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71.发明授权公开(公告)号：US08440845B2
公开(公告)日：2013-05-14
申请号：US13235575
申请日：2011-09-19
IPC分类号： C07D493/04 , C07D307/20
CPC分类号： C07D493/04 , C07D307/20
摘要： A process is disclosed for converting a polysaccharide-containing biomass material to platform chemicals.The process comprises dissolving the polysaccharides in an inorganic molten salt hydrate, converting the polysaccharides to monosaccharides, and converting the monosaccharides to derivatized (di)anhydro sugars that are easily separable from the inorganic molten salt hydrate.The derivatized (di)anhydro sugars are useful as fuel additives and fuel substitutes.
摘要翻译： 公开了将含多糖的生物质材料转化为平台化学品的方法。 该方法包括将多糖溶解在无机熔融盐水合物中，将多糖转化为单糖，并将单糖转化为易于与无机熔融盐水合物分离的衍生化（二）脱氢糖。 衍生的（二）脱水糖可用作燃料添加剂和燃料替代品。
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72.发明申请Co-Processing Solid Biomass In A Conventional Petroleum Refining Process Unit 有权在常规石油炼制工艺装置中共同处理固体生物质公开(公告)号：US20130068997A1
公开(公告)日：2013-03-21
申请号：US13617289
申请日：2012-09-14
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C09K3/00
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译： 制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。 生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。 搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。 共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。 生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。
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73.发明申请PROCESSING OF BIOMASS-DERIVED OXYGENATES WITH PARTICLES COMPRISING A COKE DEPOSIT 有权用含有沉淀物的颗粒加工生物质衍生的氧化剂公开(公告)号：US20130048915A1
公开(公告)日：2013-02-28
申请号：US13196543
申请日：2011-08-02
CPC分类号： C10G11/182 , C01B3/44 , C01B2203/0233 , C01B2203/0238 , C01B2203/1211 , C10G2300/1014 , C10G2300/708 , C10G2300/80 , C10G2300/807 , Y02P20/142 , Y02P20/145 , Y02P20/52 , Y02P30/20
摘要： A method is disclosed for producing a mixture of CO and H2 (syn-gas). The method comprises contacting particles containing a coke deposit with oxygenated molecules derived from biomass. In a preferred embodiment the particles are catalyst particles.The method may be carried out in the regenerator of a conventional fluid catalyst cracking (FCC) unit.
摘要翻译： 公开了一种用于生产CO和H 2（合成气）的混合物的方法。 该方法包括将含有焦炭沉积物的颗粒与衍生自生物质的氧化分子接触。 在优选的实施方案中，颗粒是催化剂颗粒。 该方法可以在常规流化催化剂裂化（FCC）单元的再生器中进行。
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公开(公告)号：US08129575B2
公开(公告)日：2012-03-06
申请号：US12377388
申请日：2007-08-15
IPC分类号： C07C1/00
摘要： A process is disclosed for fluid catalytic cracking of oxygenated hydrocarbon compounds such as glycerol and bio-oil.In the process the oxygenated hydrocarbon compounds are contacted with a fluid cracking catalyst material for a period of less than 3 seconds.In a preferred process a crude-oil derived material, such as VGO, is also contacted with the catalyst.
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75.发明申请公开(公告)号：US20120022307A1
公开(公告)日：2012-01-26
申请号：US12867214
申请日：2009-06-29
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译： 制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。 生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。 搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。 共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。 生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。
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公开(公告)号：US20110256615A1
公开(公告)日：2011-10-20
申请号：US13057968
申请日：2009-12-22
申请人： Michael Brady , Dennis Stamires , Paul O'Connor
发明人： Michael Brady , Dennis Stamires , Paul O'Connor
CPC分类号： D21C1/02 , C12P2201/00 , D21C3/00 , D21C11/0007 , Y02E50/16
摘要： A process is disclosed for preparing biomass particles for thermolytic or enzymatic conversion whereby the biomass particles baying a moisture content of at least 20% are subjected to flash heating. The flash heating may be preceded by one or more adsorption/desorption cycles with water or steam. A swelling aid may be added during the adsorption part of an adsorption/desorption cycle.
摘要翻译： 公开了一种用于制备用于热分解或酶促转化的生物质颗粒的方法，其中使水分含量至少为20％的生物质颗粒经受闪蒸加热。 闪蒸加热之前可以用水或蒸汽进行一次或多次吸附/解吸循环。 在吸附/解吸循环的吸附部分可以加入溶胀助剂。
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公开(公告)号：US20110114765A1
公开(公告)日：2011-05-19
申请号：US12934006
申请日：2009-11-30
申请人： Michael Brady , Robert Bartek , Dennis Stamires , Paul O'Connor
发明人： Michael Brady , Robert Bartek , Dennis Stamires , Paul O'Connor
摘要： A method is disclosed for reducing the mechanical strength of solid biomass material, in particular ligno-cellulosic biomass. The method comprises heating the solid biomass material to a temperature in the range of 105° C. to 200° C. The heat treatment, which is referred to as “toasting”, significantly reduces the mechanical energy required for reducing the particle size of the solid biomass material.The method is particularly suitable as a pretreatment step to a conversion reaction of the solid biomass material.
摘要翻译： 公开了一种降低固体生物质材料，特别是木质纤维素生物质的机械强度的方法。 该方法包括将固体生物质材料加热至105℃至200℃的温度。被称为“烘烤”的热处理显着降低了降低颗粒尺寸所需的机械能 固体生物质材料。 该方法特别适用于固体生物质材料的转化反应的预处理步骤。
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公开(公告)号：US20100293839A1
公开(公告)日：2010-11-25
申请号：US12746140
申请日：2008-12-02
申请人： Paul O'Connor
发明人： Paul O'Connor
IPC分类号： C10L1/00
摘要： A reactive distillation process is disclosed for converting aquatic biomass to a bio-oil. In the process a slurry of aquatic biomass is contacted with a particulate inorganic material. The mixture is heated to or above its boiling point. During the heating step biomass is converted to bio-oil. In a preferred embodiment water vapors emanating from the slurry are collected and condensed. The fresh water obtained may be used for irrigation, in human domestic uses, and for human consumption.
摘要翻译： 公开了将水生生物质转化为生物油的反应蒸馏方法。 在该过程中，水生生物质的浆液与颗粒状无机材料接触。 将混合物加热至或高于其沸点。 在加热阶段，生物质被转化为生物油。 在优选的实施方案中，从浆液中发出的水蒸汽被收集并冷凝。 所获得的淡水可用于灌溉，在家庭用途和人类消费。
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公开(公告)号：US20100113849A1
公开(公告)日：2010-05-06
申请号：US12612378
申请日：2009-11-04
申请人： Robert Bartek , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Steve Yanik , Paul O'Connor
CPC分类号： C10L1/04 , C10G1/08 , C10G1/083 , C10G2300/1011 , C10G2300/4006 , C10G2300/708 , Y02E50/14 , Y02P30/20
摘要： A process is disclosed including: contacting solid biomass with a first catalyst stream in a first reaction zone operated at a temperature T1 (from about 250 to about 400° C.), for conversion of a portion of the solid biomass and forming a first gaseous product stream; downwardly passing unconverted biomass to a second reaction zone for contact with a second catalyst stream charged to the second reaction zone operated at a temperature T2, for conversion to form a second gaseous product stream and a spent catalyst; burning coke off the spent catalyst in a regenerator to form a regenerated catalyst; charging a portion of the regenerated catalyst to each of the first and second reaction zones, as the first and second catalyst streams, respectively; upwardly passing the second gaseous product stream to the first reaction zone; and removing both first and second gaseous product streams from the first reaction zone.
摘要翻译： 公开了一种方法，包括：使第一催化剂流与第一反应区在温度T1（约250至约400℃）下操作，以使一部分固体生物质转化并形成第一气态 产品流; 向下通过未转化的生物质到第二反应区，以与加入在温度T2下操作的第二反应区的第二催化剂流接触，以转化以形成第二气态产物流和废催化剂; 在再生器中燃烧焦炭废催化剂以形成再生催化剂; 将一部分再生催化剂分别装入第一和第二反应区中的第一和第二反应区，作为第一和第二催化剂流; 向上通过第二气态产物流到第一反应区; 以及从所述第一反应区域除去第一和第二气态产物流。
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公开(公告)号：US20090314627A1
公开(公告)日：2009-12-24
申请号：US12373745
申请日：2007-07-13
申请人： Paul O'Connor , Dennis Stamires
发明人： Paul O'Connor , Dennis Stamires
IPC分类号： B01J19/12
摘要： A process is disclosed for making a biomass susceptible to depolymerization or liquefaction under mild conditions. The process comprises introducing into the biomass a material susceptible to the absorption of electro-magnetic radiation to form a radiation absorbent biomass. The radiation absorbent biomass is subjected to electro-magnetic radiation to form an activated biomass.
摘要翻译： 公开了一种用于使生物质在温和条件下易于解聚或液化的方法。 该方法包括将易受吸收电磁辐射影响的材料引入生物质以形成辐射吸收生物质。 对辐射吸收生物质进行电磁辐射以形成活化的生物质。
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