公开(公告)号：US09670404B2

公开(公告)日：2017-06-06

申请号：US13542868

申请日：2012-07-06

申请人： Chuanjun Xia ,  Bin Ma ,  Alan DeAngelis

发明人： Chuanjun Xia ,  Bin Ma ,  Alan DeAngelis

IPC分类号： H01L51/54 ,  C09K11/06 ,  C07F15/00 ,  H01L51/00 ,  H05B33/14 ,  H01L51/50

CPC分类号： C09K11/06 ,  C07F15/0033 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/5016 ,  H05B33/14

摘要： Compounds comprising the formula L1L2MX wherein L1, L2, and X are distinct bidentate ligands that form an octahedral complex on the metal M, wherein M is a metal with an atomic weight greater than 40. Compounds of this formula are sublimated more facilely than octahedral metal complexes where L1, L2, and X are not distinct bidentate ligands. Organic light emitting devices are also described wherein the emissive layer may comprise a host material containing an emissive molecule of formula L1L2MX, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including iridium complexes of the formula L1L2IrX wherein L1, L2, and X are distinct bidentate ligands.

公开(公告)号：US09175211B2

公开(公告)日：2015-11-03

申请号：US12868350

申请日：2010-08-25

申请人： Chuanjun Xia ,  Bert Alleyne ,  Nasrin Ansari

发明人： Chuanjun Xia ,  Bert Alleyne ,  Nasrin Ansari

IPC分类号： H01L51/54 ,  C09K11/06 ,  H01L51/00 ,  H01L51/50 ,  C07F15/00 ,  H05B33/14

CPC分类号： C09K11/06 ,  C07F15/0033 ,  C09K2211/1022 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/185 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14

摘要： Compounds comprising a 2-phenylpyridine ligand further substituted with a heterocyclic group are provided. In particular, the compound comprises a 2-phenylpyridine ligand further substituted with a nitrogen-containing heterocycle. The compounds may be used in organic light emitting devices to provide devices having improved efficiency and lifetime.

摘要翻译： 提供了包含另外被杂环基取代的2-苯基吡啶配体的化合物。 特别地，该化合物包含进一步被含氮杂环取代的2-苯基吡啶配体。 这些化合物可以用于有机发光器件中以提供具有改进的效率和寿命的器件。

公开(公告)号：US09034483B2

公开(公告)日：2015-05-19

申请号：US12559764

申请日：2009-09-15

申请人： Bert Alleyne ,  Raymond Kwong ,  Walter Yeager ,  Chuanjun Xia

发明人： Bert Alleyne ,  Raymond Kwong ,  Walter Yeager ,  Chuanjun Xia

IPC分类号： H01L51/54 ,  C09K11/06 ,  H01L51/00 ,  C07F15/00 ,  H01L51/50

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/185 ,  H01L51/5016 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088 ,  H01L51/5206 ,  H01L51/5221 ,  H01L2251/301 ,  H01L2251/308

摘要： Phosphorescent materials and devices having high efficiency and stability, narrow spectrum, and improved processibility. In particular, iridium complexes containing acac-derived ligands with branched alkyl substituents with branching at a position further than the α position to the carbonyl group, were found to be suitable for use as emitters in OLED devices.

摘要翻译： 磷光材料和器件具有高效率和稳定性，光谱窄，加工性好。 特别地，发现含有具有支链烷基取代基的acac衍生配体的铱络合物在比羰基的α位置更位置处具有支链，被发现适用于OLED器件中的发射体。

公开(公告)号：US08927749B2

公开(公告)日：2015-01-06

申请号：US13788775

申请日：2013-03-07

申请人： Pierre-Luc T. Boudreault ,  Chuanjun Xia

发明人： Pierre-Luc T. Boudreault ,  Chuanjun Xia

IPC分类号： C07F7/00 ,  H01L35/24 ,  H01L51/00

CPC分类号： H01L51/0094 ,  C07F7/0816 ,  C07F7/30 ,  C09K11/06 ,  C09K2211/104 ,  H01L51/0059 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016

摘要： A compound according to a formula I and devices incorporating the same are described. The compound according to the formula I can have the structure: wherein X is Si or Ge; R1 and R2 represent mono, di, tri, tetra, or penta substitutions or no substitution; R3, R4 represent mono, di, tri, or tetra substitutions or no substitution; R1 and R2 are optionally joined to form a ring, which may be further substituted; L is a single bond or comprises an aryl or heteroaryl group having from 5-20 carbon atoms, which is optionally further substituted; and A is an aromatic group. A contains a group selected from the group consisting of indole, carbazole, benzofuran, dibenzofuran, benzothiophene, dibenzothiophene, benzoselenophene, dibenzoselenophene, triphenylene, azacarbazole, azadibenzofuran, azadibenzothiophene, azadibenzoselenophene, azatriphenylene, and combinations thereof, which are optionally further substituted. The device can include the compound according to Formula I in an organic layer.

摘要翻译： 描述根据式I的化合物和其结合的化合物。 根据式I的化合物可以具有以下结构：其中X是Si或Ge; R1和R2表示单，二，三，四或五取代或不取代; R3，R4代表单，二，三或四取代或不取代; R1和R2任选地连接形成环，其可进一步被取代; L是单键或包含任选进一步取代的具有5-20个碳原子的芳基或杂芳基; A是芳香族基团。 A包含任选进一步取代的选自吲哚，咔唑，苯并呋喃，二苯并呋喃，苯并噻吩，二苯并噻吩，苯并硒吩，二苯并硒吩，三亚苯，azacarbazole，azadibenzofuran，azadibenzothiophene，azadibenzoselenophen，azatriphenylene及其组合的基团。 该装置可以包括有机层中根据式I的化合物。

公开(公告)号：US20140361252A1

公开(公告)日：2014-12-11

申请号：US13914124

申请日：2013-06-10

申请人： Alexey Dyatkin ,  Chuanjun Xia ,  David Zenan Li

发明人： Alexey Dyatkin ,  Chuanjun Xia ,  David Zenan Li

IPC分类号： H01L51/00 ,  H01L51/50

CPC分类号： H01L51/0081 ,  C07F5/069 ,  H01L51/0085 ,  H01L51/5028

摘要： Aluminum chelate complex compounds with two substituted 8-hydroxyquinoline ligand and one dibenzothiophene, dibenzofuran or dibenzoselenophene ligands or aza-analogs of these molecules, attached directly or through an aromatic spacer to the oxygen atom is provided to improve lifetime, operating voltage and efficiency of an OLED. Additional substitution of dibenzothiophene or dibenzofuran ring may also provide charge delocalization, HOMO modification and higher Tg.

摘要翻译： 提供具有两个取代的8-羟基喹啉配体和一个二苯并噻吩，二苯并呋喃或二苯并硒吩配体或这些分子的氮杂类似物直接或通过芳族间隔基连接到氧原子的铝螯合物络合物，以改善寿命，操作电压和效率 OLED。 二苯并噻吩或二苯并呋喃环的额外取代也可以提供电荷离域，HOMO修饰和更高的Tg。

公开(公告)号：US20140197389A1

公开(公告)日：2014-07-17

申请号：US14113529

申请日：2011-05-27

申请人： Vadim Adamovich ,  Hitoshi Yamamoto ,  Michael S. Weaver ,  Chuanjun Xia

发明人： Vadim Adamovich ,  Hitoshi Yamamoto ,  Michael S. Weaver ,  Chuanjun Xia

IPC分类号： H01L51/50 ,  H01L51/56

CPC分类号： H01L51/5056 ,  H01L51/0054 ,  H01L51/0071 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5028 ,  H01L51/5072 ,  H01L51/56 ,  H01L2251/308 ,  H01L2251/552

摘要： Organic light-emitting devices having a multi-component organic electroluminescent layer. The organic electroluminescent layer comprises a phosphorescent dopant and a host material that is a mixture of at least three different compounds: a wide band gap host compound, an electron-transporting host compound, and a hole-transporting host compound. Use of such a multi-component organic electroluminescent layer may improve device efficiency and lifetime.

摘要翻译： 具有多组分有机电致发光层的有机发光器件。 有机电致发光层包括磷光掺杂剂和作为至少三种不同化合物的混合物的主体材料：宽带隙主体化合物，电子传输性主体化合物和空穴传输性主体化合物。 使用这种多组分有机电致发光层可以提高器件的效率和寿命。

公开(公告)号：US20140131687A1

公开(公告)日：2014-05-15

申请号：US14113533

申请日：2012-06-06

申请人： Chun Lin ,  Chuanjun Xia ,  Bin Ma ,  Lichang Zeng ,  Alan DeAngelis ,  Edward Barron

发明人： Chun Lin ,  Chuanjun Xia ,  Bin Ma ,  Lichang Zeng ,  Alan DeAngelis ,  Edward Barron

IPC分类号： H01L51/00 ,  H01L51/50

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  H01L51/0072 ,  H01L51/50 ,  H01L51/5012 ,  H01L51/5016

摘要： Novel heteroleptic iridium carbene complexes are provided. The complexes have lower-than expected sublimation temperatures, which is beneficial for the processing of these materials in solid state applications. Selective substitution of the ligands provides for phosphorescent compounds that are suitable for use in a variety of OLED devices. The carbene complexes can also be used as materials in a hole blocking layer and/or an electron transport layer to improve device performance.

摘要翻译： 提供新的杂多铱卡宾配合物。 复合物具有低于预期的升华温度，这有利于在固态应用中处理这些材料。 配体的选择性取代提供了适用于各种OLED器件的磷光化合物。 卡宾络合物也可以用作空穴阻挡层和/或电子传输层中的材料，以提高器件性能。

公开(公告)号：US08709615B2

公开(公告)日：2014-04-29

申请号：US13193221

申请日：2011-07-28

申请人： Gregg Kottas ,  Nasrin Ansari ,  Zeinab Elshenawy ,  Alan DeAngelis ,  Chuanjun Xia

发明人： Gregg Kottas ,  Nasrin Ansari ,  Zeinab Elshenawy ,  Alan DeAngelis ,  Chuanjun Xia

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1088 ,  C09K2211/185 ,  H01L51/0054 ,  H01L51/0056 ,  H01L51/0058 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/50 ,  H01L51/5012 ,  H01L51/5016 ,  H05B33/14

摘要： Novel phosphorescent heteroleptic iridium complexes with phenylpyridine and dibenzo-containing ligands are provided. Alkyl substitution at specific positions on the ligands gives rise to compounds with improved OLED properties, including saturated green emission.

摘要翻译： 提供了具有苯基吡啶和二苯并配体的新颖的磷光杂光铱络合物。 在配体上的特定位置上的烷基取代产生具有改善的OLED性质的化合物，包括饱和绿色发射。

公开(公告)号：US20140103305A1

公开(公告)日：2014-04-17

申请号：US13872840

申请日：2013-04-29

申请人： Bin MA ,  Alan DeAngelis ,  Chuanjun Xia ,  Vadim Adamovich

发明人： Bin MA ,  Alan DeAngelis ,  Chuanjun Xia ,  Vadim Adamovich

IPC分类号： H01L51/00

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/185 ,  H01L51/5016

摘要： Compounds are provided that comprise a ligand having a 5-substituted 2-phenylquinoline. In particular, the 2-phenylquinoline may be substituted with a bulky alkyl at the 5-position. These compounds may be used in organic light emitting devices, in particular as red emitters in the emissive layer of such devices, to provide devices having improved properties.

摘要翻译： 提供了包含具有5-取代的2-苯基喹啉的配体的化合物。 特别地，2-苯基喹啉可以在5位被大体积烷基取代。 这些化合物可以用于有机发光器件，特别是在这种器件的发射层中的红色发射体，以提供具有改进性能的器件。

公开(公告)号：US20140054563A1

公开(公告)日：2014-02-27

申请号：US13798668

申请日：2013-03-13

申请人： Chuanjun Xia ,  Chun Lin ,  Gregg Kottas ,  Zeinab Elshenawy

发明人： Chuanjun Xia ,  Chun Lin ,  Gregg Kottas ,  Zeinab Elshenawy

IPC分类号： H01L51/00

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/5016 ,  H05B33/14

摘要： Phosphorescent materials are provided, where the materials comprise a coordination compound having at least one ligand L3 having Formula (I): wherein A and B are each independently a 5-membered or 6-membered carbocyclic or heterocyclic ring; wherein RA, RB, RC, and RD each represent mono, di, tri, tetra substitutions, or no substitution; wherein Z1, Z2, Z3, Z4, Z5, Z6, Z7, and Z8 are each selected from N or C; wherein at least one of Z1, Z2, Z3, Z4, Z5, Z6, Z7, and Z8 is N; wherein one of Z1, Z2, Z3, and Z4 is C that is bonded to N of A; wherein Z is selected from the group consisting of BR, NR, PR, O, S, Se, C═O, S═O, SO2, CRR′, SiRR′, and GeRR′; wherein R, R′, RA, RB, RC, and RD are described herein; wherein L3 is coordinated to a metal M1; and wherein L3 may be linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand. Devices, such as organic light emitting devices, comprising such compounds are also provided.

摘要翻译： 提供磷光材料，其中材料包含具有至少一个具有式（I）的配体L3的配位化合物：其中A和B各自独立地为5元或6元碳环或杂环; 其中RA，RB，RC和RD各自表示单，二，三，四取代或不取代; 其中Z 1，Z 2，Z 3，Z 4，Z 5，Z 6，Z 7和Z 8各自选自N或C; 其中Z 1，Z 2，Z 3，Z 4，Z 5，Z 6，Z 7和Z 8中的至少一个为N; 其中Z1，Z2，Z3和Z4中的一个为与N的N键合的C; 其中Z选自由BR，NR，PR，O，S，Se，C = O，S = O，SO 2，CRR'，SiRR'和GeRR'组成的组。 其中R，R'，RA，RB，RC和RD在本文中描述; 其中L3与金属M1配位; 并且其中L3可以与其它配体连接以包含三齿，四齿，五齿戊酸或六齿配体。 还提供了包含这些化合物的装置，例如有机发光装置。