公开(公告)号：US4657847A

公开(公告)日：1987-04-14

申请号：US765238

申请日：1985-08-13

申请人： Hideo Ikeda ,  Shigeru Ohno ,  Koki Nakamura ,  Nobuaki Miyasaka

发明人： Hideo Ikeda ,  Shigeru Ohno ,  Koki Nakamura ,  Nobuaki Miyasaka

IPC分类号： G03C1/06 ,  C07D235/28 ,  C07D263/58 ,  C07D277/72 ,  G03C1/005 ,  G03C1/035 ,  G03C1/34

CPC分类号： C07D263/58 ,  C07D235/28 ,  C07D277/72 ,  G03C1/346

摘要： A silver halide photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer and a surface protecting layer, said silver halide photographic light-sensitive material comprising photosensitive silver halide grains and internally fogged silver halide grains, said internally fogged silver halide grains having adsorbed thereon at least one compound represented by the formula (I): ##STR1## wherein X represents --O--, --NH-- or --S--, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen atom or a substituent, and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is substituted or unsubstituted alkyl or aryl group having up to 13 carbon atoms, which is bonded directly or through a divalent linkage group, to the aromatic nucleus.

摘要翻译： 一种卤化银照相感光材料，其包含在其上涂覆有至少一个卤化银乳剂层和表面保护层的载体，所述卤化银照相感光材料包含感光卤化银颗粒和内部雾化的卤化银颗粒，所述内部雾化 在其上吸附有至少一种由式（I）表示的化合物的卤化银颗粒：其中X表示-O - ， - NH-或-S-，R 1，R 2，R 3和R 4表示氢原子或 取代基，R 1，R 2，R 3和R 4中的至少一个为具有至多13个碳原子的取代或未取代的烷基或芳基，其直接或通过二价连接基团键合到芳香核上。

公开(公告)号：US5240826A

公开(公告)日：1993-08-31

申请号：US788344

申请日：1991-11-06

申请人： Nobuaki Miyasaka ,  Hideo Ikeda ,  Shigeru Ohno

发明人： Nobuaki Miyasaka ,  Hideo Ikeda ,  Shigeru Ohno

IPC分类号： G03C1/09

CPC分类号： G03C1/09

摘要： A novel silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer coated on at least one side of a support, wherein said photographic emulsion layer comprises a light-sensitive silver halide emulsion and said photographic emulsion or other layer(s) comprises a substantially light-insensitive, unfogged silver halide fine grain emulsion, with a heterocyclic mercapto compound represented by the following general formula (I) being adsorbed on the fine grains in said emulsion: general formula (I) ##STR1## wherein X represents --O--, --NH--, or --S--; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are a hydrogen atom or a substituent group; at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a substituted or unsubstituted alkyl or aryl group having up to 13 carbon atoms, such alkyl or aryl being bonded directly or through a divalent linkage group to the aromatic nucleus; X.sub.1 represents a hydrogen atom or a cation, such cation being required to neutralize the molecule.The silver halide photographic light-sensitive material is a high-speed material which exhibits improved granularity, gradation and rate of development.

摘要翻译： 一种新型卤化银照相感光材料，其具有涂覆在载体的至少一侧上的至少一个卤化银照相乳剂层，其中所述照相乳剂层包含感光卤化银乳剂和所述照相乳剂或其它层 ）包含基本上不光泽的未雾化的卤化银细粒乳液，其中由以下通式（I）表示的杂环巯基化合物被所述乳液中的细晶粒吸附：通式（I）其中X表示 -O - ， - NH-或-S-; R1，R2，R3和R4是氢原子或取代基; R 1，R 2，R 3和R 4中的至少一个是具有至多13个碳原子的取代或未取代的烷基或芳基，所述烷基或芳基直接键合或通过二价连接基团键合至芳香核; X1表示氢原子或阳离子，这种阳离子是中和分子所必需的。 卤化银摄影感光材料是高速材料，其表现出改善的粒度，分级和发展速度。

公开(公告)号：US4818675A

公开(公告)日：1989-04-04

申请号：US872895

申请日：1986-06-11

申请人： Nobuaki Miyasaka ,  Hideo Ikeda ,  Minoru Sakai ,  Shigeru Ohno ,  Yasuo Mukunoki

发明人： Nobuaki Miyasaka ,  Hideo Ikeda ,  Minoru Sakai ,  Shigeru Ohno ,  Yasuo Mukunoki

IPC分类号： G03C1/08 ,  G03C1/005 ,  G03C1/825 ,  G03C1/02 ,  G03C7/26

CPC分类号： G03C1/825

摘要： This invention provides a silver halide photographic light sensitive material having an improved blackness of image silver, as well as high sensitivity and covering power. The present silver halide photographic light sensitive material includes at least one layer of a silver halide photographic emulsion on at least one side of a support, characterized in that said layer of silver halide photographic emulsion contains fine silver halide grains, or tabular silver halide grains having a grain thickness of 0.4.mu. or less, and a dye having a maximum absorption wave length of 520 to 580 nm is contained in said layer of silver halide photographic emulsion and/or another layer such that the transmission density of green light is 0.03 or less after the developing treatment of the photographic light sensitive material.

摘要翻译： 本发明提供了具有改善的图像银黑度以及高灵敏度和覆盖功率的卤化银照相感光材料。 本发明的卤化银照相感光材料在载体的至少一侧包括至少一层卤化银照相乳剂，其特征在于，所述卤化银照相乳剂层含有细卤化银颗粒或具有 粒度为0.4μm以下，并且在所述卤化银照相乳剂层和/或另一层中含有最大吸收波长为520〜580nm的染料，使得绿光的透过密度为0.03以下 在照相感光材料的显影处理之后。

公开(公告)号：US4853323A

公开(公告)日：1989-08-01

申请号：US919136

申请日：1986-10-15

申请人： Hideo Ikeda ,  Shuzo Suga ,  Nobuaki Miyasaka

发明人： Hideo Ikeda ,  Shuzo Suga ,  Nobuaki Miyasaka

IPC分类号： G03C1/08 ,  G03C1/035 ,  G03C1/06 ,  G03C1/10

CPC分类号： G03C1/10

摘要： The present invention relates to a silver halide emulsion containing a thiocyanate and having a high sensitivity in particular to light of a low illuminance. According to the present invention, a silver halide emulsion is provided, wherein the IR absorbance at 2052 cm.sup.-1 due to thiocyanate ion contained in the silver halide grain of the emulsion is observed and a tricarboxylic acid or its salt is contained in the emulsion.

摘要翻译： 本发明涉及含有硫氰酸盐并具有高灵敏度，特别是低照度光的卤化银乳剂。 根据本发明，提供了一种卤化银乳剂，其中观察到乳液中卤化银颗粒中含有的硫氰酸根离子在2052cm -1处的IR吸光度，乳液中含有三羧酸或其盐。

公开(公告)号：US4770991A

公开(公告)日：1988-09-13

申请号：US904277

申请日：1986-09-08

申请人： Tetsuro Kojima ,  Shigeru Ohno ,  Morio Yagihara ,  Hideo Ikeda

发明人： Tetsuro Kojima ,  Shigeru Ohno ,  Morio Yagihara ,  Hideo Ikeda

IPC分类号： G03C1/09 ,  G03C1/34 ,  G03C1/10

CPC分类号： G03C1/346 ,  G03C1/09

摘要： A novel silver halide photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, said silver halide photographic light-sensitive material comprising photosensitive silver halide grains and internally fogged silver halide grains, said internally fogged silver halide grains having contained therein at least one compound such as ##STR1## The silver halide photographic light-sensitive material is a high-speed one which gives an image having high contrast and high maximum density.

摘要翻译： 一种新型卤化银照相感光材料，其包含在其上涂覆有至少一个卤化银乳剂层的载体，所述卤化银照相感光材料包含感光卤化银颗粒和内部雾化的卤化银颗粒，所述内部雾化卤化银颗粒具有 其中含有至少一种化合物，例如 + TR 卤化银照相感光材料是高速的，其给出具有高对比度和高最大密度的图像。

公开(公告)号：US4604339A

公开(公告)日：1986-08-05

申请号：US556667

申请日：1983-11-30

申请人： Tadao Sugimoto ,  Hideo Ikeda ,  Hiroyuki Mifune ,  Koki Nakamura

发明人： Tadao Sugimoto ,  Hideo Ikeda ,  Hiroyuki Mifune ,  Koki Nakamura

IPC分类号： G03C5/29 ,  C07D473/38 ,  C07D487/04 ,  G03C1/34 ,  G03C5/30 ,  G03C5/54 ,  G03C5/24

CPC分类号： C07D487/04 ,  C07D473/38 ,  G03C1/346 ,  G03C5/30

摘要： A method of developing silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally-fogged silver halide emulsion, in which the internally-fogged emulsion has internal fogging nuclei at a depth of 0.02.mu. or more below the surface of the grains is disclosed. The photographic material is developed in the presence of at least one compound selected from the group consisting of tetraazaindenes containing at least one mercapto group, purines containing at least one mercapto group, triazaindenes containing at least one mercapto group and pentaazaindenes containing at least one mercapto group, to increase photographic speed, contrast and maximum density as well as remove uneven stain.

摘要翻译： 一种显影卤化银照相材料的方法，其含有感光卤化银乳剂和内部雾化的卤化银乳剂，其中内部雾化的乳液在内表面上的0.02μm或更多的深度处具有内部雾化核 披露了谷物。 照相材料在至少一种选自含有至少一个巯基的四氮杂茚基，含有至少一个巯基的嘌呤，含有至少一个巯基的三嗪类和含有至少一个巯基的五唑烷酮的化合物存在下显影 ，以提高摄影速度，对比度和最大密度，以及去除不均匀的污渍。

公开(公告)号：US4551419A

公开(公告)日：1985-11-05

申请号：US579048

申请日：1984-02-10

申请人： Tadao Sugimoto ,  Hideo Ikeda ,  Koki Nakamura

发明人： Tadao Sugimoto ,  Hideo Ikeda ,  Koki Nakamura

IPC分类号： G03C5/26 ,  C07C323/25 ,  C07D277/36 ,  C07D487/04 ,  G03C1/005 ,  G03C1/09 ,  G03C1/34

CPC分类号： C07D487/04 ,  C07C323/25 ,  C07D277/36 ,  G03C1/005 ,  G03C1/09 ,  G03C1/346

摘要： A silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally fogged silver halide emulsion is development-processed in the presence of at least one compound selected from the group consisting of compounds represented by the general formulae (I) and (II) and at least one azaindene having a mercapto group to exhibit high photographic speed, high contrast and high maximum image density:R.sub.1 --(R.sub.3).sub.l X}.sub.n R.sub.3 '--R.sub.2 (I)wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an aryl group, an aryl group, or a heterocyclic group; R.sub.3 and R.sub.3 ' each represents an alkylene group, an arylene group, a heterocyclic group; X presents ##STR1## R.sub.4 represents a hydrogen atom or --R.sub.5 --Y}.sub.m R.sub.5 '--R.sub.6 ; R.sub.5 and R.sub.5 ' have the same meanings as R.sub.3 and R.sub.3 '; R.sub.6 has the same meaning as R.sub.1 and R.sub.2 ; Y represents ##STR2## R.sub.7 has the same meaning as R.sub.1 and R.sub.2 ; l represents 0 or 1, n represents an integer of 1 to 110, and m represents an integer of 0 to 10, and at least one X therein must be a sulfur atom: ##STR3## wherein Q represents atoms necessary to form a heterocyclic ring, and A represents an alkyl group, or an aryl group.

摘要翻译： 含有感光卤化银乳剂和内部雾化卤化银乳剂的卤化银照相材料在至少一种选自由通式（I）和（I）表示的化合物组成的组的存在下进行显影处理， II）和具有巯基的至少一种具有巯基的亚烷基，以显示高照相速度，高对比度和高最大图像密度：R1-（R3）1X} nR3'-R2（I）其中R1和R2各自表示氢原子， 芳基，芳基或杂环基; R 3和R 3'各自表示亚烷基，亚芳基，杂环基; X表示 + TR C（R4）2; R4表示氢原子或-R5-Y} mR5'-R6; R5和R5'与R3和R3'具有相同的含义; R6与R1和R2具有相同的含义; Y表示 + TR R7与R1和R2具有相同的含义; l表示0或1，n表示1至110的整数，m表示0至10的整数，并且其中至少一个X必须为硫原子：其中Q表示形成所需的原子 杂环，A表示烷基或芳基。

公开(公告)号：US4956269A

公开(公告)日：1990-09-11

申请号：US441592

申请日：1989-11-27

申请人： Hideo Ikeda ,  Shigeru Ohno

发明人： Hideo Ikeda ,  Shigeru Ohno

IPC分类号： G03C7/20 ,  G03C1/035 ,  G03C7/30 ,  G03C7/32

CPC分类号： G03C7/30

摘要： A silver halide color photographic material comprising a support having thereon at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, wherein each of the green-sensitive silver halide emulsion layer, the red-sensitive silver halide emulsion layer and the blue-sensitive silver emulsion layer contains at least one color image forming coupler, and wherein 50% or more of the total projected area of the silver halide grains in at least one of the emulsion layers comprises tabular silver halide grains having a thickness of less than 0.5 .mu.m, a diameter of 0.6 .mu.m or more and an average aspect ratio of 3 or more and the red-sensitive emulsion layer and/or the green-sensitive emulsion layer contains a dye in an amount sufficient to reduce the sensitivity thereof by 20% or more based on the sensitivity of the red-sensitive emulsion layer and/or the green-sensitive emulsion layer containing no dye, the dry film thickness from the photosensitive emulsion layer that is farthest from the support to the photosensitive emulsion layer that is nearest the support is 16.0 .mu.m or less and the swelling ratio of the silver halide color photographic material excluding the support is 1.25 or more.

摘要翻译： 一种卤化银彩色照相材料，包括其上具有至少一种感红卤化银乳剂层，至少一种感绿卤化银乳剂层和至少一种蓝敏感卤化银乳剂层的载体，其中， 感光卤化银乳剂层，感红卤化银乳剂层和蓝敏感银乳剂层包含至少一种彩色图像形成成色剂，并且其中至少在卤化银颗粒的总投影面积中的50％或更多 乳剂层之一包括厚度小于0.5μm，直径为0.6μm或更大，平均纵横比为3或更大的片状卤化银颗粒和红色感光乳剂层和/或绿色乳剂层， 敏感乳剂层含有足以使其灵敏度降低20％以上的量的染料，其基于感红乳剂层和/或感绿乳剂的灵敏度 n层，不含染料的离层最靠近感光乳剂层的感光性乳剂层的干膜厚度为16.0μm以下，卤化银色彩照相材料的溶胀比除了 支持为1.25以上。

公开(公告)号：US4551421A

公开(公告)日：1985-11-05

申请号：US579321

申请日：1984-02-13

申请人： Tadao Sugimoto ,  Hideo Ikeda ,  Koki Nakamura

发明人： Tadao Sugimoto ,  Hideo Ikeda ,  Koki Nakamura

IPC分类号： G03C1/005 ,  C07C67/00 ,  C07C313/00 ,  C07C323/12 ,  C07C323/20 ,  C07C323/24 ,  C07C323/44 ,  C07C323/52 ,  C07C323/60 ,  C07C323/67 ,  G03C1/035 ,  G03C1/043 ,  G03C1/06 ,  G03C1/28

CPC分类号： G03C1/043 ,  G03C1/06

摘要： A silver halide photographic material is disclosed. The material is comprised of a support base having positioned thereon a silver halide emulsion layer and a surface protective layer. The emulsion layer contains a photosensitive silver halide emulsion, an internally fogged silver halide emulsion and a compound represented by the general formula (I):R.sub.1 [(R.sub.3).sub.l X].sub.n R.sub.3 '--R.sub.2wherein the substituents within the general formula (I) are defined within the specification. The photographic material is capable of providing an image having a high maximum density at a high speed and a high contrast. The material can be processed without requiring any specific additives in a short developing period using low-temperature processing. The material also possesses high-temperature quick processing aptitude.

摘要翻译： 公开了一种卤化银照相材料。 该材料包括其上定位有卤化银乳剂层和表面保护层的支撑基底。 乳剂层含有感光卤化银乳剂，内部雾化的卤化银乳剂和由通式（I）表示的化合物：R1 [（R3）1X] nR3'-R2，其中通式（I）中的取代基为 在规范中定义。 照相材料能够以高速度和高对比度提供具有高最大密度的图像。 该材料可以在短时间内使用低温处理而不需要任何特定的添加剂。 该材料还具有高温快速加工能力。

公开(公告)号：US4675276A

公开(公告)日：1987-06-23

申请号：US906710

申请日：1986-09-12

申请人： Koki Nakamura ,  Tetsuro Kojima ,  Takashi Toyoda ,  Hideo Ikeda

发明人： Koki Nakamura ,  Tetsuro Kojima ,  Takashi Toyoda ,  Hideo Ikeda

IPC分类号： C07D249/12 ,  C07D401/04 ,  C07D487/04 ,  G03C1/34 ,  G03C1/42 ,  G03C5/26

CPC分类号： C07D401/04 ,  C07D249/12 ,  C07D487/04 ,  G03C1/34 ,  G03C1/346

摘要： A silver halide photographic material containing a mesoionic 1,2,4-triazolium-3-thiolate compound in at least one hydrophilic colloidal layer of the silver halide photographic material gives photographic images having stable and excellent quality without being accompanied by the increased formation of fog and increased changes of sensitivity and gradation upon high temperature processing.

摘要翻译： 在卤化银照相材料的至少一个亲水性胶体层中含有介观异构的1,2,4-三唑鎓-3-硫醇盐化合物的卤化银照相材料使摄影图像具有稳定和优异的质量，而不伴随增加的雾化形成 并且在高温处理时增加灵敏度和灰度的变化。