摘要:
A liquid developing agent comprising a resin dispersed in a nonaqueous solvent wherein said comprisecopolymer resin grains produced by polymerization of a solution containing one monofunctional monomer (a) which is soluble in said nonaqueous solvent but is rendered insoluble by polymerization and at least one monomer (B) which contains at least two polar groups and/or polar linkage groups and is represented by ##STR1## in the presence of a resin for dispersion stabilization which is soluble in said nonaquous solvent and is a polymer which has repeating units represented by the general formula (I) below ##STR2##
摘要:
A liquid developer for electrostatic photography comprising a resin dispersed in a non-aqueous solvent having an electric resistance of at least 10.sup.9 .OMEGA.cm and a dielectric constant of not higher than 3.5, wherein the dispersed resin is a polymer resin obtained by polymerizing a solution containing at least one monofunctional monomer (A) which is soluble in the aforesaid non-aqueous solvent but become insoluble after being polymerized, in the presence of a dispersion-stabilizing resin which is soluble in the aforesaid non-aqueous solvent and at least one oligomer (B) having a number average molecular weight of not more than 1.times.10.sup.4 and having at least one polar group selected from a carboxy group, a sulfo group, a hydroxy group, a formyl group, an amino group, a phosphono group, and ##STR1## wherein R.sup.0 represents a hydrocarbon group or --OR.sup.1, (wherein R.sup.1 represents a hydrocarbon group) bonded to only one terminal of the main chain of a polymer composed of a recurring unit represented by following formula (II): ##STR2## wherein V.sup.1, R.sup.2, a.sup.1 and a.sup.2 are as defined in the specification. The liquid developer is excellent in dispersion stability, re-dispersibility, and fixability, and also is capable of forming an offset printing plate having excellent ink-receptivitiy for printing ink and excellent printing durability by electrophotography.
摘要:
Disclosed is a liquid developer composition for electrophotography. In a non-aqueous solvent there is dispersed copolymer resin particles having been polymerized from at least one monofunctional monomer (A) and at least one monofunctional macromonomer (B) such as (III) ##STR1## in the presence of a dispersion stabilization resin copolymerizable with a mono-functional monomer (A).
摘要:
An liquid developer for electrostatic photography is described, comprising a carrier liquid having an electric resistance of at least 10.sup.9 .OMEGA..multidot.cm and a dielectric constant of not more than 3.5, and a resin dispersed therein, said resin being obtained by polymerizing a monomer, which is soluble in said carrier liquid but becomes insoluble upon being polymerized, in the presence of at least one kind of a soluble dispersion stabilizing resin, said soluble dispersion stabilizing resin being a copolymer containing at least recurring units represented by following formulae (IIIa) and (IIIb) obtained by applying a reaction for introducing an unsaturated bond into a copolymer obtained by polymerizing a monomer represented by formula (I) and a monomer represented by formula (III) ##STR1## wherein in formula (I), V represents --O--, --S--, --CO--, --CO.sub.2 --, --SO.sub.2 --, --OCO--, --CONH--, --CONR'-- (wherein R' represents a hydrocarbon group), --NHCO--, NHCO.sub.2 --, or --NHCONH--; X represents --CO.sub.2 H, --COCl, --OH, --SH, --NH.sub.2, --NCO, or --SO.sub.2 CH.sub.2 CH.sub.2 Cl; W represents a hydrocarbon group linking said atomic group V and said atomic group X directly or through a hetero atom, or W represents a chemical bond; and a.sub.1, a.sub.2, and a.sub.3 each represents a hydrogen atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group;in formula (II), Y represents --O--, --S--, --CO--, --CO.sub.2 --, --SO.sub.2 --, --OCO--, CONH--, --CONR"-- (wherein R" represents a hydrocarbon group), --NHCO--, --NHCO.sub.2 --, or --NHCONH--; R represents a hydrocarbon group; and b.sub.1, b.sub.2, and b.sub.3 each represents a hydrocarbon atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group;in formula (IIIa), a.sub.1, a.sub.2, a.sub.3, V, and W have the same meanings as defined for formula (I); X' represents --CO.sub.2 --, --COS--, --SCO--, --CONH--, --OCO--, --NHCO--, --NHCONH--, --SO.sub.2 --, --O--, or --S--; Z represents a hydrocarbon group linking said atomic group X' and unsaturated bond directly or through a hetero atom, or Z represents a chemical bond; the total number of atoms of the main chain portion of atomic group --V--W--X'--Z-- must, however, be at least 9; and d.sub.1, d.sub.2, and d.sub.3 each represents a hydrocarbon atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group; andin formula (IIIb), b.sub.1, b.sub.2, b.sub.3, Y, and R have the same meanings as defined for formula (II).
摘要:
An ink jet printing method which comprises: directly forming an image on a printing medium on the basis of signals of image data; and fixing the image to produce a printed matter, wherein said image formation is carried out by an ink jet system of ejecting an oily ink by an electrostatic field. The method preferably further comprises cleaning an ink jet head, said cleaning step comprising: immersing said ink jet head in a cleaning solution; and applying voltage to said ink jet head. Alternatively, the method preferably further comprises, when a malfunction happens, either or both of stopping the image formation and eliminating a cause of the malfunction. Also disclosed are printing apparatuses suitably used for these methods.
摘要:
An on-press recording type lithographic printing method comprising mounting a plate material on a plate cylinder of a press, ejecting an oil-based ink onto the plate material from a recording head having a plurality of ejection channels utilizing an electrostatic field according to signals of image data to directly form an image on the surface of the plate material and prepare a printing plate, and then effecting the lithographic printing using the printing plate as it is, wherein the distance of the ejection channels is 170 &mgr;m, or more (150 dpi (150 dots per inch) or less as calculated in terms of resolution of recorded image).
摘要:
A process for preparing an ink-jet system printing plate, wherein an image is formed according to a hot melt type ink-jet system by heat-melting an ink composition that is solid at ordinary temperature, spraying droplets of the ink composition in a hot melt state from nozzles onto an intermediate transferrer to form an image, and contact-transferring the image on the intermediate transferrer to an image receiving layer of a planographic printing plate precursor, the image receiving layer being provided on a water-resistive support and containing zinc oxide and a binder resin, and thereafter, a nonimage area of the image receiving layer is desensitized by chemical reaction treatment to prepare a planographic printing plate.
摘要:
An ink jet recording method comprising: supplying insulating oily ink to an ejection part disposed so as to face a recording medium; irradiating the ink at the ejection part with light; applying an electrostatic field to the ink at the ejection part under irradiation in accordance with image data so as to eject the ink to form an image on the recording medium; and recovering excess ink from the ejection part. Also disclosed is an ink jet recording apparatus suitable for the ink jet recording method.
摘要:
An oil-based ink for a printing plate by an ink jet process comprising spraying an oil-based ink comprising at least resin particles dispersed in a nonaqueous carrier liquid having an electric resistance of 10.sup.9 .OMEGA.cm or more and a dielectric constant of 3.5 or less on an image receiving layer of a lithographic printing plate precursor dropwise from a nozzle to form an image, and then desensitizing a non-image area of the image receiving layer by a chemical reaction to prepare a lithographic printing plate, the image receiving layer being formed on a water-resistant support and comprising zinc oxide and a binding resin; and a surface of the image receiving layer having a contact angle with water of 50.degree. or more, wherein the resin particles dispersed are polymer particles obtained by polymerization granulation of a solution comprising (i), (ii) and (iii): (i) at least one monofunctional monomer (A) which is soluble in a nonaqueous solvent which is at least miscible with the nonaqueous carrier liquid and becomes insoluble therein by polymerization; (ii) (ii-a) at least one monomer which is copolymerizable with the monomer (A), or (ii-b) at least one monofunctional macromonomer (MA) having a weight average molecular weight of 2.times.10.sup.4 or less in which a polymerizable double bond group is combined with only one end of a main chain of a polymer comprising a repeating unit corresponding to a monomer; and (iii) at least one dispersion-stabilizing resin which is soluble in the nonaqueous solvent and has no graft group polymerizing with a monomer.
摘要:
A method for forming an image using scanning exposure of an electrophotographic lithographic printing plate comprising an electrically conductive support having thereon a photoconductive layer containing an inorganic photoconductor, a chemical sensitizer, a sensitizing dye and a binder resin, and a back layer on the opposite side of the photoconductive layer, wherein the back layer has a surface resistivity of 1.times.10.sup.10 .OMEGA. or less and the sensitizing dye in the photoconductive layer is at least one selected from the compounds represented by formulae (I) and (II) defined in the disclosure.