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104 条记录 (耗时 0.02 秒)

    Alpha-hydroxyisobutyric acid process
    2.
    发明授权
    Alpha-hydroxyisobutyric acid process 失效
    α-羟基异丁酸方法

    公开(公告)号：US4351955A

    公开(公告)日：1982-09-28

    申请号：US204676

    申请日：1980-11-05

    申请人： Carl L. Willis ,  Lynn H. Slaugh

    发明人： Carl L. Willis ,  Lynn H. Slaugh

    IPC分类号： C07C51/08 ,  C07C59/00

    CPC分类号： C07C51/08

    摘要： Acetone cyanohydrin is converted to alpha-hydroxyisobutyric acid by contacting the cyanohydrin with alpha-hydroxymethanesulfonic acid and water at a temperature of about 70.degree.-125.degree. C. The alpha-hydroxymethanesulfonic acid is an equilibrium product of the reaction of water, sulfur dioxide and formaldehyde.

    摘要翻译： 丙酮氰醇通过使氰醇与α-羟基甲磺酸和水在约70-125℃的温度下接触而转化为α-羟基异丁酸.α-羟基甲磺酸是水，二氧化硫和 甲醛。

    Method for removing hydrogenation catalyst residues from hydrogenated conjugated diene polymers
    3.
    发明授权
    Method for removing hydrogenation catalyst residues from hydrogenated conjugated diene polymers 失效
    从氢化共轭二烯聚合物中除去氢化催化剂残留物的方法

    公开(公告)号：US4396761A

    公开(公告)日：1983-08-02

    申请号：US294969

    申请日：1981-08-21

    申请人： Carl L. Willis ,  Lynn H. Slaugh

    发明人： Carl L. Willis ,  Lynn H. Slaugh

    IPC分类号： C08C2/04 ,  C08F6/02 ,  C08F6/08

    CPC分类号： C08C2/04 ,  C08F6/02

    摘要： A process is disclosed for removing hydrogenation catalyst residues from hydrogenated conjugated diene polymers by contacting a hydrocarbon solution of said polymers with an aqueous dilute solution of an alpha-hydroxysulfonic acid, separating the aqueous phase from the hydrocarbon phase, removing the hydrocarbon solvent from the hydrocarbon phase, producing a solid polymer, and applying heat and/or vacuum to the solid polymer to remove the residual alpha-hydroxysulfonic acid.

    摘要翻译： 公开了一种通过使所述聚合物的烃溶液与α-羟基磺酸的稀水溶液接触来从氢化共轭二烯聚合物中除去氢化催化剂残余物的方法，从烃相中分离出水相，从烃中除去烃溶剂 产生固体聚合物，并向固体聚合物施加热和/或真空以除去残留的α-羟基磺酸。

    Method for removing catalyst residues from atactic polypropylene
    4.
    发明授权
    Method for removing catalyst residues from atactic polypropylene 失效
    从无规聚丙烯中除去催化剂残留物的方法

    公开(公告)号：US4316008A

    公开(公告)日：1982-02-16

    申请号：US209627

    申请日：1980-11-24

    申请人： Carl L. Willis ,  Lynn H. Slaugh

    发明人： Carl L. Willis ,  Lynn H. Slaugh

    IPC分类号： C08F6/02 ,  C08F6/08

    CPC分类号： C08F6/02

    摘要： Process for removing catalyst residues from atactic polypropylene is disclosed which comprises contacting the polypropylene with an aqueous solution of an alpha-hydroxysulfonic acid and then separating the polypropylene-containing phase from the aqueous phase.

    摘要翻译： 公开了从无规立构聚丙烯除去催化剂残余物的方法，其包括使聚丙烯与α-羟基磺酸的水溶液接触，然后将含聚丙烯的相与水相分离。

    Olefin hydration process
    5.
    发明授权
    Olefin hydration process 失效
    烯烃水合过程

    公开(公告)号：US4306101A

    公开(公告)日：1981-12-15

    申请号：US204677

    申请日：1980-11-05

    申请人： Lynn H. Slaugh ,  Carl L. Willis

    发明人： Lynn H. Slaugh ,  Carl L. Willis

    IPC分类号： C07C29/04 ,  C07C29/05

    CPC分类号： C07C29/04 ,  C07C29/05

    摘要： A process is disclosed for hydrating olefins to alcohols using a very active catalyst comprising an alpha-hydroxysulfonic acid prepared by reacting a carbonyl compound with sulfur dioxide and water.

    摘要翻译： 公开了使用包含通过使羰基化合物与二氧化硫和水反应制备的α-羟基磺酸的非常活泼的催化剂将烯烃水合成醇的方法。

    Cobalt-catalyzed process for preparing 1,3-propanediol using a lipophilic dihydroxyarene promoter
    8.
    发明授权
    Cobalt-catalyzed process for preparing 1,3-propanediol using a lipophilic dihydroxyarene promoter 失效
    使用亲脂性二羟基芳烃助催化剂制备1,3-丙二醇的钴催化方法

    公开(公告)号：US5576471A

    公开(公告)日：1996-11-19

    申请号：US316669

    申请日：1994-09-30

    申请人： Thomas C. Semple ,  Joseph B. Powell ,  Lynn H. Slaugh ,  Thomas C. Forschner ,  Paul R. Weider

    发明人： Thomas C. Semple ,  Joseph B. Powell ,  Lynn H. Slaugh ,  Thomas C. Forschner ,  Paul R. Weider

    IPC分类号： C07C29/141 ,  C07C29/16 ,  C07C45/58 ,  C07C45/80 ,  C07C27/04

    CPC分类号： C07C45/58 ,  C07C29/141 ,  C07C29/16 ,  C07C45/80

    摘要： 1,3-Propanediol is prepared in a process which involves reacting ethylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of a non-phosphine-ligated cobalt catalyst and a lipophilic dihydroxyarene promoter to produce an intermediate product mixture containing 3-hydroxypropanal in an amount less than 15 wt %; extracting the 3-hydroxypropanal from the intermediate product mixture into an aqueous liquid at a temperature less than about 100.degree. C. and separating the aqueous phase containing 3-hydroxypropanal from the organic phase containing cobalt catalyst; hydrogenating the 3-hydroxypropanal in the aqueous phase to 1,3-propanediol; and recovering the 1,3-propanediol.The process enables the production of 1,3-propanediol in high yields and selectivity without the use of a phosphine ligand-modified cobalt catalyst.

    摘要翻译： 1,3-丁二醇的制备方法是在非磷化氢连接的钴催化剂和亲脂性二羟基芳烃助催化剂存在下，使环氧乙烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中进行反应，生成中间体 含有小于15重量％的3-羟基丙醛的产物混合物; 在低于约100℃的温度下将中间产物混合物中的3-羟基丙醛萃取到含水液体中，并从含钴催化剂的有机相中分离出含有3-羟基丙醛的水相; 将水相中的3-羟基丙醛氢化为1,3-丙二醇; 并回收1,3-丙二醇。 该方法能够以高产率和选择性生产1,3-丙二醇，而不需要使用膦配体改性的钴催化剂。

    Process or making 3-hydroxyaldehydes
    9.
    发明授权
    Process or making 3-hydroxyaldehydes 失效
    制备或制备3-羟基醛

    公开(公告)号：US5344993A

    公开(公告)日：1994-09-06

    申请号：US130258

    申请日：1993-10-01

    申请人： Lynn H. Slaugh ,  Juan P. Arhancet

    发明人： Lynn H. Slaugh ,  Juan P. Arhancet

    IPC分类号： C07C29/16 ,  C07C31/20 ,  C07C45/58 ,  C07C45/50 ,  C07C45/57

    CPC分类号： C07C45/58 ,  C07C29/16 ,  C07C31/20

    摘要： This invention relates to a process for making 3-hydroxyaldehydes having 4 or more carbon atoms by intimately contacting(a) 1,2-epoxides having 3 or more carbon numbers,(b) ditertiary phosphine-modified cobalt carbonyl catalyst, said phosphine being a hydrocarbylene-bis(monophosphabicyclononane) in which each phosphorus atom is joined to hydrocarbylene and is a member of a bridge linkage without being a bridgehead atom and which hydrocarbylene-bis(monophosphabicyclononane) has 11 to 80 carbon atoms, 5 to 12 carbon atoms thereof together with a phosphorus atom being members of each of the two bicyclic skeletal structures,(c) carbon monoxide, and(d) hydrogen, the molar ratio of carbon monoxide to hydrogen being from about 4:1 to about 1:6, in liquid-phase solution in an inert reaction solvent, at a temperature of from about 30.degree. C. to about 150.degree. C. and a pressure of from about 50 psi to about 10,000 psi. Acids and promoter salts may be added to the reaction mixture to promote the hydroformylation reaction.

    摘要翻译： 本发明涉及一种通过紧密接触（a）具有3个或更多个碳数的1,2-环氧化物制备具有4个或更多个碳原子的3-羟基醛的方法，（b）二膦膦改性的羰基钴催化剂，所述膦是 其中每个磷原子连接到亚烃基并且不是桥头原子的桥连构件的亚烃基 - 双（单磷酰基二环壬烷），并且亚烃基 - 双（单磷杂二环壬烷）具有11至80个碳原子，5至12个碳原子在一起 其中磷原子是两个双环骨架结构中的每一个的成员，（c）一氧化碳和（d）氢，一氧化碳与氢的摩尔比为约4:1至约1:6， 在惰性反应溶剂中，在约30℃至约150℃的温度和约50psi至约10,000psi的压力下进行。 可以向反应混合物中加入酸和促进剂盐以促进加氢甲酰化反应。

    Melt stabilized polyketone blend containing a mixture of magnesium oxide and alumina
    10.
    发明授权
    Melt stabilized polyketone blend containing a mixture of magnesium oxide and alumina 失效
    含有氧化镁和氧化铝混合物的熔融稳定的聚酮共混物

    公开(公告)号：US5126496A

    公开(公告)日：1992-06-30

    申请号：US738410

    申请日：1991-07-31

    申请人： Lynn H. Slaugh

    发明人： Lynn H. Slaugh

    IPC分类号： C08K3/22

    CPC分类号： C08K3/22

    摘要： A stabilized polymer composition comprising a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon, and a melt stabilizer comprising a mixture of magnesium oxide and alumina. A process of preparing the composition and articles of manufacture made of the composition are also disclosed.

    摘要翻译： 一种稳定的聚合物组合物，其包含一氧化碳和至少一种烯属不饱和烃的线性交替聚合物和包含氧化镁和氧化铝的混合物的熔体稳定剂。 还公开了制备由该组合物制成的组合物和制品的方法。