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1.发明授权Method for forming silver halide emulsion comprising forming silver halide grains in the presence of mesoionic 1,2,4-triazolium-3-thiolate compound 失效用于形成卤化银乳剂的方法，包括在介孔中的1,2,4-三唑鎓-3-硫醇化合物存在下形成卤化银颗粒
公开(公告)号：US4631253A
公开(公告)日：1986-12-23
申请号：US697825
申请日：1985-02-04
申请人： Hiroyuki Mifune , Koki Nakamura , Shoji Ishiguro
发明人： Hiroyuki Mifune , Koki Nakamura , Shoji Ishiguro
IPC分类号： C07D249/12 , C07D405/04 , C07D487/04 , G03C1/005 , G03C1/015 , G03C1/07 , G03C1/02 , G03C1/06
CPC分类号： G03C1/07
摘要： A photographic material is described, comprising a support and at least one silver halide emulsion layer which contains nearly uniform and large size silver halide grains formed in the presence of a novel silver halide solvent represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represents an unsubstituted or substituted alkyl group, alkenyl group, cycloalkyl group, aralkyl group, aryl group, or heterocyclic group; R.sup.3 represents an unsubstituted or substituted alkyl group, alkenyl group, cycloalkyl group, aralkyl group, aryl group, --NR.sup.4 R.sup.5, a heterocyclic group; and R.sup.4 and R.sup.5 each represents a hydrogen atom, an alkyl group or an aryl group; and wherein R.sup.1 and R.sup.2 or R.sup.2 and R.sup.3 can combine with each other to form a 5- or 6-membered ring.
摘要翻译： 描述了一种照相材料，其包括载体和至少一种卤化银乳剂层，其含有在由式（I）表示的新型卤化银溶剂存在下形成的几乎均匀且大尺寸的卤化银颗粒，其中 R1和R2各自表示未取代或取代的烷基，烯基，环烷基，芳烷基，芳基或杂环基; R3表示未取代或取代的烷基，烯基，环烷基，芳烷基，芳基，-NR4R5，杂环基; R 4和R 5各自表示氢原子，烷基或芳基; 并且其中R 1和R 2或R 2和R 3可以彼此结合形成5-或6-元环。
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2.发明授权
公开(公告)号：US4634660A
公开(公告)日：1987-01-06
申请号：US732819
申请日：1985-05-10
申请人： Hiroyuki Mifune , Koki Nakamura , Shoji Ishiguro
发明人： Hiroyuki Mifune , Koki Nakamura , Shoji Ishiguro
IPC分类号： C07D257/04 , G03C1/34 , G03C5/305 , G03C5/30
CPC分类号： C07D257/04 , G03C1/34 , G03C5/305 , Y02P20/55
摘要： In the presence of a novel antifoggant represented by the general formula (I), a silver halide photographic material which has at least one light-sensitive silver halide emulsion layer on a support is development-processed. The developing solution is one containing both dihydroxybenzenes and 3-pyrazolidones, a developing solution containing both dihydroxybenzenes and aminophenoles, or a developing solution containing a primary aromatic amine developer to suppress markedly fog generation at much reduced sacrifice of sensitivity: ##STR1## wherein M represents a hydrogen atom, an alkali metal atom, NH.sub.4 or a mercapto group-protecting moiety which can be split-off in the presence of an alkali; n represents 1, 2 or 3; R.sup.1 represents a hydrogen atom or --COOR.sup.2 ; and R.sup.2 represents a hydrogen atom, an alkali metal atom, NH.sub.4, or an unsubstituted or substituted alkyl, aryl or aralkyl group.
摘要翻译： 在由通式（I）表示的新型防灰雾剂的存在下，在载体上具有至少一个感光卤化银乳剂层的卤化银照相材料进行显影处理。 显影溶液是含有二羟基苯和3-吡唑烷酮的显影液，其是含有二羟基苯和氨基苯酚的显影液，或含有主要芳族胺显影剂的显影液，以在极少的敏感性牺牲下抑制明显的雾产生。 其中M表示氢原子，碱金属原子，NH 4或可在碱存在下分离的巯基保护基; n表示1,2或3; R1表示氢原子或-COOR2; R 2表示氢原子，碱金属原子，NH 4或未取代或取代的烷基，芳基或芳烷基。
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公开(公告)号：US4418140A
公开(公告)日：1983-11-29
申请号：US366515
申请日：1982-04-08
IPC分类号： G03C7/26 , C07D257/04 , G03C7/30 , G03C7/392 , G03C7/00
CPC分类号： C07D257/04 , G03C7/3926 , Y02P20/55
摘要： A process for the development of color photographic light-sensitive material is described. The process comprises color developing an exposed light-sensitive material in the presence of a compound of the general formula: ##STR1## wherein M is a hydrogen atom, an alkali metal atom, NH.sub.4 or a protective group for the mercapto group which undergoes cleavage by the action of an alkali; R is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms; and R' is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms. This process prevents the formation of color development fog without seriously reducing sensitivity.
摘要翻译： 描述了彩色照相感光材料的开发方法。 该方法包括在下列通式的化合物存在下显色曝光的感光材料：其中M是氢原子，碱金属原子，NH 4或巯基的保护基，其通过 碱的作用; R是氢原子或含有1至3个碳原子的烷基; 并且R'是氢原子或含有1至3个碳原子的烷基。 该过程防止形成颜色发展，而不会严重降低灵敏度。
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公开(公告)号：US5587279A
公开(公告)日：1996-12-24
申请号：US791402
申请日：1991-11-14
CPC分类号： G03C7/3022 , G03C1/035 , G03C1/04 , G03C1/28
摘要： A silver halide photographic emulsion which comprises silver halide grains having a silver chloride content of at least 60 mol % and an octatetracontahedral crystal form of the kind which is constructed of 48 triangular faces, every one of which contacts convexly with each of its two adjoining faces to form a line and concavely with its one adjoining face to form a line, with the grains being formed in the presence of a synthetic polymer peptizer which contains, as repeating units, units derived from a thioether linkage-containing ethylenically unsaturated monomer, in a mole fraction of from about 20 to 100 mole %, thereby achieving low fog and high sensitivity.
摘要翻译： 一种卤化银照相乳剂，其包含氯化银含量为至少60摩尔％的卤化银颗粒和由48个三角形面构成的八面体结晶形式，每个三角形面都与其两个邻接面中的每一个凸起接触 以形成一条线并且与其一个相邻的表面凹入以形成一条线，其中在合成聚合物胶溶剂的存在下形成晶粒，该合成聚合物胶溶剂包含作为重复单元的衍生自含硫醚键的烯属不饱和单体的单元， 摩尔分数为约20至100摩尔％，从而实现低雾和高灵敏度。
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公开(公告)号：US4334010A
公开(公告)日：1982-06-08
申请号：US284164
申请日：1981-07-17
IPC分类号： C07C13/20 , C07D333/22 , C07D335/02 , G03C1/34
CPC分类号： G03C1/34 , C07D333/22
摘要： A silver halide photographic light-sensitive element is described comprising a support having thereon at least one silver halide emulsion layer, wherein at least one compound represented by formula (I) is incorporated in the silver halide emulsion layer or in another hydrophilic colloid layer: ##STR1## wherein X represents a hydroxy group or a group represented by ##STR2## wherein R.sup.2 and R.sup.3 (which may be the same or different) each reprsents hydrogen, an alkyl group, or an aryl group; R.sup.1 represents a sulfur-containing saturated heterocyclic group or a group represented by -A-S-B, wherein A represents an alkylene group and B represents hydrogen, an alkyl group, or an aryl group; and Z represents an atomic group forming a 5-membered or 6-membered unsubstituted or substituted carbocyclic ring.In the silver halide photographic light-sensitive element, the so-called "latent image fading" phenomenon is prevented without accompanying degradation of other photograhic properties.
摘要翻译： 描述了一种卤化银照相感光元件，其包括其上具有至少一个卤化银乳剂层的载体，其中至少一种由式（I）表示的化合物引入卤化银乳剂层或另一亲水胶体层中： 图像（I）其中X表示羟基或由其表示的基团，其中R2和R3（可以相同或不同）各自代表氢，烷基或芳基; R1表示含硫的饱和杂环基或由-A-S-B表示的基团，其中A表示亚烷基，B表示氢，烷基或芳基; Z表示形成5元或6元未取代或取代的碳环的原子团。 在卤化银摄影感光元件中，防止所谓的“潜像褪色”现象，而不伴随着其它光致变色性能的降低。
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公开(公告)号：US4738918A
公开(公告)日：1988-04-19
申请号：US907335
申请日：1986-09-15
CPC分类号： G03C5/305 , G03C1/10 , G03C7/3924
摘要： A process for processing silver halide photographic material is disclosed, which comprises development-processing a silver halide photographic material in the presence of a compound represented by formula (I) or a salt thereof with an inorganic or organic acid: ##STR1## wherein Z represents an atomic group of carbon atoms, nitrogen atoms, or a combination thereof forming a 5-, 6-, or 7-membered unsaturated heterocyclic ring, said unsaturated heterocyclic ring being optionally fused with a monocyclic or bicyclic aryl group;R.sup.0 represents ##STR2## R.sup.1 represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group;R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an alkoxy group, a substituted alkoxy group, an amino group, or a substituted amino group;R.sup.4 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group; andR.sup.5 represents an acyl group, a sulfinyl group, a sulfonyl group, or a carbamoyl group, or represents a group selected from the groups represented by R.sup.1, R.sup.2, R.sup.3 and R.sup.4.
摘要翻译： 公开了一种用于处理卤化银照相材料的方法，其包括在由式（I）表示的化合物或其盐与无机或有机酸存在下显影处理卤化银照相材料：（I） 其中Z表示碳原子的原子团，氮原子或其组合形成5-，6-或7-元不饱和杂环，所述不饱和杂环任选地与单环或双环芳基稠合; R 0表示R 1表示烷基，取代的烷基，芳基或取代的芳基; R2和R3各自表示氢原子，烷基，取代的烷基，芳基，取代的芳基，烷氧基，取代的烷氧基，氨基或取代的氨基; R4表示氢原子，烷基，取代的烷基，芳基或取代的芳基; 并且R 5表示酰基，亚磺酰基，磺酰基或氨基甲酰基，或表示选自由R 1，R 2，R 3和R 4表示的基团的基团。
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公开(公告)号：US4581322A
公开(公告)日：1986-04-08
申请号：US681762
申请日：1984-12-14
摘要： A method for developing a silver halide photographic material in the presence of an amino compound represented by the following general formula (I) or the salt thereof to increase photographic speed and/or gamma without being attended by a concomitant increase in generation of fog: ##STR1## wherein R.sup.1 represents an alkyl group, an aryl group, an aralkyl group or a cycloalkyl group; R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group or an alkylcarbonyl group, or R.sup.2 and R.sup.3 may combine with each other and form a ring; and A represents a divalent aliphatic linkage group.
摘要翻译： 在由下列通式（I）表示的氨基化合物或其盐的存在下显影卤化银照相材料的方法，以增加摄影速度和/或γ，而不伴随着雾的产生的伴随增加： （I）其中R1表示烷基，芳基，芳烷基或环烷基; R 2和R 3可以相同或不同，各自表示氢原子，烷基，烯基，芳基，芳烷基或烷基羰基，或者R 2和R 3可以彼此结合形成 环; A表示二价脂肪连接基团。
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公开(公告)号：US4528264A
公开(公告)日：1985-07-09
申请号：US552224
申请日：1983-11-16
IPC分类号： C08F12/00 , C08F12/26 , C08F20/00 , C08F20/34 , C08F20/52 , C08F20/60 , G03C1/053 , G03C1/34
CPC分类号： G03C1/053 , G03C1/34 , G03C1/346 , Y10S430/142 , Y10S430/156
摘要： A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a high molecular compound having a repeating unit containing a residue of benzotriazoles. The repeating unit may be represented by the general formula (I) ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group, L represents a divalent bonding group, and X represents a monovalent group of benzotriazoles. Improved antifogging agent effects are obtained by utilizing the high molecular compound of applicants' invention in connection with silver halide photographic light-sensitive materials.
摘要翻译： 公开了一种卤化银照相感光材料。 该材料由其上具有卤化银乳剂层的支撑基底和具有含有苯并三唑残基的重复单元的高分子化合物组成。 重复单元可以由通式（I）表示，其中R 1表示氢原子或低级烷基，L表示二价键合基团，X表示一价基团的苯并三唑。 通过利用申请人发明的高分子化合物与卤化银照相感光材料相结合，可获得改善的防雾剂效果。
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公开(公告)号：US4334014A
公开(公告)日：1982-06-08
申请号：US244993
申请日：1981-03-18
IPC分类号： G03C1/34
CPC分类号： G03C1/34
摘要： A silver halide photographic light-sensitive element is described containing a cephalosporin compound in its silver halide emulsion layer of substantially the surface latent image type, or in its hydrophilic colloid layer. This light-sensitive element is prevented in the latent image fading.
摘要翻译： 描述了一种卤化银照相感光元件，其在其基本上表面潜影型的卤化银乳剂层中或其亲水胶体层中含有头孢菌素化合物。 这种感光元件在潜像褪色中被防止。
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公开(公告)号：US4395483A
公开(公告)日：1983-07-26
申请号：US352928
申请日：1982-02-26
CPC分类号： G03C1/48523 , Y10S430/137
摘要： A high contrast, chemically fogged direct positive type silver halide photosensitive material is described containing at least one ammine complex salt selected from those including cobalt, nickel, ruthenium or chromium, by which the contrast in the lower optical density region is improved while retaining superior Dmax and sensitivity.
摘要翻译： 描述了高对比度，化学雾化的直接正型卤化银感光材料，其包含至少一种选自钴，镍，钌或铬的氨络合盐，通过该沉淀，可以改善较低光密度区域中的对比度，同时保持优异的Dmax 和灵敏度。
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