DESULFURIZATION AND DENITRATION METHOD USING CHLORINE DIOXIDE

    公开(公告)号:US20220274057A1

    公开(公告)日:2022-09-01

    申请号:US17628798

    申请日:2020-03-20

    申请人: Shanghui Tong

    发明人: Shanghui Tong

    IPC分类号: B01D53/60 B01D53/75 B01D53/78

    摘要: A desulfurization and denitration method includes adding an aqueous solution of a chlorate, an aqueous solution of a peroxide, and an aqueous solution of sulfuric acid to a chlorine dioxide generator to obtain gaseous chlorine dioxide, and mixing the gaseous chlorine dioxide with air to obtain a mixed gas. The gaseous chlorine dioxide is 4-10 vol % of the mixed gas. The method includes letting the mixed gas come into contact with a flue gas to obtain an oxidized flue gas. A molar ratio of the gaseous chlorine dioxide in the mixed gas to nitric oxide in the flue gas is 1-1.8. The final step includes passing the oxidized flue gas to the desulfurization and denitration tower and mixing the oxidized flue gas with a spray of an alkaline absorbent dry powder, and spraying water into the desulfurization and denitration tower to obtain a desulfurized and denitrated flue gas.

    Chemical sequestering of CO2, NOx and SO2

    公开(公告)号:US11369918B2

    公开(公告)日:2022-06-28

    申请号:US16773293

    申请日:2020-01-27

    摘要: The disclosure provides seven integrated methods for the chemical sequestration of carbon dioxide (CO2), nitric oxide (NO), nitrogen dioxide (NO2) (collectively NOx, where x=1, 2) and sulfur dioxide (SO2) using closed loop technology. The methods recycle process reagents and mass balance consumable reagents that can be made using electrochemical separation of sodium chloride (NaCl) or potassium chloride (KCl). The technology applies to marine and terrestrial exhaust gas sources for CO2, NOx and SO2. The integrated technology combines compatible and green processes that capture and/or convert CO2, NOx and SO2 into compounds that enhance the environment, many with commercial value.

    INTELLIGENT MULTI-POLLUTANT ULTRA-LOW EMISSION SYSTEM AND GLOBAL OPTIMIZATION METHOD THEREOF

    公开(公告)号:US20210319373A1

    公开(公告)日:2021-10-14

    申请号:US17263869

    申请日:2019-10-30

    摘要: The invention relates to an intelligent multi-pollutant ultra-low emission system and a global optimization method thereof. The intelligent multi-pollutant ultra-low emission system comprises a device layer, a sensing layer, a control layer and an optimization layer from bottom to top. The global optimization method comprises: obtaining an accurate description multiple pollutants in the generation, migration, transformation and removal process in multiple devices by means of accurate modeling of a multi-device multi-pollutant simultaneous removal process of the ultra-low emission system; accurately evaluating multi-pollutant emission reduction costs under different loads, coal qualities, pollutant concentrations and operating parameters through a global operating cost evaluation method of the ultra-low emission system; realizing minute-level planning and optimization of emission reductions of a global pollutant emission reduction device under different emission targets through a multi-pollutant, multi-target and multi-condition global operating optimization method; and guaranteeing reliable emission reduction and margin control of the pollutants through an advanced control method for reliable up-to-standard ultra-low emission of the pollutants.

    REMOVAL OF ATMOSPHERIC POLLUTANTS FROM GAS, RELATED APPARATUS, PROCESSES AND USES THEREOF

    公开(公告)号:US20200289979A1

    公开(公告)日:2020-09-17

    申请号:US16748196

    申请日:2020-01-21

    摘要: Methods related generally to the removal of atmospheric pollutants from the gas phase, are provided, as well as related apparatus, processes and uses thereof. A single-stage air scrubbing apparatus is provided that includes at least one reaction vessel, at least one introduction duct, and a turbulence component, wherein a residence time is sufficient to allow the conversion of at least one atmospheric pollution compound to at least one other compound, molecule or atom. In some embodiments, the at least one atmospheric pollution compound comprises nitrogen oxide, sulfur oxide or a combination thereof. Additionally, methods of removing atmospheric pollution compounds from a waste gas stream are disclosed that include introducing a waste gas stream and at least one additional gas stream, mist stream, liquid stream or combination thereof into a single-stage air scrubbing apparatus at a flow rate sufficient to allow for conversion of the at least one atmospheric pollution compound.

    Device and method for purifying sulfur dioxide and nitrogen oxide in flue gas

    公开(公告)号:US10730010B2

    公开(公告)日:2020-08-04

    申请号:US16515634

    申请日:2019-07-18

    IPC分类号: B01D53/60 B01D9/00 B01D53/79

    摘要: The invention is a device and method for purifying sulfur dioxide and nitrogen oxide in flue gas with an electrolysis-chemical advanced oxidation enhanced ammonia method. The device includes a thermal activation reactor, ammonium hydroxide storage tank, absorption tower, electrolytic bath and crystallization separator. The method takes raw material part of an ammonium sulfate solution that is a reaction product of ammonia and sulfur oxide in flue gas, and an ammonium persulfate solution prepared by electrolysis of an electrolytic bath as an oxidant to enhance the efficiency of purifying sulfur dioxide and nitrogen oxide in the flue gas with an ammonia method. A thermal activation reactor activates an ammonium persulfate containing solution to generate a strong oxidizing SO4.−, so that NOx and SO2 in the flue gas may be more efficiently converted into a product having higher solubleness for enhanced removal of sulfur dioxide and nitrogen oxide in the flue gas.