Flue gas desulfurization process utilizing hydrogen peroxide
    4.
    发明授权
    Flue gas desulfurization process utilizing hydrogen peroxide 有权
    烟气脱硫工艺利用过氧化氢

    公开(公告)号:US07998446B2

    公开(公告)日:2011-08-16

    申请号:US12111732

    申请日:2008-04-29

    Abstract: A flue gas desulfurization process in which a SO2-containing flue gas stream is contacted with a recirculating stream of an aqueous medium containing concentrated sulfuric acid and hydrogen peroxide, to yield a desulfurized flue gas stream and to produce additional sulfuric acid in the aqueous medium. A portion of the recirculating aqueous sulfuric acid stream is diverted for recovery of the additional sulfuric acid as gypsum in a neutralization step, and the process parameters are adjusted so that the heat of reaction generated during the neutralization step is sufficient to evaporate the free water that is present and yield a gypsum product that is substantially dry.

    Abstract translation: 一种烟道气脱硫方法,其中使含SO2的烟气流与含有浓硫酸和过氧化氢的水性介质的再循环流接触,以产生脱硫烟道气流并在水性介质中产生另外的硫酸。 转移一部分再循环的硫酸水溶液以在中和步骤中回收作为石膏的附加硫酸,并调节工艺参数,使得在中和步骤中产生的反应热足以蒸发游离水, 并且产生基本干燥的石膏产品。

    Method of purifying flue gas waste slurries for use in gypsum production
    6.
    发明授权
    Method of purifying flue gas waste slurries for use in gypsum production 有权
    净化用于石膏生产的废气废料浆的方法

    公开(公告)号:US06197200B1

    公开(公告)日:2001-03-06

    申请号:US09309633

    申请日:1999-05-11

    Abstract: A method of purifying a flue gas desulfurization aqueous waste slurry containing calcium-sulfur salts and residual solid grits, fly ash, carbon and oils by supplying the aqueous waste slurry to a screening station to remove the grits, passing the grit-free aqueous waste slurry to a magnetic separator to remove fly ash components, and transferring the aqueous slurry to a floatation cell to remove carbon and oils therefrom. A purified aqueous slurry of calcium-sulfur salts is removed from the floatation cell which can be used in producing quality plaster, wallboard, or feedstock in producing &agr;-hemihydrate gypsum.

    Abstract translation: 一种通过将含水废弃物浆料供应到筛选站以除去砂粒,使无粗细的含水废料浆料通过,将含有硫酸钙硫酸盐和残余固体砂粒,粉煤灰,碳和油的烟道气脱硫废水浆液净化的方法 到磁性分离器以除去飞灰组分,并将含水浆料转移到漂浮池中以从其中除去碳和油。 从浮选池中除去纯化的钙 - 硫盐水溶液,其可用于生产高质量的石膏,墙板或原料以生产α-半水石膏。

    Wet flue-gas dsulfurization system
    9.
    发明授权
    Wet flue-gas dsulfurization system 失效
    湿式烟气脱硫系统

    公开(公告)号:US5665129A

    公开(公告)日:1997-09-09

    申请号:US523826

    申请日:1995-09-06

    CPC classification number: B01D53/504 C01F11/464 C01F5/40

    Abstract: A wet flue-gas desulfurization system which effectively reduces the mist concentration in the treated gas at its outlet. The system includes an absorption column, formed with a tank at the bottom which is supplied with an absorbent slurry and a circulating pump for forcing the slurry upwardly from the tank into the flue gas inlet at the top of the column for contact with flue gas. Sulfur dioxide, for example, is removed from the flue gas, being introduced in the flue gas inlet, by absorption with the absorbent slurry. The treated gas, free of sulfur dioxide, is discharged through a gas-outlet duct formed to rise integrally from the top of an end part of the tank. For reducing the mist concentration a mist eliminator is provided and is held upright, as a vertical partition, across the riser of the duct, with the lower end of the eliminator being extended partly into the bath of the absorbent slurry inside the tank.

    Abstract translation: 一种湿式烟气脱硫系统,可有效降低出口处理气体中的雾浓度。 该系统包括吸收塔,底部形成有供给吸收剂浆料的罐,以及循环泵,用于将浆料从罐向上推入塔顶部的烟道气入口以与烟气接触。 例如,二氧化硫通过吸收剂浆料的吸收被从烟道气中除去,被引入烟道气入口。 处理过的无二氧化硫的气体通过形成为从罐的端部顶部整体上升的气体出口导管排出。 为了减少雾浓度,提供雾气消除器,并且作为垂直分隔件直立地延伸穿过管道的立管,消除器的下端部分地延伸到罐内的吸收剂浆液的浴中。

    Process for producing ammonium sulfate from flue-gas scrubber waste
liquor
    10.
    发明授权
    Process for producing ammonium sulfate from flue-gas scrubber waste liquor 失效
    从废气洗涤塔废液中生产硫酸铵的方法

    公开(公告)号:US5618511A

    公开(公告)日:1997-04-08

    申请号:US516346

    申请日:1995-08-11

    CPC classification number: C01C1/245 B01D53/60 B01D53/96 C01F11/464

    Abstract: A flue-gas scrubbing-liquor regeneration process that is based on contacting N-S compounds contained in a flue-gas scrubbing liquor with a lime/limestone solution in a double draw-off crystallizer under suitable pH conditions for precipitating calcium salts of N-S compounds. The precipitated crop is filtered and then hydrolyzed in a sulfuric acid environment to produce gypsum and ammonium sulfate in solution. The hydrolyzed slurry is filtered and the filtrate is neutralized with lime to liberate ammonia gas that is then sparged through a sulfuric acid solution to cause the precipitation of commercial-grade ammonium sulfate.

    Abstract translation: 一种烟道气洗涤液再生方法,其基于将烟道气洗涤液中所含的N-S化合物与双重抽出结晶器中的石灰/石灰石溶液在合适的pH条件下接触以沉淀N-S化合物的钙盐。 将沉淀的作物过滤,然后在硫酸环境中水解,在溶液中产生石膏和硫酸铵。 将水解的浆液过滤并用石灰中和滤液以释放出氨气,然后将氨气喷射通过硫酸溶液使商业级硫酸铵沉淀。

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