摘要:
A nitrile rubber composition comprising a carboxyl group-containing highly saturated nitrile rubber (A) containing an α,β-ethylenically unsaturated nitrile monomer unit in a content of 5 to 60 wt % and an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit in a content of 1 to 30 wt %, and having an iodine value of 120 or less, and a phenol compound (B) represented by the following general formula (1): (In the general formula (1), R1 to R5 are each independently a hydrogen atom, a heteroatom-free alkyl group having 1 to 8 carbon atoms, or a heteroatom-containing alkyl group having 1 to 15 carbon atoms, and at least one of R1 to R5 is a heteroatom-containing alkyl group having 1 to 15 carbon atoms.)
摘要:
Process for functionalizing a polymer by treating said polymer at a temperature in the range 80-250° C. with a monoazide of the formula wherein m is 0 or 1, n is 0 or 1, n+m=1 or 2, X is a linear or branched, aliphatic or aromatic hydrocarbon moiety with 1-12 carbon atoms, optionally containing heteroatoms, Rb is selected from the group consisting of hydrogen, linear and branched alkyl groups with 1-6 carbon atoms optionally substituted with O, S, P, Si, or N-containing functional groups, alkoxy groups with 1-6 carbon atoms, and halogens, and each Ra is individually selected from hydrogen, linear or branched alkyl groups with 1-6 carbon atoms, or may form a saturated or unsaturated aliphatic or aromatic ring structure with at least one other Ra.
摘要:
The present invention provides a pneumatic tire having well-improved rubber tensile strength and abrasion resistance while maintaining or improving good fuel economy. The present invention relates to a pneumatic tire formed from a rubber composition, the rubber composition containing: a hydrogenated copolymer obtained by copolymerization of an aromatic vinyl compound and a conjugated diene compound, the hydrogenated copolymer having a degree of hydrogenation of the conjugated diene units of 75 mol % or more; carbon black; and silica, the rubber composition containing, per 100% by mass of the rubber component, 75% by mass or more of the hydrogenated copolymer, the rubber composition containing, relative to 100 parts by mass of the rubber component, 3 parts by mass or more of the carbon black and 1 to 200 parts by mass of the silica.
摘要:
To provide a process for producing an acrylic rubber/fluorinated rubber composition, capable of forming a layer excellent in the interlayer-adhesion with a layer formed by crosslinking a fluorinated rubber.A process for producing an acrylic rubber/fluorinated rubber composition having particles of a crosslinked acrylic rubber (B) dispersed in a continuous phase of a fluorinated rubber (A), which comprises kneading a fluorinated rubber (A), a crosslinking agent for an acrylic rubber and a crosslinking coagent for an acrylic rubber to obtain a fluorinated rubber composition containing the crosslinking agent for an acrylic rubber and the crosslinking coagent for an acrylic rubber, and kneading under heating the obtained fluorinated rubber composition and an acrylic rubber (B) in a mass ratio of fluorinated rubber (A)/acrylic rubber (B)=5/95 to 50/50 to crosslink the acrylic rubber (B), and dispersing particles of the crosslinked acrylic rubber (B) in a continuous phase of the fluorinated rubber (A).
摘要:
The invention related to novel compounds useful as modifying monomers and precursors for polymerization initiators. The invention further relates to a method of making the polymerization initiators and resulting polymers. The invention also relates to polymer compositions comprising the polymer of the invention and further components such as extender oils, fillers, vulcanizing agents etc., and to corresponding vulcanized polymer compositions and articles comprising vulcanized parts made from the vulcanized polymer composition.
摘要:
Provided are a blended rubber and a blended rubber composition that give a vulcanizate superior in abrasion resistance and ozone resistance, and a vulcanizate prepared by vulcanizing the blended rubber composition. A blended rubber, comprising 30 to 93 mass % of a chloroprene rubber, 5 to 50 mass % of a soft polyvinyl chloride, and 2 to 20 mass % of an acrylonitrile-butadiene rubber. The polyvinyl chloride resin used preferably has a polymerization degree of 300 to 3000 and the acrylonitrile-butadiene rubber preferably has an acrylonitrile content of 18 to 50 mass %.
摘要:
To provide a process for producing an acrylic rubber/fluorinated rubber composition, capable of forming a layer excellent in the interlayer-adhesion with a layer formed by crosslinking a fluorinated rubber.A process for producing an acrylic rubber/fluorinated rubber composition having particles of a crosslinked acrylic rubber (B) dispersed in a continuous phase of a fluorinated rubber (A), which comprises kneading a fluorinated rubber (A), a crosslinking agent for an acrylic rubber and a crosslinking coagent for an acrylic rubber to obtain a fluorinated rubber composition containing the crosslinking agent for an acrylic rubber and the crosslinking coagent for an acrylic rubber, and kneading under heating the obtained fluorinated rubber composition and an acrylic rubber (B) in a mass ratio of fluorinated rubber (A)/acrylic rubber (B)=5/95 to 50/50 to crosslink the acrylic rubber (B), and dispersing particles of the crosslinked acrylic rubber (B) in a continuous phase of the fluorinated rubber (A).
摘要:
A method for producing a polyacrylic water-absorbent resin powder includes the steps of: producing an acrylic monomer solution in which gas is dissolved and/or dispersed; polymerizing the monomer solution in the absence of a surface active agent or in the presence of not more than 300 ppm of a surface active agent; during or after polymerizing, fragmenting the resulting hydrated gel crosslinked polymer; and drying the fragmented hydrated gel crosslinked polymer, the gas being dissolved and/or dispersed in the monomer solution by (a) applying pressure to the acrylic monomer solution and the gas; (b) creating swirling flows of the acrylic monomer solution and the gas; or (c) introducing the gas with the acrylic monomer solution via fine holes. The production method efficiently produces a water-absorbent resin having an excellent water-absorption rate without deteriorating a liquid-absorbent property of a sanitary product or the like.
摘要:
In general the present invention provides a functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I) A-R1—Z (I) where R1 is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R1, and Z are substituents that will not protonate a pseudo-living polymer.
摘要:
A method for preparing a functionalized polymer comprising the steps of preparing a polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, wherein the lanthanide-based catalyst comprises (a) a lanthanide compound, (b) an alkylating agent, and (c) a source of halogen, and reacting the pseudo-living polymer with at least one amide-containing functionalizing agent.