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129 条记录 (耗时 0.023 秒)

    Vinyl silane compounds
    7.
    发明授权
    Vinyl silane compounds 失效
    乙烯基硅烷化合物

    公开(公告)号：US4814475A

    公开(公告)日：1989-03-21

    申请号：US242007

    申请日：1988-09-08

    申请人： Yuichi Funahashi ,  Junichiro Watanabe ,  Kiyoshi Takeda ,  Makaoto Matsumoto

    发明人： Yuichi Funahashi ,  Junichiro Watanabe ,  Kiyoshi Takeda ,  Makaoto Matsumoto

    IPC分类号： C07F7/08

    CPC分类号： C07F7/0809

    摘要： A vinylsilane compound represented by general formula (I):R.sup.1 CH.sub.2 CH.sub.2 SiR.sub.a.sup.2 (CH.dbd.CH.sub.2)3-a (I)wherein R.sup.1 represents a monovalent alicyclic unsaturated hydrocarbon group selected from the group consisting of a cyclohexenyl group and a bicycloheptenyl group; R.sup.2 represents a monovalent hydrocarbon group free from an aliphatic unsaturated bond; and a represents 1 or 2, is herein disclosed.

    摘要翻译： 由通式（I）表示的乙烯基硅烷化合物：R1CH2CH2SiRa2（CH = CH2）3-a（I）其中R1表示选自环己烯基和双环庚烯基的一价脂环族不饱和烃基; R2表示不含脂族不饱和键的一价烃基; 和a表示1或2。

    Diethynylated diphenyl hexafluoropropanes
    8.
    发明授权
    Diethynylated diphenyl hexafluoropropanes 失效
    二乙氧基二苯基六氟丙烷

    公开(公告)号：US4814472A

    公开(公告)日：1989-03-21

    申请号：US466271

    申请日：1985-02-14

    申请人： Kreisler S. Y. Lau

    发明人： Kreisler S. Y. Lau

    IPC分类号： C07C1/32 ,  C07C15/50 ,  C07C17/093 ,  C07F7/08

    CPC分类号： C07F7/0809 ,  C07C1/321 ,  C07C15/50 ,  C07C17/093

    摘要： There are disclosed diethynylated diphenyl hexafluoropropane compounds, which are suitable for forming copolymers and carbon-carbon composites. These compounds are prepared in high yields by first providing a dihalogenated diphenyl hexafluoropropane compound, coupling the dihalogenated compound with ethynyltrimethylsilane in the presence of an organometallic catalyst to form a silylated ethynyl terminated diphenyl substituted compound and subsequently desilylating the compound to form the desired diethynylated diphenyl hexafluoropropane compound.

    摘要翻译： 公开了二异戊基化二苯基六氟丙烷化合物，其适于形成共聚物和碳 - 碳复合材料。 通过首先提供二卤代二苯基六氟丙烷化合物，在有机金属催化剂的存在下将二卤代化合物与乙炔基三甲基硅烷偶联以形成甲硅烷基化的乙炔基封端的二苯基取代的化合物，随后使该化合物脱甲硅烷化以形成所需的二异丙基二苯基六氟丙烷 复合。

    Poly(dimethylsilmethylene) methylacetylene compound and a method for the preparation thereof
    9.
    发明授权
    Poly(dimethylsilmethylene) methylacetylene compound and a method for the preparation thereof 失效
    聚（二甲基亚甲硅烷基）甲基乙炔化合物及其制备方法

    公开(公告)号：US4539417A

    公开(公告)日：1985-09-03

    申请号：US658597

    申请日：1984-10-09

    申请人： Minoru Takamizawa ,  Akira Yamamoto ,  Toshinobu Ishihara ,  Mistuyoshi Ohshima

    发明人： Minoru Takamizawa ,  Akira Yamamoto ,  Toshinobu Ishihara ,  Mistuyoshi Ohshima

    IPC分类号： C08G77/00 ,  C07F7/08 ,  C08G77/48 ,  C08G77/60

    CPC分类号： C07F7/0809 ,  C08G77/60

    摘要： The invention provides a novel organosilicon compound poly(dimethylsilmethylene) methylacetylene compound of the formula MeC.tbd.C--SiMe.sub.2 --CH.sub.2 --SiMe.sub.2).sub.n Me, in which Me is a methyl group and n is a positive integer of 1 to 25. The compound is synthesized by reacting a propynylmagnesium halide of the formula MeC.tbd.CMgX, in which X is a halogen atom, or (propynyl dimethylsilyl)methylmagnesium chloride of the formula MeC.tbd.C--SiMe.sub.2 --CH.sub.2 MgCl with chloromethyl dimethyl chlorosilane in the presence of metallic magnesium and hydrolyzing the reaction product. Specifically, 1-propynyl-1,1,3,3,3-pentamethyl disilmethylene, i.e. the inventive compound with n=1, is synthesized by reacting (propynyl dimethylsilyl)methylmagnesium chloride with trimethyl chlorosilane.

    摘要翻译： 本发明提供了一种新颖的有机硅化合物，具有式MeC 3BOND C-SiMe2-CH2-SiMe2）nMe的聚（二甲基亚甲硅烷基）甲基乙炔化合物，其中Me是甲基，n是1至25的正整数。该化合物被合成 通过在金属镁的存在下使式MeC 3BOND CMgX（其中X是卤素原子）的丙炔基卤化镁或式MeC 3BOND C-SiMe2-CH2MgCl的（丙炔基二甲基甲硅烷基）甲基氯化镁与氯甲基二甲基氯硅烷反应，并水解 反应产物。 具体地，1-丙炔基-1,1,3,3,3-五甲基二亚甲基，即n = 1的本发明化合物，通过（丙炔基二甲基甲硅烷基）甲基氯化镁与三甲基氯硅烷反应合成。