公开(公告)号：US09102903B2

公开(公告)日：2015-08-11

申请号：US13982975

申请日：2012-02-03

Applicant: Gerd Reinhardt ,  Werner Janitschek ,  Miriam Ladwig

Inventor： Gerd Reinhardt ,  Werner Janitschek ,  Miriam Ladwig

IPC: C11D3/39 ,  C11D3/395 ,  C11D7/18 ,  C11D7/38 ,  C11D3/386 ,  C11D1/00 ,  C11D7/32 ,  C11D3/43

CPC classification number: C11D3/3951 ,  C11D1/00 ,  C11D3/386 ,  C11D3/3905 ,  C11D3/391 ,  C11D3/392 ,  C11D3/3932 ,  C11D3/43 ,  C11D7/32

Abstract: The invention relates to the use of manganese or iron complexes which, as well as a tetraoxolene unit, contain two macrocyclic, N-containing ligands, especially cyclen or cyclam ligands, in washing and cleaning compositions in the form of granules or powder or solution or suspension for bleaching of colored stains both on textiles and on hard surfaces. The invention also relates to washing and cleaning compositions which comprise such complexes as bleach activators and to the use thereof for textile washing or for dishwashing detergents and other uses in personal care and other areas.

Abstract translation: 本发明涉及锰或铁络合物的用途以及四氧杂环己烷单元在颗粒或粉末或溶液形式的洗涤和清洁组合物中含有两个大环的含N配体，特别是环烯或环基配体，或 在纺织品和硬表面上漂白有色染料的悬浮液。 本发明还涉及洗涤和清洁组合物，其包含诸如漂白活化剂的复合物，以及其用于纺织品洗涤或餐具洗涤剂的用途以及个人护理和其它区域中的其它用途。

公开(公告)号：US20130217911A1

公开(公告)日：2013-08-22

申请号：US13816686

申请日：2011-08-06

Applicant: Melanie Sajitz ,  Gerd Reinhardt ,  Isabel Scheffer ,  Werner Janitschek ,  Ina Herrgen

Inventor： Melanie Sajitz ,  Gerd Reinhardt ,  Isabel Scheffer ,  Werner Janitschek ,  Ina Herrgen

IPC: C07C67/14

CPC classification number: C07C67/14 ,  C07C69/017 ,  C07C69/24 ,  C07C69/78

Abstract: The invention relates to a method for producing acyloxy benzoic acids of the formula (I), in which R1 is a linear or branched saturated alkyl group with 6 to 30 carbon atoms, a linear or branched mono- or polyunsaturated alkenyl group with 6 to 30 carbon atoms, or an aryl group with 6 to 30 carbon atoms. The acyloxy benzoic acids of the formula (I) are produced from para-hydroxy benzoic acid and a corresponding carboxylic acid halide in the presence of an alkali hydroxide.

Abstract translation: 本发明涉及一种制备式（I）的酰氧基苯甲酸的方法，其中R 1为具有6至30个碳原子的直链或支链饱和烷基，具有6至30个直链或支链单或多不饱和链烯基 碳原子或具有6至30个碳原子的芳基。 式（I）的酰氧基苯甲酸由对羟基苯甲酸和相应的羧酸卤化物在碱金属氢氧化物存在下制备。

公开(公告)号：US20120058927A1

公开(公告)日：2012-03-08

申请号：US13263028

申请日：2010-04-01

Applicant: Georg Borchers ,  Gerd Reinhardt ,  Andreas Schottstedt

Inventor： Georg Borchers ,  Gerd Reinhardt ,  Andreas Schottstedt

IPC: C11D3/60 ,  C11D17/00

CPC classification number: C11D3/3932 ,  C11D3/3935 ,  C11D17/0039 ,  C11D17/06

Abstract: The invention relates to co-granules containing a granule core and a sheath or coating layer surrounding the granule core. Said co-granules are characterised in that the granule core contains a) at least one bleach activator, a2) between 0 and 20 wt. % of the total quantity of at least one bleach catalyst contained in the co-granule, and c) at least one binding agent, and the sheath or coating layer contains d) between 80 and 100 wt. % of the total quantity of the at least one bleach catalyst contained in the co-granule, and e) at least one coating agent. The co-granules are advantageously suitable for producing cleaning products and detergents and especially products for washing crockery in a machine.

Abstract translation: 本发明涉及包含颗粒核心和围绕颗粒核心的鞘或包衣层的共颗粒剂。 所述共颗粒的特征在于颗粒核含有a）至少一种漂白活化剂，a2）0-20wt。 包含在共颗粒中的至少一种漂白催化剂总量的百分比，和c）至少一种粘合剂，并且所述护套或涂层含有d）80-100重量份。 包含在共颗粒中的至少一种漂白催化剂的总量的％，以及e）至少一种涂布剂。 共混颗粒有利地适用于生产清洁产品和洗涤剂，特别是用于在机器中洗涤陶器的产品。

公开(公告)号：US20110021812A1

公开(公告)日：2011-01-27

申请号：US12921468

申请日：2009-03-04

Applicant: Gerd Reinhardt ,  Peter Naumann ,  Georg Borchers ,  Mathias Groeschen

Inventor： Gerd Reinhardt ,  Peter Naumann ,  Georg Borchers ,  Mathias Groeschen

IPC: C07C309/04

CPC classification number: C11D1/143 ,  C11D11/02

Abstract: A process for preparing solid alkaline earth metal salts of secondary paraffinsulphonic acids is claimed. This process comprises converting an aqueous solution of a secondary paraffinsulphonic acid and an alkaline earth metal hydroxide into solid form by spray drying.

Abstract translation: 要求保护二级链烷烃磺酸的固体碱土金属盐的方法。 该方法包括通过喷雾干燥将次级链烷烃磺酸和碱土金属氢氧化物的水溶液转化为固体形式。

公开(公告)号：US20080113036A1

公开(公告)日：2008-05-15

申请号：US11662311

申请日：2005-09-03

Applicant: Gerd Reinhardt ,  Georg Borchers

Inventor： Gerd Reinhardt ,  Georg Borchers

IPC: C11D3/39 ,  C11D3/30 ,  A01N59/00 ,  A01P1/00

CPC classification number: C11D3/3935 ,  C11D3/3907 ,  C11D3/391 ,  C11D3/3917

Abstract: What are claimed are synergistically active bleach activator mixtures consisting ofa) a hydroxybenzoic acid derivative of the formula 1 in which R is C8-C11-alkyl, andb) tetraacetylethylenediamine and/or 1,5-diacetyl-2,4-dioxo-1,3,5-hexahydrotriazine.

Abstract translation: 所要求的是协同活性的漂白活化剂混合物，其由a）式1的羟基苯甲酸衍生物，其中R是C 8 -C 11 - 烷基，b） 四乙酰基乙二胺和/或1,5-二乙酰基-2,4-二氧代-1,3,5-六氢三嗪。

公开(公告)号：US06875734B2

公开(公告)日：2005-04-05

申请号：US10769963

申请日：2004-02-02

Applicant: Gerd Reinhardt ,  Ekaterina Jonas ,  Daniel Kewitz ,  Aylin Karadag ,  Hans Prehler

Inventor： Gerd Reinhardt ,  Ekaterina Jonas ,  Daniel Kewitz ,  Aylin Karadag ,  Hans Prehler

IPC: D06L3/02 ,  C07F13/00 ,  C07F15/02 ,  C11D3/39 ,  C11D7/18 ,  C11D7/32 ,  C11D7/38 ,  C11D7/54

CPC classification number: C11D3/3932

Abstract: The use of compounds of the formula (1) M(L)nXm  (1) where M is a metal atom from the group Mn, Fe, Co, Ni, Mo, W, L is a ligand from the group of nitrogen-containing heterocycles, X is chloride, bromide, nitrate, perchlorate, sulfate, ammonia, tetrafluoroborate, hexafluorophosphate or an anion of an organic acid having 1 to 22 carbon atoms, n is a number from 2 to 4 and m is a number from 0 to 4, as catalyst for peroxygen compounds, in particular in washing, bleaching and cleaning compositions is claimed.

Abstract translation: 使用式（1）的化合物，其中M是Mn，Fe，Co，Ni，Mo，W，L中的金属原子，是来自含氮杂环基团的配体，X是氯化物，溴化物，硝酸盐 ，高氯酸盐，硫酸盐，氨，四氟硼酸盐，六氟磷酸盐或具有1至22个碳原子的有机酸的阴离子，n为2至4的数，m为0至4的数，作为过氧化合物的催化剂，特别是 在洗涤中，要求保护漂白和清洁组合物。

公开(公告)号：US20050054550A1

公开(公告)日：2005-03-10

申请号：US10897838

申请日：2004-07-23

Applicant: Georg Borchers ,  Alexander Lerch ,  Gerd Reinhardt

Inventor： Georg Borchers ,  Alexander Lerch ,  Gerd Reinhardt

IPC: C07C303/44 ,  C07C309/42 ,  C11D1/22 ,  C11D3/42 ,  C11D11/00 ,  C11D1/00

CPC classification number: C11D3/3935 ,  C09B23/148 ,  C11D1/22 ,  C11D3/42 ,  C11D11/0082

Abstract: A process is claimed for preparing granulated acyloxybenzenesulfonates which consists in granulating a mixture composed essentially of acyloxybenzenesulfonate and optical brightener.

Abstract translation: 要求一种制备粒状酰氧基苯磺酸盐的方法，其包括将基本上由酰氧基苯磺酸盐和荧光增白剂组成的混合物制粒。

公开(公告)号：US06822113B2

公开(公告)日：2004-11-23

申请号：US10431951

申请日：2003-05-08

Applicant: Gerd Reinhardt ,  Peter Naumann ,  Alexander Lerch ,  Wolf-Dieter Mueller ,  Narayan D. Sadanani

Inventor： Gerd Reinhardt ,  Peter Naumann ,  Alexander Lerch ,  Wolf-Dieter Mueller ,  Narayan D. Sadanani

IPC: C07C6900

CPC classification number: C07C303/32 ,  C07C303/22 ,  C07C309/42

Abstract: A process for preparing acyloxybenzenesulfonates by reacting anhydrous phenolsulfonates with carboxylic acid derivatives comprises conducting the reaction with a salt of a phenolsulfonic acid which has a water content of less than 0.5% by weight and has been contacted with a substance having basic properties.

公开(公告)号：US06746996B2

公开(公告)日：2004-06-08

申请号：US10052123

申请日：2002-01-17

Applicant: Gerd Reinhardt ,  Michael Seebach ,  Nicole Reichardt ,  Laszlo I. Simandi ,  Tatiana M. Simandi ,  Gabor Besenyei

Inventor： Gerd Reinhardt ,  Michael Seebach ,  Nicole Reichardt ,  Laszlo I. Simandi ,  Tatiana M. Simandi ,  Gabor Besenyei

IPC: C11D738

CPC classification number: C11D3/3932

Abstract: Transition metal complexes used as bleach catalysts of the formula (1) M(L)nXm  (1) where M is a metal atom from the group Mn, Fe, Co, Ni, Mo, W, L is a ligand of the formula R1R2C═N—O(H)z R1 is C1-C22-alkyl, C2-C22-alkenyl or C5-C24-aryl, R2 is H, C1-C22-alkyl, C2-C22-alkenyl, C5-C24-aryl or where z=0 or 1, X is a neutral or anion ligand from the group consisting of pyridines, imidazolines, methylimidazoles, picolines, lutidines, chloride, bromide, nitrate, perchlorate, citrate, hexafluorophosphate or anions of organic acids having C1-C22 carbon atoms, n is a number from 2 to 4 and m is a number from 0 to 4.

Abstract translation: 用作式（1）的漂白催化剂的过渡金属络合物其中M是Mn，Fe，Co，Ni，Mo，W，L中的金属原子，式R的配体是C 1 -C 22烷基，C 2 -C 22 - 烯基或C 5 -C 24 - 芳基，R 2是H，C 1 -C 22 - 烷基，C 2 -C 22 - 烯基，C 5 -C 24 - 芳基或其中z = 0或1，X是来自吡啶的中性或阴离子配体 ，咪唑啉，甲基咪唑，吡啶甲酸，l啶，氯化物，溴化物，硝酸盐，高氯酸盐，柠檬酸盐，六氟磷酸盐或具有C 1 -C 22碳原子的有机酸阴离子，n为2至4的数，m为0至4的数。

公开(公告)号：US5610318A

公开(公告)日：1997-03-11

申请号：US455351

申请日：1995-05-31

Applicant: Frank Jaekel ,  Gerd Reinhardt ,  Wolf-Dieter M uller

Inventor： Frank Jaekel ,  Gerd Reinhardt ,  Wolf-Dieter M uller

IPC: C07D207/452 ,  C07D207/40 ,  C07D209/48 ,  C07D211/88 ,  C07D223/10 ,  C07D275/02 ,  C07D275/06 ,  C07D279/02 ,  C07D281/02 ,  C07D401/06 ,  C07D401/10 ,  C07D403/06 ,  C07D403/10 ,  C07D417/06 ,  C07D417/10 ,  C11D3/39 ,  C11D3/395 ,  C11D3/48 ,  C11D7/54 ,  D06L3/02 ,  C07D207/02

CPC classification number: C07D207/40 ,  C07D209/48 ,  C11D3/392

Abstract: This invention is directed to a process for preparing a compound containing a persalt activators and salts thereof which are derived from imidocarboxylic acids and sulfimidocarboxylic acids of the formula I: ##STR1## in which A is a group of the formula ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, chlorine, bromine, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, aryl, or alkylaryl,R.sup.2 is hydrogen, chlorine, bromine, --SO.sub.3 M, --CO.sub.2 M or --OSO.sub.3 M, X is C.sub.1 -C.sub.19 -alkylene or arylene,B is a group of the formula C.dbd.O or SO.sub.2,L is a leaving group.

Abstract translation: 本发明涉及一种制备含有衍生自式I的亚氨基羧酸和亚磺酰亚胺羧酸的含有活性剂及其盐的化合物的方法：其中A是下式的基团： n是数字0,1或2，R1是氢，氯，溴，C1-C20-烷基，C2-C20-烯基，芳基或烷基芳基，R2是氢，氯，溴， SO 3 M，-CO 2 M或-OSO 3 M，X为C 1 -C 19 - 亚烷基或亚芳基，B为式C = O或SO 2的基团，L为离去基团。