摘要:
The invention relates to a metallocene compound of the formula I ##STR1## where the two indenyl ligands have substitution patterns different from one another. The metallocene compound can be used as catalyst component for olefin polymerization.
摘要:
A highly effective catalyst system for the polymerization of olefins comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## where M.sup.1 =Zr or Hf, R.sup.1 and R.sup.2 =(C.sub.1 -C.sub.4)-alkyl or chlorine, R.sup.3, with the proviso that at least one of the radicals R.sup.3 is not hydrogen, =hydrogen, F, Cl, --OR.sup.7, --NR.sup.7 R.sup.8, --P(O)R.sup.7 R.sup.8, --P(OR.sup.7).sub.2 or SR.sup.7, R.sup.4 is a ##STR2## radical, and m plus n are zero or 1.
摘要:
Process for the preparation of an olefin polymer using metallocenes containing specifically substituted indenyl ligandsA highly effective catalyst system for the polymerization of olefins comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## in which, preferably M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.5 is hydrogen or alkyl, R.sup.3 and R.sup.4 are alkyl, where R.sup.3, R.sup.4 and R.sup.5 may be halogenated, --(CR.sup.7 R.sup.8).sub.m --R.sup.6 --(CR.sup.7 R.sup.8).sub.n -- is a single- or multi-membered chain in which R.sup.6 may also be a (substituted) heteroatom, and m+n is zero or 1.
摘要:
Improved Ziegler-Natta catalysts and methods of making the improved catalyst are described. The Ziegler-Natta catalyst is formed using a spherical MgCl2-xROH support, where R is a linear, cyclic or branched hydrocarbon unit with 1-10 carbon atoms and where ROH is an alcohol or a mixture of at least two different alcohols and where x has a range of about 1.5 to 6.0, preferably about 2.5 to 4, more preferably about 2.9 to 3.4, and even more preferably 2.95 to 3.35. The Ziegler-Natta catalyst includes a Group 4-8 transition metal and an internal donor. The catalyst has improved activity in olefin polymerization reactions as well as good stereoregularity and hydrogen sensitivity.
摘要:
A gene expression signature of colon cancer, microarrays including them and methods of using the colon gene expression signature are provided. The gene expression signature is especially useful for determining the prognosis of a patient diagnosed with colon cancer, such as stage II colon cancer. The gene signature described herein is also useful for determining effectiveness of surgical resection with or without adjuvant chemotherapy, and determining possibility of cancer recurrence in patients with colon cancer.
摘要:
A rotary laser device and method is disclosed. The rotary laser device includes a laser device, which generates a laser beam, a rotating device, which moves the laser device at least partially around an axis of rotation at a rotation speed, and a measuring device, with which an angle of rotation of the laser device around the axis of rotation can be determined. A memory device is provided for saving at least one angular position.
摘要:
A gene expression signature of colon cancer, microarrays including them and methods of using the colon gene expression signature are provided. The gene expression signature is especially useful for determining the prognosis of a patient diagnosed with colon cancer, such as stage II colon cancer. The gene signature described herein is also useful for determining effectiveness of surgical resection with or without adjuvant chemotherapy, and determining possibility of cancer recurrence in patients with colon cancer.
摘要:
A method for copy protection includes providing audiovisual or audio data stored in sectors of a record carrier having a file system, and providing additional data to be stored in further sectors. The method includes generating first and second files referencing respective first and second parts of the sectors and respective further first and second parts of the further sectors, so when the first and second files are completely rendered by a playback device, respective first and second parts of the data and respective further first and second parts of the additional data are reproduced. The method also includes determining program instructions, which when executed by the playback device, control switching between reading the first file and the second file, and when the record carrier is an original, switching is controlled so only the sectors and none of the further sectors are read such that no additional data is reproduced.
摘要:
Certain metallocene compounds are provided that, when used as a component in a supported polymerization catalyst under industrially relevant polymerization conditions, afford high molar mass homo polymers or copolymers like polypropylene or propylene/ethylene copolymers without the need for any α-branched substituent in either of the two available 2-positions of the indenyl ligands. The substituent in the 2-position of one indenyl ligand can be any radical comprising hydrogen, methyl, or any other C2-C40 hydrocarbon which is not branched in the α-position, and the substituent in the 2-position of the other indenyl ligand can be any C4-C40 hydrocarbon radical with the proviso that this hydrocarbon radical is branched in the β-position. This metallocene topology affords high melting point, very high molar mass homo polypropylene and very high molar mass propylene-based copolymers. The activity/productivity levels of catalysts including the metallocenes of the present invention are exceptionally high.
摘要:
A method for copy protection includes providing audiovisual or audio data stored in sectors of a record carrier having a file system, and providing additional or modified data to be stored in further sectors. The method includes generating a first file of the file system referencing at least a part of the sectors and none of the further sectors, so when the first file is rendered by a playback device, the data is reproduced which is included in the part of the sectors. The method also includes generating a second file of the file system being another file than the first file and referencing at least a part of the sectors and further referencing at least one of the further sectors, such that when the second file is rendered by the playback device the part of the sectors and the at least one of the further sectors are reproduced.