公开(公告)号：US4994363A

公开(公告)日：1991-02-19

申请号：US286562

申请日：1988-12-19

申请人： Keizo Koya ,  Koki Nakamura ,  Hiroyuki Watanabe ,  Yasuhiro Yoshioka

发明人： Keizo Koya ,  Koki Nakamura ,  Hiroyuki Watanabe ,  Yasuhiro Yoshioka

IPC分类号： G03C7/26 ,  G03C7/305

CPC分类号： G03C7/30576 ,  Y10S430/156 ,  Y10S430/157 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/16

摘要： A novel silver halide light-sensitive material is provided, comprising a compound represented by the general formula (I): ##STR1## wherein EAG represents an aromatic group which receives electrons from a reducing substance; R.sup.1 represents hydrogen atom or a substituent; R.sup.2 represents an electrophilic group, with the proviso that R.sup.1 and R.sup.2 may be in the position of cis or trans to each other; R.sup.3 and R.sup.4 each represents hydrogen atom or a hydrocarbon group; ETG represents a group capable of transferring electrons; e represents an integer 0 or 1; Time represents a group which undergoes reaction triggered by the cleavage from the carbon carrying R.sup.3 and R.sup.4 to release PUG; t represents an integer 0 or 1; and PUG represents a photographically useful group.In a preferred embodiment, R.sup.1 represents an aromatic group, heterocyclic group or group represented by --Y.sup.1 --R.sup.5 in which Y.sup.1 represents a hetero atom or hetero atomic group and R.sup.5 represents hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group. R.sup.2 represents an acyl group, carbamoyl group, alkoxycarbonyl group, cyano group, sulfonyl group or nitro group. R.sup.1 is a group represented by --Y.sup.1 --Y.sup.2 --R.sup.6 in which Y.sup.1 and Y.sup.2 each represents a hetero atom or hetero atomic group and may be the same or different and R.sup.6 represents hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group.

摘要翻译： 提供了一种新型的卤化银感光材料，其包含由通式（I）表示的化合物：其中EAG表示从还原物质接收电子的芳族基团; R1表示氢原子或取代基; R2表示亲电子基团，条件是R 1和R 2可以彼此相邻或相互反应; R3和R4各自表示氢原子或烃基; ETG表示能够转移电子的基团; e表示0或1的整数; 时间表示经由从携带R3和R4的碳裂解引发的反应释放PUG的基团; t表示整数0或1; PUG代表摄影有用的组。 在优选的实施方案中，R 1表示由-Y 1 -R 5表示的芳基，杂环基或基团，其中Y 1表示杂原子或杂原子，R 5表示氢原子，脂族基团，芳族基团或杂环基。 R2表示酰基，氨基甲酰基，烷氧基羰基，氰基，磺酰基或硝基。 R1是由-Y1-Y2-R6表示的基团，其中Y1和Y2各自表示杂原子或杂原子基团，可以相同或不同，R6表示氢原子，脂族基团，芳族基团或杂环基 。

公开(公告)号：US4950764A

公开(公告)日：1990-08-21

申请号：US189072

申请日：1988-05-02

申请人： Koki Nakamura ,  Shigeru Makamura

发明人： Koki Nakamura ,  Shigeru Makamura

IPC分类号： A01N43/824 ,  C07D413/06 ,  C07D413/12 ,  C07D413/14 ,  C07D417/12 ,  C07D487/04 ,  G03C1/06 ,  G03C1/10 ,  G03C7/305

CPC分类号： C07D413/06 ,  C07D413/12 ,  C07D417/12 ,  C07D487/04 ,  G03C7/30511

摘要： 2-Aryl-4-isoxazolin-3-one derivatives having the following general formula (I): ##STR1## wherein R.sup.1 represents an alkyl group or an aryl group, R.sup.2, R.sup.3, and R.sup.4 each represents a hydrogen atom, a trifluoromethyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group, a halogen atom, a cyano group, a nitro group, an alkoxy group, an aryloxy group, an acyl group, a carboxy group, or a sulfo group, with at least one of R.sup.2, R.sup.3, and R.sup.4 being selected from among a nitro group, a cyano group, a sulfamoyl group, a carbamoyl group, and a sulfonyl group, and X represents a monovalent group of one of a mercaptoazole, a mercaptoazaindene, a tetrazaindene, a mercaptopyrimidine a benzotriazole, an indazole, and a benzimiazole, are disclosed.

摘要翻译： 具有以下通式（I）的2-芳基-4-异恶唑啉-3-酮衍生物：其中R 1表示烷基或芳基，R 2，R 3和R 4各自表示氢原子， 三氟甲基，氨基甲酰基，氨磺酰基，烷氧基羰基，芳氧基羰基，磺酰基，卤素原子，氰基，硝基，烷氧基，芳氧基，酰基，羧基 基团或磺基，其中R 2，R 3和R 4中的至少一个选自硝基，氰基，氨磺酰基，氨基甲酰基和磺酰基，X表示一价基团 公开了巯基咔唑，巯基吖庚因酮，四氮茚，巯基嘧啶，苯并三唑，吲唑和苯并噻唑中的一种。

公开(公告)号：US4840887A

公开(公告)日：1989-06-20

申请号：US188779

申请日：1988-04-29

申请人： Koki Nakamura

发明人： Koki Nakamura

IPC分类号： C07D249/18 ,  C07D231/56 ,  C07D233/72 ,  C07D233/84 ,  C07D249/12 ,  C07D257/04 ,  C07D263/56 ,  C07D521/00 ,  G03C1/06 ,  G03C7/26 ,  G03C7/305

CPC分类号： G03C7/30511 ,  C07D231/56 ,  C07D257/04 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/159

摘要： A silver halide photographic material is disclosed, which comprises a support having formed thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains, in the silver halide emulsion layer, other hydrophilic colloid layer(s), or both, a compound represented by formula (I) ##STR1## wherein EAG represents an electron accepting group, --SO.sub.2 -- represents a sulfonylene group; X represents an oxygen atom (--O--), a sulfur atom (--S--) or an atomic group (--N(R.sub.2)--) containing a nitrogen atom; the single bond between --SO.sub.2 and X being cleaved after EAG receives an electron, wherein R.sub.1 and R.sub.2 each represents a simple bond or a group other than a hydrogen atom; said R.sub.1, R.sub.2, EAG may be combined with each other to form a ring; (Time) represents a group capable of releasing a photographically useful group (PUG) upon the cleavage of the SO.sub.2 --X bond; t represents 0 or 1; when said t is 0, (Time) represents a simple bond and X may be a part of PUG; the solid line represents a bond; the dotted lines show that at least one of them is bonded.

摘要翻译： 公开了一种卤化银照相材料，其包括其上形成有至少一个卤化银乳剂层的载体，其中卤化银照相材料在卤化银乳剂层中包含其它亲水胶体层或两者， 由式（I）表示的化合物其中EAG表示电子接受基团，-SO 2 - 表示亚磺酰基; X表示含有氮原子的氧原子（-O-），硫原子（-S-）或原子团（-N（R2） - ） 在EAG接收电子之后，-SO 2和X之间的单键被切割，其中R 1和R 2各自表示简单的键或氢原子以外的基团; 所述R1，R2，EAG可以相互结合形成环; （时间）表示能够在切割SO2-X键时释放照相用组（PUG）的基团; t表示0或1; 当所述t为0时，（时间）表示简单的键，X可以是PUG的一部分; 实线代表债券; 虚线表示其中至少有一个是粘合的。

公开(公告)号：US4788132A

公开(公告)日：1988-11-29

申请号：US884169

申请日：1986-07-10

申请人： Naoyasu Deguchi ,  Tetsuro Kojima ,  Hideo Miyazaki ,  Shigeru Ohno ,  Koki Nakamura

发明人： Naoyasu Deguchi ,  Tetsuro Kojima ,  Hideo Miyazaki ,  Shigeru Ohno ,  Koki Nakamura

IPC分类号： G03C7/26 ,  G03C7/392 ,  G03C5/50

CPC分类号： G03C7/39276

摘要： A silver halide color reversal photographic material is disclosed which comprises a support and at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one red-sensitive silver halide emulsion layer on the support, which material is characterized in that at least one light-sensitive silver halide emulsion layer or at least one layer adjacent thereto contains at least one of the compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## All the symbols used are as defined in the Specification.

摘要翻译： 公开了一种卤化银彩色反转照相材料，其包含载体和至少一种蓝敏感卤化银乳剂层，载体上至少一种感绿卤化银乳剂层和至少一种感红卤化银乳剂层， 该材料的特征在于至少一种感光卤化银乳剂层或与其相邻的至少一层含有由以下通式（I），（II），（III）和（IV）表示的至少一种化合物 通用型（Ⅰ）通用型（II）通用型（II）通用型（III）通用型（III）通用型（IV）使用的所有符号均在规范中定义。

公开(公告)号：US4770990A

公开(公告)日：1988-09-13

申请号：US852044

申请日：1986-04-14

申请人： Koki Nakamura ,  Shigeo Hirano ,  Osamu Takahashi

发明人： Koki Nakamura ,  Shigeo Hirano ,  Osamu Takahashi

IPC分类号： G03C7/26 ,  G03C1/06 ,  G03C7/00 ,  G03C7/305 ,  G03C7/32 ,  G03C8/08 ,  G03C1/02 ,  G03C5/54

CPC分类号： G03C7/305 ,  Y10S430/156 ,  Y10S430/157 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/16 ,  Y10S430/161

摘要： A silver halide photographic material is disclosed. The material comprises a support and at least one silver halide emulsion layer formed thereon, in which said emulsion layer or other layer contains a compound represented by formula (I) ##STR1## wherein X represents an atomic group capable of releasing (Time).sub.t PUG by undergoing an oxidation-reduction reaction with CA.dbd.CR.sub.1 --CR.sub.2).sub.n C.sub.B ; C.sub.A and C.sub.B each represents a carbon atom; n represents an integer of 0, 1, 2, or 3; R.sub.1 and R.sub.2 each a hydrogen atom or a group substitutable for a hydrogen atom; EWG represents an electron withdrawing group having a Hammett's .sigma. para value greater than 0.3; --Time).sub.t PUG represents a group bonded to C.sub.B through an oxygen atom thereof; Time represents a timing group; t represents 0 or 1; and PUG represents a photographically useful group.

摘要翻译： 公开了一种卤化银照相材料。 该材料包括载体和形成在其上的至少一个卤化银乳剂层，其中所述乳剂层或其它层含有由式（I）表示的化合物（I），其中X表示能够释放的原子团（时间 ）tPUG通过与CA = CR1-CR2）nCB进行氧化还原反应; CA和CB各自表示碳原子; n表示0,1,2或3的整数; R1和R2各自为氢原子或可取代氢原子的基团; EWG表示具有大于0.3的哈米特σ值的吸电子基团; 时间）tPUG表示通过其氧原子与CB结合的基团; 时间表示时间组; t表示0或1; PUG代表摄影有用的组。

公开(公告)号：US4740454A

公开(公告)日：1988-04-26

申请号：US886490

申请日：1986-07-17

申请人： Naoyasu Deguchi ,  Tetsuro Kojima ,  Hideo Miyazaki ,  Shigeru Ohno ,  Koki Nakamura

发明人： Naoyasu Deguchi ,  Tetsuro Kojima ,  Hideo Miyazaki ,  Shigeru Ohno ,  Koki Nakamura

IPC分类号： G03C1/06 ,  C07D285/12 ,  C07D285/125 ,  C07D285/135 ,  G03C1/035 ,  G03C1/09 ,  G03C7/392 ,  G03C1/34 ,  G03C1/02

CPC分类号： G03C1/09 ,  G03C7/39276

摘要： A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing tabular silver halide grains which have a diameter not less than 5 times the thickness thereof and account for at least 50% of the total projected area of the silver halide grains present in the silver halide emulsion layer and the silver halide photographic material also contains at least one compound represented by following general formulae (I), (II), (III) and (IV): ##STR1## wherein R represents a straight chain, branched chain or cyclic alkylene group, a straight chain or branched chain alkenylene group, a straight chain or branched chain aralkylene group or an arylene group; R.sub.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aralkyl group or a substituted or unsubstituted aryl group; Z represents a hydrogen atom or a polar substituent; X represents a hydrogen atom, a cation necessary for neutralizing the molecule or a precursor; and n represents 0 or 1.The silver halide photographic material has improved image sharpness not only at high spatial frequencies but also at low spatial frequencies.

摘要翻译： 一种卤化银照相材料，包括其上具有至少一种含有片状卤化银颗粒的感光卤化银乳剂层的载体，所述片状卤化银颗粒的直径不小于其厚度的5倍，并且占总投影面积的至少50％ 存在于卤化银乳剂层和卤化银照相材料中的卤化银颗粒还含有至少一种由以下通式（I），（II），（III）和（IV）表示的化合物： （III）其中R表示直链，支链或环状亚烷基，直链或支链亚烯基，直链或支链亚芳基或 亚芳基; R1表示取代或未取代的烷基，取代或未取代的烯基，取代或未取代的芳烷基或取代或未取代的芳基; Z表示氢原子或极性取代基; X表示氢原子，中和该分子或前体所必需的阳离子; 并且n表示0或1.卤化银照相材料不仅在高空间频率下而且在低空间频率下具有改善的图像清晰度。

公开(公告)号：US4657847A

公开(公告)日：1987-04-14

申请号：US765238

申请日：1985-08-13

申请人： Hideo Ikeda ,  Shigeru Ohno ,  Koki Nakamura ,  Nobuaki Miyasaka

发明人： Hideo Ikeda ,  Shigeru Ohno ,  Koki Nakamura ,  Nobuaki Miyasaka

IPC分类号： G03C1/06 ,  C07D235/28 ,  C07D263/58 ,  C07D277/72 ,  G03C1/005 ,  G03C1/035 ,  G03C1/34

CPC分类号： C07D263/58 ,  C07D235/28 ,  C07D277/72 ,  G03C1/346

摘要： A silver halide photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer and a surface protecting layer, said silver halide photographic light-sensitive material comprising photosensitive silver halide grains and internally fogged silver halide grains, said internally fogged silver halide grains having adsorbed thereon at least one compound represented by the formula (I): ##STR1## wherein X represents --O--, --NH-- or --S--, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen atom or a substituent, and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is substituted or unsubstituted alkyl or aryl group having up to 13 carbon atoms, which is bonded directly or through a divalent linkage group, to the aromatic nucleus.

摘要翻译： 一种卤化银照相感光材料，其包含在其上涂覆有至少一个卤化银乳剂层和表面保护层的载体，所述卤化银照相感光材料包含感光卤化银颗粒和内部雾化的卤化银颗粒，所述内部雾化 在其上吸附有至少一种由式（I）表示的化合物的卤化银颗粒：其中X表示-O - ， - NH-或-S-，R 1，R 2，R 3和R 4表示氢原子或 取代基，R 1，R 2，R 3和R 4中的至少一个为具有至多13个碳原子的取代或未取代的烷基或芳基，其直接或通过二价连接基团键合到芳香核上。

公开(公告)号：US4636456A

公开(公告)日：1987-01-13

申请号：US731249

申请日：1985-05-07

申请人： Toshiro Takahashi ,  Koki Nakamura

发明人： Toshiro Takahashi ,  Koki Nakamura

IPC分类号： C07D231/56 ,  C07D257/04 ,  G03C1/06 ,  G03C5/29 ,  G03C7/305 ,  G03C5/24

CPC分类号： G03C7/30511 ,  C07D231/56 ,  C07D257/04 ,  G03C1/06 ,  Y10S430/15 ,  Y10S430/158 ,  Y10S430/16

摘要： A process for forming photographic image is disclosed, comprising photographically developing, in the presence of a polyalkylene oxide compound, a silver halide photographic light-sensitive material including at least one silver halide emulsion layer and containing in at least said emulsion layer or other hydrophilic layer a compound represented by formula (I). ##STR1## wherein: A and A' each represents a hydrogen atom or an alkalihydrolyzable group;R.sub.1, R.sub.2, and R.sub.3 each represents a group capable of substituting a hydrogen atom on the hydroquinone nucleus, with R.sub.2 and R.sub.3, A and R.sub.1, or A and R.sub.2 together form a ring; andX represents a group which shows a development-inhibiting effect after being released.

摘要翻译： 公开了一种用于形成照相图像的方法，包括在聚环氧烷化合物存在下照相显影包含至少一个卤化银乳剂层的卤化银照相感光材料，并至少包含所述乳剂层或其它亲水层 由式（I）表示的化合物。 （I）其中：A和A'各自表示氢原子或碱可水解的基团; R 1，R 2和R 3各自表示能够用氢取代氢醌原子的基团，其中R2和R3，A和R1，或A和R2一起形成环; X表示在释放后表现出显影抑制作用的基团。

公开(公告)号：US4634660A

公开(公告)日：1987-01-06

申请号：US732819

申请日：1985-05-10

申请人： Hiroyuki Mifune ,  Koki Nakamura ,  Shoji Ishiguro

发明人： Hiroyuki Mifune ,  Koki Nakamura ,  Shoji Ishiguro

IPC分类号： C07D257/04 ,  G03C1/34 ,  G03C5/305 ,  G03C5/30

CPC分类号： C07D257/04 ,  G03C1/34 ,  G03C5/305 ,  Y02P20/55

摘要： In the presence of a novel antifoggant represented by the general formula (I), a silver halide photographic material which has at least one light-sensitive silver halide emulsion layer on a support is development-processed. The developing solution is one containing both dihydroxybenzenes and 3-pyrazolidones, a developing solution containing both dihydroxybenzenes and aminophenoles, or a developing solution containing a primary aromatic amine developer to suppress markedly fog generation at much reduced sacrifice of sensitivity: ##STR1## wherein M represents a hydrogen atom, an alkali metal atom, NH.sub.4 or a mercapto group-protecting moiety which can be split-off in the presence of an alkali; n represents 1, 2 or 3; R.sup.1 represents a hydrogen atom or --COOR.sup.2 ; and R.sup.2 represents a hydrogen atom, an alkali metal atom, NH.sub.4, or an unsubstituted or substituted alkyl, aryl or aralkyl group.

摘要翻译： 在由通式（I）表示的新型防灰雾剂的存在下，在载体上具有至少一个感光卤化银乳剂层的卤化银照相材料进行显影处理。 显影溶液是含有二羟基苯和3-吡唑烷酮的显影液，其是含有二羟基苯和氨基苯酚的显影液，或含有主要芳族胺显影剂的显影液，以在极少的敏感性牺牲下抑制明显的雾产生。 其中M表示氢原子，碱金属原子，NH 4或可在碱存在下分离的巯基保护基; n表示1,2或3; R1表示氢原子或-COOR2; R 2表示氢原子，碱金属原子，NH 4或未取代或取代的烷基，芳基或芳烷基。

公开(公告)号：US4521508A

公开(公告)日：1985-06-04

申请号：US549515

申请日：1983-11-07

申请人： Tadao Sugimoto ,  Hideo Ikeda ,  Hiroyuki Mifune ,  Koki Nakamura

发明人： Tadao Sugimoto ,  Hideo Ikeda ,  Hiroyuki Mifune ,  Koki Nakamura

IPC分类号： G03C1/06 ,  G03C1/005 ,  G03C1/09 ,  G03C1/28

CPC分类号： G03C1/09 ,  Y10S430/141 ,  Y10S430/15

摘要： A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a protective layer. The material contains a photosensitive silver halide emulsion and inside fogged silver halide emulsion as well as a disulfide compound. The disulfide compound is a compound represented by the general formula (I):A--S--S--B (I)wherein A and B independently represent an alkyl group, an aralkyl group, an aryl group, a heterocyclic group or ##STR1## wherein R represents an alkyl group, an aryl group, an aralkyl group, a heterocyclic group or an amino group. The material can form images having high contrast and a high maximum density. Further, the material has high sensitivity to light and can be developed at a low temperature in a reduced amount of time.

摘要翻译： 公开了一种卤化银照相感光材料。 该材料由其上具有卤化银乳剂层和保护层的支撑基底组成。 该材料含有光敏卤化银乳剂和雾化的卤化银乳剂以及二硫化物。 二硫化物是由通式（I）表示的化合物：ASSB（I）其中A和B独立地表示烷基，芳烷基，芳基，杂环基或其中R表示烷基 芳基，芳烷基，杂环基或氨基。 该材料可以形成具有高对比度和高最大密度的图像。 此外，该材料对光具有高灵敏度，并且可以在较短的时间内在低温下显影。