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    Hydroesterification of polymerized conjugated dienes
    82.
    发明授权
    Hydroesterification of polymerized conjugated dienes 失效
    聚合共轭二烯的加氢酯化

    公开(公告)号：US4980422A

    公开(公告)日：1990-12-25

    申请号：US569680

    申请日：1990-08-20

    申请人： Carl L. Willis

    发明人： Carl L. Willis

    IPC分类号： C08C19/00 ,  C08C19/10

    CPC分类号： C08C19/00 ,  C08C19/10

    摘要： Polymerized 1,3-butadiene, including styrenic block copolymers, are functionalized with both carboxylic ester groups and ketone linking groups by reaction with carbon monoxide and an alcohol. Such conjugated diene polymers can be reacted in the presence of a catalyst composition that includes a cobalt compound and an amine ligand. The functionalized 1,3-butadiene polymers may be hydrogenated with a nickel/aluminum catalyst which removes olefinically unsaturated carbon-carbon bonds without substantially hydrogenating the ketone linking groups and carboxylic ester groups.

    摘要翻译： 包括苯乙烯嵌段共聚物在内的聚合的1,3-丁二烯通过与一氧化碳和醇反应而被羧酸酯基和酮连接基官能化。 这样的共轭二烯聚合物可以在包括钴化合物和胺配体的催化剂组合物的存在下反应。 官能化的1,3-丁二烯聚合物可以用镍/铝催化剂氢化，镍/铝催化剂除去烯键不饱和碳 - 碳键，而基本上不使酮连接基团和羧酸酯基团氢化。

    Block copolymer grafting process
    83.
    发明授权
    Block copolymer grafting process 失效
    嵌段共聚物接枝过程

    公开(公告)号：US4960831A

    公开(公告)日：1990-10-02

    申请号：US398298

    申请日：1989-08-24

    申请人： Carl L. Willis ,  Michael F. Conway ,  Michael K. Martin

    发明人： Carl L. Willis ,  Michael F. Conway ,  Michael K. Martin

    IPC分类号： C08F8/00

    CPC分类号： C08F8/00

    摘要： Elastomeric polymers comprising at least one alkali metal atom are modified by incorporating at least one group capable of sterically hindering coupling reactions which frequently occur when functional groups are subsequently incorporated into such polymers. In general, the group capable of sterically hindering coupling reactions may be incorporated by reacting the elastomeric polymer comprising at least one alkali metal atom with a compound containing a group capable of reacting with the elastomeric polymer at one end and at least one pendant group larger than hydrogen at the other. Groups that will react with elastomeric polymers comprising at least one alkali-metal atom are of course, well known, in the art, and include groups containing sulfur, oxygen, nitrogen and the like and ethylenically and acetylenically unsaturated groups. Compounds containing terminal ethylenically unsaturated groups are particularly useful in preparing the modified elastomeric polymers of this invention. Terminal groups capable of sterically hindering coupling reactions, generally, include all groups larger than hydrogen. Hydrocarbon groups are, however, particularly useful since these generally do not alter the properties which are characteristic of the elastomeric polymers. Aromatic groups containing at least 6 carbon atoms or cyclic hydrocarbon groups containing at least 5 carbon atoms are particularly effective. 1,1-diphenyl ethylene is particularly preferred in the present invention. Elastomeric polymers which have been modified in accordance with this invention may then be functionalized with less risk of undesirable coupling.

    摘要翻译： 包含至少一个碱金属原子的弹性体聚合物通过引入至少一个能够空间阻碍偶联反应的基团而被修饰，当随后将官能团引入到这些聚合物中时，它们经常发生。 通常，能够空间阻碍偶联反应的基团可以通过使包含至少一个碱金属原子的弹性体聚合物与含有能够在一端与弹性体聚合物反应的基团和至少一个大于 另一方面是氢气。 与本领域技术人员众所周知的将包含至少一个碱金属原子的弹性体聚合物反应的基团包括含有硫，氧，氮等的烯基和炔属不饱和基团。 含有末端烯键式不饱和基团的化合物特别适用于制备本发明的改性弹性体聚合物。 能够空间阻碍偶联反应的末端基团通常包括大于氢的所有基团。 然而，烃基是特别有用的，因为它们通常不改变弹性体聚合物特性的性质。 含有至少6个碳原子的芳族基团或含有至少5个碳原子的环状烃基是特别有效的。 在本发明中特别优选1,1-二苯基乙烯。 然后可以将具有根据本发明改性的弹性体聚合物功能化，具有较少的不期望的偶联的风险。

    Impact resistant blends of thermoplastic polyesters and modified block copolymers
    85.
    发明授权
    Impact resistant blends of thermoplastic polyesters and modified block copolymers 失效
    热塑性聚酯和改性嵌段共聚物的抗冲击共混物

    公开(公告)号：US4954568A

    公开(公告)日：1990-09-04

    申请号：US311009

    申请日：1989-02-15

    申请人： Richard Gelles ,  Carl L. Willis ,  Robert G. Lutz ,  William P. Gergen

    发明人： Richard Gelles ,  Carl L. Willis ,  Robert G. Lutz ,  William P. Gergen

    IPC分类号： C08F8/04 ,  C08L53/02

    CPC分类号： C08F8/04 ,  C08L53/025

    摘要： A toughened multiphase thermoplastic composition is provided by incorporating at least one functionalized, selectively hydrogenated alkenyl arene/conjugated diene block copolymer to which has been grafted an effective amount of carboxyl functional groups primarily in the alkenyl arene blocks thereof with a thermoplastic polyester. The carboxyl functional groups may be in the form of carboxylic acids, their salts, their esters, and combinations of two or more of these.

    摘要翻译： 通过引入至少一种官能化的，选择性氢化的烯基芳烃/共轭二烯嵌段共聚物来提供增韧的多相热塑性组合物，其中主要在热塑性聚酯的烯基芳烃嵌段中接枝有效量的羧基官能团。 羧基官能团可以是羧酸，它们的盐，它们的酯，以及它们中的两种或更多种的组合。

    Method for removing hydrogenation catalyst residues from hydrogenated conjugated diene polymers
    88.
    发明授权
    Method for removing hydrogenation catalyst residues from hydrogenated conjugated diene polymers 失效
    从氢化共轭二烯聚合物中除去氢化催化剂残留物的方法

    公开(公告)号：US4396761A

    公开(公告)日：1983-08-02

    申请号：US294969

    申请日：1981-08-21

    申请人： Carl L. Willis ,  Lynn H. Slaugh

    发明人： Carl L. Willis ,  Lynn H. Slaugh

    IPC分类号： C08C2/04 ,  C08F6/02 ,  C08F6/08

    CPC分类号： C08C2/04 ,  C08F6/02

    摘要： A process is disclosed for removing hydrogenation catalyst residues from hydrogenated conjugated diene polymers by contacting a hydrocarbon solution of said polymers with an aqueous dilute solution of an alpha-hydroxysulfonic acid, separating the aqueous phase from the hydrocarbon phase, removing the hydrocarbon solvent from the hydrocarbon phase, producing a solid polymer, and applying heat and/or vacuum to the solid polymer to remove the residual alpha-hydroxysulfonic acid.

    摘要翻译： 公开了一种通过使所述聚合物的烃溶液与α-羟基磺酸的稀水溶液接触来从氢化共轭二烯聚合物中除去氢化催化剂残余物的方法，从烃相中分离出水相，从烃中除去烃溶剂 产生固体聚合物，并向固体聚合物施加热和/或真空以除去残留的α-羟基磺酸。

    Method for removing catalyst residues from atactic polypropylene
    89.
    发明授权
    Method for removing catalyst residues from atactic polypropylene 失效
    从无规聚丙烯中除去催化剂残留物的方法

    公开(公告)号：US4316008A

    公开(公告)日：1982-02-16

    申请号：US209627

    申请日：1980-11-24

    申请人： Carl L. Willis ,  Lynn H. Slaugh

    发明人： Carl L. Willis ,  Lynn H. Slaugh

    IPC分类号： C08F6/02 ,  C08F6/08

    CPC分类号： C08F6/02

    摘要： Process for removing catalyst residues from atactic polypropylene is disclosed which comprises contacting the polypropylene with an aqueous solution of an alpha-hydroxysulfonic acid and then separating the polypropylene-containing phase from the aqueous phase.

    摘要翻译： 公开了从无规立构聚丙烯除去催化剂残余物的方法，其包括使聚丙烯与α-羟基磺酸的水溶液接触，然后将含聚丙烯的相与水相分离。

    Olefin hydration process
    90.
    发明授权
    Olefin hydration process 失效
    烯烃水合过程

    公开(公告)号：US4306101A

    公开(公告)日：1981-12-15

    申请号：US204677

    申请日：1980-11-05

    申请人： Lynn H. Slaugh ,  Carl L. Willis

    发明人： Lynn H. Slaugh ,  Carl L. Willis

    IPC分类号： C07C29/04 ,  C07C29/05

    CPC分类号： C07C29/04 ,  C07C29/05

    摘要： A process is disclosed for hydrating olefins to alcohols using a very active catalyst comprising an alpha-hydroxysulfonic acid prepared by reacting a carbonyl compound with sulfur dioxide and water.

    摘要翻译： 公开了使用包含通过使羰基化合物与二氧化硫和水反应制备的α-羟基磺酸的非常活泼的催化剂将烯烃水合成醇的方法。