Process For Producing 3,7-Diaza-Bicyclo[3.3.1]Nonane-Metal Complexes
    72.
    发明申请
    Process For Producing 3,7-Diaza-Bicyclo[3.3.1]Nonane-Metal Complexes 审中-公开
    制备3,7-二氮杂双环[3.3.1]壬烷 - 金属络合物的方法

    公开(公告)号:US20130072685A1

    公开(公告)日:2013-03-21

    申请号:US13575747

    申请日:2011-01-28

    CPC classification number: C07F15/025 C07D471/08 C07F13/005

    Abstract: The invention describes a process for producing metal complexes of the general formula (2): [MaLxXn]Ym (2), where M is a metal from the group comprising Mn(II), Mn(III), Mn(IV), Fe(II), Fe(III) or Fe(IV), X is a coordinated compound selected from mono- bi- or tri-charged anions or neutral molecules which are able to coordinate with a metal mono- bi- or tri-dentate, Y represents a non-coordinated counter-ion which ensures charge equalization of the complex, L represents a ligand of the general formula (1) or the protonized or de-protonized form thereof, and a, x, n, m, R, R1, R2, R3 and z have the meaning specified in claim 1. Said process is characterized in that the reaction of a ligand of the formula (1) with an iron or manganese salt in a heterogeneous reaction is carried out in water, where the reaction is carried out in a temperature range of 35 to 50° C. and the pH value of the reaction mixture is from 1 to 3 after the addition of the iron or manganese salt.

    Abstract translation: 本发明描述了一种制备通式(2)金属络合物的方法:[MaLxXn] Ym(2),其中M是包含Mn(II),Mn(III),Mn(IV),Fe (II),Fe(III)或Fe(IV),X是选自单 - 或三 - 电荷的阴离子或中性分子的配位化合物,其能够与金属单 - 或三 - Y表示非配位的抗衡离子,其确保络合物的电荷均衡,L表示通式(1)的配体或其质子化或去质子化形式,以及a,x,n,m,R,R 1 R 2,R 3和Z具有权利要求1中所述的含义。所述方法的特征在于式(1)的配体与非均相反应中的铁或锰盐的反应在水中进行,其中反应 在35〜50℃的温度范围内进行,加入铁盐或锰盐后,反应混合物的pH值为1〜3。

    Bleach activator mixtures
    75.
    发明授权
    Bleach activator mixtures 有权
    漂白活化剂混合物

    公开(公告)号:US07541324B2

    公开(公告)日:2009-06-02

    申请号:US11662311

    申请日:2005-09-03

    CPC classification number: C11D3/3935 C11D3/3907 C11D3/391 C11D3/3917

    Abstract: What are claimed are synergistically active bleach activator mixtures consisting of a) a hydroxybenzoic acid derivative of the formula 1 in which R is C8-C11-alkyl, and b) tetraacetylethylenediamine and/or 1,5-diacetyl-2,4-dioxo-1,3,5-hexahydrotriazine.

    Abstract translation: 所要求的是协同活性的漂白活化剂混合物,其由a)式1的羟基苯甲酸衍生物,其中R是C 8 -C 11 - 烷基,b)四乙酰基乙二胺和/或1,5-二乙酰基-2,4-二氧代 - 1,3,5-六氢三嗪。

    Granular bleach-activating mixtures
    76.
    发明申请
    Granular bleach-activating mixtures 审中-公开
    颗粒漂白剂 - 活化混合物

    公开(公告)号:US20090130224A1

    公开(公告)日:2009-05-21

    申请号:US11991051

    申请日:2006-08-25

    CPC classification number: C11D3/3907 C11D3/391 C11D3/3917 C11D3/392 C11D3/3935

    Abstract: The invention relates to an improved bleach activator and bleach activator compositions in the form of granules for use in washing, cleaning and disinfectant compositions. More specifically, the invention relates to granular bleach-activating mixtures that consist substantially of a) a hydroxybenzoic acid derivative of formula (I) in which R is C8-C11-alkyl and b) tetraacetyl ethylene diamine and/or 1,5-diacetyl-2,4-dioxo-1,3,5-hexahydrotriazine, the granules being free of binding agents.

    Abstract translation: 本发明涉及用于洗涤,清洁和消毒组合物的颗粒形式的改进的漂白活化剂和漂白活化剂组合物。 更具体地说,本发明涉及基本由a)式(I)的羟基苯甲酸衍生物(其中R是C 8 -C 11 - 烷基)和b)四乙酰基乙二胺和/或1,5-二乙酰基 -2,4-二氧代-1,3,5-六氢三嗪,颗粒不含粘合剂。

    Mixtures Of Bleaching Agents
    77.
    发明申请
    Mixtures Of Bleaching Agents 有权
    漂白剂的混合物

    公开(公告)号:US20080105850A1

    公开(公告)日:2008-05-08

    申请号:US11662305

    申请日:2005-09-03

    CPC classification number: C11D3/3935 C11D3/3917 C11D3/392 C11D3/3945

    Abstract: Mixtures of bleaching agentsWhat are claimed are synergistically active bleach mixtures consisting ofa) a compound of the formula (1) in which n is 3, 4 or 5, andb) tetraacetylethylenediamine and/or 1,5-diacetyl-2,4-dioxo-1,3,5-hexa-hydrotriazine.

    Abstract translation: 漂白剂的混合物所要求的是协同活性的漂白混合物,其由a)式(1)的化合物(其中n为3,4或5)和b)四乙酰基乙二胺和/或1,5-二乙酰基-2,4 - 二氧代-1,3,5-六氢 - 三嗪。

    Mixtures Of Ammonionitrile Bleach Activators And Amino Acids
    78.
    发明申请
    Mixtures Of Ammonionitrile Bleach Activators And Amino Acids 审中-公开
    氨腈漂白活化剂和氨基酸的混合物

    公开(公告)号:US20080064620A1

    公开(公告)日:2008-03-13

    申请号:US11629325

    申请日:2005-06-08

    Applicant: Gerd Reinhardt

    Inventor: Gerd Reinhardt

    CPC classification number: C11D3/3925 C11D3/33

    Abstract: Mixtures of ammonionitrile bleach activators and amino acids Mixtures of ammonionitrile bleach activators and amino acids which contain at least two nitrogen atoms are claimed, as is their use in bleaches and in washing and cleaning compositions. The presence of the amino acid lowers the color- and fiber-damaging action of the ammonionitriles.

    Abstract translation: 氨腈漂白活化剂和氨基酸的混合物要求具有至少两个氮原子的氨腈漂白活化剂和氨基酸的混合物,以及它们在漂白剂和洗涤和清洁组合物中的用途。 氨基酸的存在降低了氨化腈的着色和纤维损伤作用。

    Use of transition metal complexes having lactam ligands as bleaching catalysts
    79.
    发明申请
    Use of transition metal complexes having lactam ligands as bleaching catalysts 失效
    使用具有内酰胺配位体的过渡金属络合物作为漂白催化剂

    公开(公告)号:US20050181964A1

    公开(公告)日:2005-08-18

    申请号:US10954425

    申请日:2004-09-30

    CPC classification number: C11D3/3932

    Abstract: The use of compounds of the formula (1) M(L)nXm  (1) in which M is a metal atom from the group consisting of Mn, Fe, Co, Ni, Mo and W, L is a ligand from the group consisting of the cyclic carboxamides (lactams), X is chloride, bromide, nitrate, perchlorate, citrate, hexafluorophosphate or anions of organic acids having C1-C22 carbon atoms and n is a number from 2 to 4 and m is a number from 0 to 4, as catalysts for peroxygen compounds, in particular in detergents, bleaches and cleaning agents, is claimed.

    Abstract translation: 使用式(1)的化合物<?in-line-formula description =“In-line Formulas”end =“lead”?> M(L)N (1)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中M是由Mn,Fe,Co,Ni,Mo组成的组中的金属原子, W,L是来自环状酰胺(内酰胺)的配体,X是氯化物,溴化物,硝酸盐,高氯酸盐,柠檬酸盐,六氟磷酸盐或具有C 1 -C 3的有机酸阴离子 > 22个碳原子,n为2〜4的数,m为0〜4的数,作为过氧化合物的催化剂,特别是洗涤剂,漂白剂和清洗剂。

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