公开(公告)号：US4663724A

公开(公告)日：1987-05-05

申请号：US580362

申请日：1984-02-15

申请人： Masakazu Onizuka ,  Naohiko Ukawa ,  Susumu Kono ,  Susumu Okino

发明人： Masakazu Onizuka ,  Naohiko Ukawa ,  Susumu Kono ,  Susumu Okino

IPC分类号： G01N31/00 ,  G01N33/00 ,  G06F15/46 ,  G01N35/08

CPC分类号： G01N31/00 ,  Y10T436/117497 ,  Y10T436/204998

摘要： A solution or slurry containing a carbonate or sulfite, or both is continuously supplied into a tightly closed vessel, while any excess of the liquid is allowed to overflow the vessel. Sulfuric acid is supplied into the vessel to maintain the pH level of the liquid in the vessel at a value not exceeding 3. Air is supplied into the vessel as a carrier gas for CO.sub.2 or SO.sub.2 or both formed by the reaction of the carbonate or sulfite or both in the liquid with the sulfuric acid. The carrier gas is collected from the vessel, and the concentration of CO.sub.2 or SO.sub.2 or both in the carrier gas is determined. The concentration of the carbonate or sulfite or both in the liquid is obtained by calculations from the concentration of CO.sub.2 or SO.sub.2 or both, the flow rate of the liquid and the flow rate of the carrier gas.

摘要翻译： 含有碳酸盐或亚硫酸盐或两者的溶液或浆料被连续地供应到密闭容器中，同时允许任何多余的液体溢出容器。 将硫酸供应到容器中以将容器中的液体的pH水平保持在不超过3的值。空气作为CO 2或SO 2的载气或二者通过碳酸盐或亚硫酸盐的反应供入到容器中 或两者都在液体与硫酸。 从容器收集载气，确定载气中的二氧化碳或二氧化硫或二者的浓度。 通过从CO 2或SO 2或二者的浓度，液体的流量和载气的流速计算得到液体中的碳酸盐或亚硫酸盐或两者的浓度。

公开(公告)号：US4420465A

公开(公告)日：1983-12-13

申请号：US390835

申请日：1982-06-22

申请人： Naoharu Shinoda ,  Atsushi Tatani ,  Naohiko Ukawa ,  Michio Oshima ,  Susumu Okino ,  Sadaichi Shigeta

发明人： Naoharu Shinoda ,  Atsushi Tatani ,  Naohiko Ukawa ,  Michio Oshima ,  Susumu Okino ,  Sadaichi Shigeta

IPC分类号： B01D53/50 ,  B01D53/77 ,  C01F11/46 ,  C01B17/00

CPC分类号： C01F11/464 ,  B01D53/501

摘要： A process for desulfurizing an exhaust gas which comprises desulfurizing an exhaust gas containing SO.sub.2 by bringing it into contact with a slurry containing calcium compounds and aluminum compounds, characterized in that the concentration of the dissolved aluminum ion in said slurry is detected and a manganese compound is supplied into said slurry in such a manner that the ratio of the concentration of manganese (including both solid and liquid) to said concentration of the dissolved aluminum ion may be maintained in a molar ratio of less than 1 in said slurry.

摘要翻译： 一种废气脱硫方法，其特征在于，将含有二氧化硫的废气与含有钙化合物和铝化合物的浆料接触，其特征在于检测所述浆料中溶解的铝离子的浓度，锰化合物为 供给到所述浆料中，使得所述浆料中锰（包括固体和液体两者）的浓度与所述溶解的铝离子的浓度之比可保持小于1的摩尔比。

公开(公告)号：US06773680B2

公开(公告)日：2004-08-10

申请号：US10294269

申请日：2002-11-14

申请人： Taku Shimizu ,  Kazuaki Kimura ,  Kiyoshi Okazoe ,  Atsushi Tatani ,  Naohiko Ukawa ,  Masao Hino ,  Susumu Okino ,  Takashi Haruki ,  Toru Takashina ,  Eiji Ochi

发明人： Taku Shimizu ,  Kazuaki Kimura ,  Kiyoshi Okazoe ,  Atsushi Tatani ,  Naohiko Ukawa ,  Masao Hino ,  Susumu Okino ,  Takashi Haruki ,  Toru Takashina ,  Eiji Ochi

IPC分类号： B01J808

CPC分类号： C10M173/02 ,  B01D53/46 ,  B01D53/501 ,  C10M2215/042 ,  C10M2229/045 ,  C10M2229/046 ,  C10N2220/13 ,  C10N2240/58 ,  F23J15/003 ,  F23J15/022 ,  F23J2215/20 ,  F23J2219/50

摘要： Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.

公开(公告)号：US06770119B2

公开(公告)日：2004-08-03

申请号：US10233526

申请日：2002-09-04

申请人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Suzaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

发明人： Masahiro Harada ,  Shintaro Honjo ,  Makoto Suzaki ,  Kazuo Ishida ,  Hajime Nagano ,  Susumu Okino

IPC分类号： B01D5314

CPC分类号： C10K1/16 ,  B01D53/14 ,  B01D53/64 ,  B01D2257/602 ,  C10K1/085 ,  C10K1/10

摘要： The present invention provides a mercury removal method which can effectively remove very small amounts of mercury components present in a gas during wet gas purification such as coal or heavy oil gasification gas purification and petroleum refining. A mercury removal method for the removal of mercury present in a gas, the method comprising the steps of bringing a gas containing at least mercury and not less than 10 ppm of hydrogen sulfide into gas-liquid contact with an absorbing fluid under pressurized conditions so as to cause mercury to pass into the absorbing fluid; flashing the mercury-containing absorbing fluid under lower-pressure conditions to separate it into gaseous components and liquid components; and removing the mercury contained in the separated gaseous components by adsorption to an adsorbent.

摘要翻译： 本发明提供了一种除汞方法，其可以有效地去除在湿气净化中例如煤或重油气化气净化和石油精炼中的气体中存在的非常少量的汞成分。 一种用于除去存在于气体中的汞的汞去除方法，该方法包括以下步骤：在加压条件下使至少包含汞和不少于10ppm硫化氢的气体与吸收液体气液接触，以便 使汞进入吸收液; 在低压条件下闪烁含汞吸收液，将其分离成气态组分和液体组分; 并且通过吸附到吸附剂上除去分离的气态组分中所含的汞。

公开(公告)号：US06471073B1

公开(公告)日：2002-10-29

申请号：US09555754

申请日：2000-06-02

申请人： Yoshihiro Okamoto ,  Eiji Ochi ,  Atsushi Tatani ,  Susumu Okino ,  Toru Takashina

发明人： Yoshihiro Okamoto ,  Eiji Ochi ,  Atsushi Tatani ,  Susumu Okino ,  Toru Takashina

IPC分类号： B01D2124

CPC分类号： B01D21/2416 ,  B01D21/003 ,  B01D21/0036 ,  B01D21/0039 ,  B01D21/0051 ,  B01D21/2444

摘要： A liquid extracting apparatus in accordance with the present invention is configured so that a connection pipe 22a (suction-side pipe) of a pump 22 for extracting slurry liquid content is connected to the upper end side of a liquid content introduction path to which slurry in a tank 8 can be introduced to attain the precipitation and separation of solid content, and a number of tubes 26 are packed at the lower end portion of the liquid content introduction path 21. The present invention can provide a simple liquid extracting apparatus that can effectively extract only liquid content in the slurry (suspension) moving in the tank.

摘要翻译： 根据本发明的液体提取装置被构造成使得用于提取浆液液体含量的泵22的连接管22a（吸入侧管）连接到液体内容物引入路径的上端侧， 可以引入罐8以获得固体含量的沉淀和分离，并且在液体含量引入路径21的下端部分填充多个管26.本发明可以提供一种简单的液体提取装置，其可以有效地 仅在罐中移动的浆液（悬浮液）中仅提取液体含量。

公开(公告)号：US6138378A

公开(公告)日：2000-10-31

申请号：US341433

申请日：1999-09-08

申请人： Toru Takashina ,  Naoyuki Kamiyama ,  Takeo Shinoda ,  Hiromitsu Nagayasu ,  Susumu Okino ,  Masakazu Onizuka ,  Koichiro Iwashita ,  Satoshi Nakamura ,  Kenji Inoue

发明人： Toru Takashina ,  Naoyuki Kamiyama ,  Takeo Shinoda ,  Hiromitsu Nagayasu ,  Susumu Okino ,  Masakazu Onizuka ,  Koichiro Iwashita ,  Satoshi Nakamura ,  Kenji Inoue

IPC分类号： B01D53/50 ,  B01D47/06 ,  B01D53/14 ,  B01D53/18 ,  B01D53/34 ,  B01D53/77 ,  B01D53/78 ,  B01D53/80 ,  F26B7/00

CPC分类号： B01D53/80 ,  B01D53/1412 ,  B01D53/18 ,  B01D53/504 ,  B01D53/78 ,  F23J2215/20 ,  F23J2219/40

摘要： This invention is related to a wet gas process which would not require a spray pump, and which would allow the absorption liquid to be recovered smoothly even if the flow velocity of the gases entrained to the liquid should decrease. A wet gas processing apparatus in which the absorption liquid collected in the first liquid storage tank is sprayed in a specified direction (which may be upward, horizontal or downward) by a discharge unit consisting of spray nozzles (14) or the like in the absorption tower. The sprayed liquid is brought into contact with the exhaust gases which are conducted into the tower, and the targeted components of the gases are absorbed and removed. This processing apparatus is distinguished by the following. The first liquid storage tank for the absorption liquid comprises a pressure tank (11) which generates a pressurized gas in the space above the surface of the collected liquid (11a). The increased pressure of the pressurized gas is employed to spray the liquid collected in the pressurized tank from the spray nozzle unit in the absorption tower. This apparatus is further distinguished as the following. This invention has overflow ports which generate a virtually horizontal overflow or source flow. The absorption liquid propelled by the overflow ports makes orthogonal contact with the flow of exhaust gases, which results in both atomization of the liquid and liquid-vapor contact.

摘要翻译： PCT No.PCT / JP98 / 05062 Sec。 371 1999年9月8日第 102（e）日期1999年9月8日PCT提交1998年11月10日PCT公布。 出版物WO99 /​​ 24148 日期1999年5月20日本发明涉及不需要喷雾泵的湿法气体处理，即使吸入液体的气体的流速降低也能使吸收液体顺利地回收。 一种湿气处理装置，其中收集在第一液体储罐中的吸收液体通过在吸收中由喷嘴（14）等组成的排出单元在特定方向（可以是向上，水平或向下）喷射） 塔。 喷射的液体与被引导到塔中的废气接触，并且气体的目标成分被吸收和去除。 该处理装置的区别在于以下。 用于吸收液体的第一液体储存罐包括在收集液体（11a）的表面上方的空间中产生加压气体的压力罐（11）。 加压气体的增加的压力用于将从加压罐中收集的液体从吸收塔中的喷嘴单元喷射。 该装置进一步区别如下。 本发明具有产生实质上水平的溢流或源流的溢流口。 由溢流口推动的吸收液体与废气流正交接触，导致液体雾化和液 - 气接触。

公开(公告)号：US6079212A

公开(公告)日：2000-06-27

申请号：US210619

申请日：1998-12-14

申请人： Atsushi Tatani ,  Makoto Susaki ,  Susumu Okino ,  Shintarou Honjo

发明人： Atsushi Tatani ,  Makoto Susaki ,  Susumu Okino ,  Shintarou Honjo

IPC分类号： F01D5/28 ,  B01D53/48 ,  B01D53/50 ,  B01D53/77 ,  B01D53/94 ,  F01K23/10 ,  F02C3/28 ,  F02C7/30 ,  F01B31/16

CPC分类号： F02C3/28 ,  B01D53/48 ,  Y02E20/16 ,  Y02E20/18

摘要： This invention relates to a gasification power generation process wherein a product gas A1 obtained by the gasification of coal or petroleum is used as the fuel of a gas turbine 4 for electric power generation, the process comprising the steps of dedusting product gas A1, introducing product gas A1 directly into gas turbine 4 as the fuel thereof to effect electric power generation, and subjecting the exhaust gas A2 discharged from gas turbine 4 to a gas purification treatment including at least desulfurization. This invention can provide a gasification power generation process which is more suitable for practical use from an economic point of view in that a high degree of exhaust gas purification and a marked improvement in thermal efficiency can be achieved and, moreover, the construction of the equipment for carrying out a gas purification treatment including desulfurization can be highly simplified.

摘要翻译： 本发明涉及一种气化发电方法，其中将通过煤或石油气化获得的产物气体A1用作用于发电的燃气轮机4的燃料，该方法包括以下步骤：除尘产物气体A1，引入产物 气体A1直接作为其燃料的燃气轮机4进行发电，并将从燃气轮机4排出的排气A2进行至少包括脱硫的气体净化处理。 从经济角度出发，本发明能够提供一种更适合于实际应用的气化发电方法，其特征在于能够实现高排气净化和热效率的明显提高，而且， 用于进行包括脱硫的气体净化处理可以被高度简化。

公开(公告)号：US5762883A

公开(公告)日：1998-06-09

申请号：US665943

申请日：1996-06-19

申请人： Kiyoshi Okazoe ,  Eiji Ochi ,  Toru Takashina ,  Susumu Okino

发明人： Kiyoshi Okazoe ,  Eiji Ochi ,  Toru Takashina ,  Susumu Okino

IPC分类号： B01D53/34 ,  B01D53/50 ,  B01D53/77

CPC分类号： B01D53/504

摘要： This invention relates to a wet flue gas desulfurization apparatus including: an absorption tower having defined in the lower part thereof a tank for holding a calcium compound-containing slurry fed thereto; a circulating pump for delivering the slurry within the tank to the upper part of the absorption tower in order to bring it into contact with flue gas; air supply member for supplying air to the tank for purposes of oxidation; a withdrawal pump for withdrawing the slurry within the tank in order to recover gypsum formed as a by-product or discharge waste water; falling slurry withdrawal member for withdrawing part of the slurry delivered to the upper part of the absorption tower by the circulating pump and falling through the absorption tower at a position above the liquid surface of the tank; and mixing member for the slurry withdrawn by the falling slurry withdrawal member with the slurry withdrawn from the tank by the withdrawal pump, whereby oxidizing substances produced in the tank of the absorption tower can be decreased by reduction.

摘要翻译： 本发明涉及一种湿式烟道气脱硫装置，包括：吸收塔，其下部具有用于保持供给其中含钙化合物的浆料的罐; 循环泵，用于将罐内的浆料输送到吸收塔的上部，以使其与烟气接触; 空气供给构件，用于向氧化槽供给空气; 用于取出罐内的浆料以便回收作为副产物形成的石膏或排出废水的抽出泵; 用于取出通过循环泵输送到吸收塔的上部的一部分浆料并且在罐的液面上方的位置落入吸收塔的落下浆料取出构件; 以及由下降浆料取出构件取出的浆料的混合构件，其中通过抽吸泵从罐中取出的浆料，由此通过还原可以减少在吸收塔的罐中产生的氧化物质。

公开(公告)号：US5560893A

公开(公告)日：1996-10-01

申请号：US472488

申请日：1995-06-07

申请人： Susumu Okino ,  Hiroshi Tanaka

发明人： Susumu Okino ,  Hiroshi Tanaka

IPC分类号： B01D53/34 ,  B01D53/50 ,  B01D53/77 ,  G05D7/00

CPC分类号： B01D53/504 ,  Y10S423/05

摘要： In a flue gas desulfurization process wherein, when sulfur oxide-containing exhaust gas is treated with an absorbing solution containing a calcium compound, an oxygen-containing gas is passed through the absorbing solution and the flow rate of the oxygen-containing gas is controlled by detecting the oxidation-reduction potential of the absorbing solution continuously, an oxidation controlling method which comprises detecting a first deviation signal between the oxidation-reduction potential of the absorbing solution and the oxidation-reduction potential of the absorbing solution in a completely oxidized state and controlling the flow rate of the oxygen-containing gas in response to a second deviation signal between the first deviation signal and a preset oxidation-reduction potential deviation value.

摘要翻译： 在一种烟道气脱硫方法中，当含有含硫氧化物的废气用含有钙化合物的吸收溶液处理时，含氧气体通过吸收溶液，含氧气体的流量由 连续检测吸收液的氧化还原电位的氧化控制方法，其包括在完全氧化状态下检测吸收溶液的氧化还原电位与吸收溶液的氧化还原电位之间的第一偏差信号，并控制 响应于第一偏差信号和预设氧化还原电位偏差值之间的第二偏差信号，含氧气体的流量。

公开(公告)号：US5284557A

公开(公告)日：1994-02-08

申请号：US720621

申请日：1991-06-25

申请人： Naohiko Ukawa ,  Susumu Okino ,  Toru Takashina ,  Masakazu Onizuka ,  Kenji Inoue

发明人： Naohiko Ukawa ,  Susumu Okino ,  Toru Takashina ,  Masakazu Onizuka ,  Kenji Inoue

IPC分类号： B01D53/60 ,  B01D53/50 ,  B01D53/74 ,  B01D53/77 ,  C25B1/00

CPC分类号： B01D53/501

摘要： A method for desulfurizing an exhaust gas containing SO.sub.2 and NO.sub.x in accordance with a wet lime process, the aforesaid desulfurizing method being characterized by comprising the steps of drawing a part of an absorbing slurry, subjecting a filtrate obtained by the solid-liquid separation of the drawn absorbing slurry to an electrolysis treatment in the presence of chlorine ions, or after adjusting the filtrate to pH 3-4, mixing a hydrochlorite with the filtrate, and then refeeding the filtrate as a make-up water to an absorbing tower.

摘要翻译： 一种根据湿法石灰处理对含有二氧化硫和氮氧化物的废气进行脱硫的方法，上述脱硫方法的特征在于包括以下步骤：拉出一部分吸收浆料，将通过固液分离得到的滤液 在氯离子存在下进行电解处理，或将滤液调节至pH 3-4后，与滤液混合，然后将滤液作为补充水重新加入到吸收塔中。