丝状凝胶; (c)洗涤如此生产的凝胶; (d)从洗涤和凝结步骤回收浓缩的无机盐水溶液; 和(e)将回收的浓缩无水盐水溶液再循环到聚合步骤中。 在这种方法中,不期望的铜离子杂质积聚在回收的浓缩无水盐水溶液中。 根据本发明,回收的无机盐水溶液在回收和再利用之前被纯化和活化,方法是:(1)将硫酸根源引入回收的无机盐水溶液中,其量足以提供浓度 约2至约200ppm的硫化物离子,基于浓缩的无机盐水溶液; 和(2)除去由所述硫化物离子引入产生的沉淀物。

    Waste asbestos recovery from production of asbestos products
    63.
    发明授权
    Waste asbestos recovery from production of asbestos products 失效
    从生产石棉产品废石棉回收

    公开(公告)号:US4131661A

    公开(公告)日:1978-12-26

    申请号:US785363

    申请日:1977-04-07

    CPC classification number: D01F13/00 Y02P70/625

    Abstract: Waste asbestos generated from a production process utilizing a surfactant as the dispersant and a coagulant as a solidifying agent is recovered for reprocessing by treating the waste with an inorganic acid to react with the precipitated surfactant and solubilize the precipitating ions. The precipitating ions are removed by washing. The insoluble residue, containing asbestos and the surfactant is mixed and reacted with an alkali to form a dispersion of asbestos that may be reprocessed by conventional methods.

    Abstract translation: 通过利用表面活性剂作为分散剂和凝固剂作为固化剂的生产方法产生的废石棉用于再处理,通过用无机酸处理废物与沉淀的表面活性剂反应并溶解沉淀离子。 通过洗涤除去沉淀离子。 将含有石棉和表面活性剂的不溶性残渣混合并与碱反应形成可通过常规方法再处理的石棉分散体。

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